An important constraint on mechanisms of past
carbon cycle variability is provided by the stable isotopic
composition of carbon in atmospheric carbon dioxide (δ¹³C-CO₂) trapped in polar ice cores, but obtaining very precise
measurements has proven to be a significant analytical challenge.
Here we describe a new technique to determine...
The South Pole ice core (SPC14), drilled in the field seasons of 2014/2015 and 2015/2016, is an intermediate length, 1,751-m ice core which preserves a 54,000-year record of past climate and atmospheric composition. The SPC14 ice core adds to the spatial grid of ice cores in Antarctica extending into the...
Laser-based spectroscopic techniques, such as cavity ring-down spectroscopy (CRDS), provide a new, cost effective and more widely available approach to measure the oxygen isotope ratio in water molecules, H₂¹⁸O/H₂¹⁶O (δ¹⁸O), and are used increasingly to measure δ¹⁸O in the world's oceans. Here, we present results from an interlaboratory comparison designed...
The exchange of carbon on earth is one of the fundamental processes that sustains life and regulates climate. Since the onset of the Industrial Revolution, the burning of fossil fuels and anthropogenic land conversion have altered the carbon cycle, increasing carbon dioxide in the atmosphere to levels that are unprecedented...
Air trapped in glacial ice offers a means of
reconstructing variations in the concentrations of atmospheric
gases over time scales ranging from anthropogenic
(last 200 yr) to glacial/interglacial (hundreds of thousands of
years). In this paper, we review the glaciological processes by
which air is trapped in the ice and...
Nitrous oxide is an important greenhouse gas that has both natural and anthropogenic sources in the modern atmosphere (Ciais et al., 2013). This project expanded the knowledge of the history of atmospheric N2O in the geologic past by measuring N2O concentrations in air trapped in very old polar ice. A...
Ice cores are considered the gold standard for recording past climate and biogeochemical changes. However, gas records derived from ice core analysis have until now been largely limited to centennial and longer timescales because sufficient temporal resolution and analytical precision have been lacking, except during rare times when atmospheric concentrations...
New ice cores retrieved from the Taylor Glacier (Antarctica) blue ice area contain ice and air spanning the Marine Isotope Stage (MIS) 5/4 transition, a period of global cooling and ice sheet expansion. Chronologies were determined for the ice and air bubbles in the new ice cores by visually matching...
One common assumption in interpreting ice-core CO₂ records is that diffusion in the ice does not affect the concentration profile. However, this assumption remains untested because the extremely small CO₂ diffusion coefficient in ice has not been accurately determined in the laboratory. In this study we take advantage of high...
This thesis focuses on the investigation of extraterrestrial tracers Ir, Pt and 3He in polar ice cores. These tracers may be used to identify characteristics of interplanetary dust particles, and to quantify the flux of extraterrestrial material during impact events, certain volcanic eruptions, and stable background periods. In the first...