The radiolytic changes in oxidation state for solutions of initially Np(V) and/or Np(VI) were investigated by gamma-irradiation in conjunction with UV/Vis spectroscopy of the aqueous phase. Samples were irradiated in varying concentrations of nitric acid, and with or without the presence of 30 % TBP in dodecane. At short irradiation...
Aqueous complexation of Th(IV), U(IV), Np(IV), Pu(III/IV), and Ce(III/IV) with DTPA was studied by potentiometry, absorption spectrophotometry, and cyclic voltammetry at 1 M ionic strength and 25 °C. The stability constants for the 1:1 complex of each trivalent and tetravalent metal were calculated. From the potentiometric data, we report stability...
Radiation damage caused by fission fragments to metal surfaces is an important research topic. Thin titanium foils were irradiated with a continuous wave beam of 132 MeV ¹³²Xe+²⁹ at the current intensity of 2 pnA. Pre- and post-irradiated surface topologies were investigated using atomic force microscopy and the observed defects...