In a recent note, Collier and Lockwood (1974) compared measurements of total solar radiation on cloudless days at an inland site in England with radiation calculated from empirical expressions derived from (i) data from weather ships in the eastern Atlantic (Lumb 1964) and (ii) measurements of radiation and turbidity in...
Fluxes of sulphur dioxide to wheat were measured over two growing seasons. The deposition velocity, vg, depended primarily on affinities of surfaces for SO2 and varied from less than 0.1 to about 1.5cms−1. Stomata were an important sink, and diurnal changes in stomatal resistance accounted for most of the variation...
The correlation between dimensionless shear ϕₘ and dimensionless height z/L, where L is the Obukhov length, for stable conditions is strongly influenced by self‐correlation for the present datasets. This effect is quite large for stronger stability but still significant for near‐neutral conditions. A conditional analysis of nocturnal stable boundary‐layer data,...
The sublimation of snow and evaporation of melted snow is contrasted between brush, grass and bare ground sites using eddy-correlation data. Averaged over the entire winter season, the evaporation/sublimation is about 20% greater over the brush site than the bare ground site, apparently due to greater supply of snow. Blowing...
A critical seasonal event for anadromous Chinook salmon (Oncorhynchus tshawytscha) is the time at which adults migrate from the ocean to breed in freshwater. We investigated whether allelic variation at the circadian rhythm genes, OtsClock1a and OtsClock1b, underlies genetic control of migration timing among 42 populations in North America. We...
Cold air drainage and pooling occur in many mountain valleys, especially at night and during winter. Local
climate regimes associated with frequent cold air pooling have substantial impacts on species phenology, distribution and
diversity. However, little is known about how the degree and frequency of cold air drainage and pooling...
North Atlantic right whales (Eubalaena glacialis) were found in an important nineteenth century whaling area east of southern Greenland, from which they were once thought to have been extirpated. In 2007–2008, a 1-year passive acoustic survey was conducted at five sites in and near the ‘Cape Farewell Ground’, the former...
The potent antitumor agent phorboxazole A was synthesized from six subunits comprising C1-C2 (115), C3-C8 (98), C9-C19 (74), C20-C32 (52), C33-C41 (84) and C42-C46 (85). Tetrahydropyrans B and C containing cis-2,6-disubstitution were fabricated via palladium(II)-mediated intramolecular alkoxycarbonylation which, in the case of tetrahydropyran C, was carried out with catalytic palladium(II)...
Mapping out multidimensional potential energy surfaces has been a goal of
physical chemistry for decades in the quest to both predict and control chemical
reactivity. Recently a new spectroscopic approach called Femtosecond Stimulated Raman
Spectroscopy or FSRS was introduced that can structurally interrogate multiple
dimensions of a reactive potential energy...
While the d⁰ transition-metal POMs of Group V (V⁵⁺, Nb⁵⁺, Ta⁵⁺) and Group VI (Mo⁶⁺, W⁶⁺) have been known for more than a century, the actinyl peroxide POMs, specifically those built of uranyl triperoxide or uranyl dihydroxidediperoxide polyhedra, were only realized within the last decade. While virtually every metal on...