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A Langmuir sorption model incorporating a second step of
irreversible absorption was applied to a model soil system. The column
was packed with cellulose triacetate; pulse and step input tests with
3,4-dichlorophenol were performed; the effluent concentration was
measured by electron capture detector gas chromatography and sorption
rate constants were...
At present the adsorption kinetic of ions by soil particles is considered to be a surface reaction. When the transport of solutes in soils is described using the one-dimensional flow equation, it becomes a serious problem that lateral diffusion of ions from the bulk solution towards the soil surfaces is...
A large rainfall simulator was used to study infiltration on six
soil plots. Water content and capillary pressure were measured during
steady rainfall at rates less than required to produce runoff. The
equipment and procedures used to make these measurements are discussed.
Water content and capillary pressure data obtained as...
The formation of solution and solid complexes with heavy metals
will partially determine their mobility and plant availability in soil
systems. Experiments were initiated to determine the effect of pH,
adsorbent and initial metal concentrations, and the presence of water
soluble ligands on the adsorption of Cd and Cu by...
The reaction of F, often a component of industrial
wastes and phosphatic fertilizers, with soil was studied
with regard to sorption reactions and resultant changes in
solution composition. Sodium fluoride solutions (0.0 to
2.5 mmol/L F) were equilibrated with ten soils for 24h.
The soil extract solutions were analyzed for...
Chromium and its compounds are widely used by modern industries, resulting in large quantities of this element being discharged into the environment. To remove chromium from contaminated soils and ground water, it is necessary to predict chemical and physical processes that control the rate of reactions and transport of chromium...
Soil column studies were performed on a chromium contaminated soil from the United
Chrome Products Superfund Site currently undergoing a pump-and-treat cleanup process. The
goal of the research was to provide insight into the feasibility of chemically changing the injection
fluid of the pump-and-treat system to enhance hexavalent chromium (Cr(VI))...