The interactions of chemical species with a solid surface play a role in many everyday applications such as heterogeneous catalysis, corrosion, and degradation reactions. Understanding the reaction kinetics and thermodynamics via rate constants and equilibrium constants, which require knowledge of the adsorbed species’ entropy, is essential for tuning these surface...
At present the adsorption kinetic of ions by soil particles is considered to be a surface reaction. When the transport of solutes in soils is described using the one-dimensional flow equation, it becomes a serious problem that lateral diffusion of ions from the bulk solution towards the soil surfaces is...
The Lizzie Bennet Diaries is a multimodal adaptation of Pride and Prejudice, released from 2012-2013. As a media event, the show proved how effective transmedia storytelling can be, eventually winning an Emmy for Original Interactive Program. In creating an intensely immediate narrative world, the series adapted more than Jane Austen’s...
This paper presents detailed information of value in experimental work in the laboratory and in promoting the effeciency of commercial paper-making plants employing the soda process.
Adsorbed molecules are involved in many reactions on solid surfaces that are of great technological
importance. As such, there has been tremendous effort worldwide to learn how to theoretically
predict rates for reactions involving adsorbed molecules. Theoretical calculations of rate constants
require knowing both their activation energy and prefactor. Recent...
The relative rates of hydrogen abstraction from 1-phenylalkanes and a,w-diphenylalkanes using N-bromosuccinimide and bromotrichloromethane were determined at 70°C. In both cases the reactions were photoinitiated. Only benzylic bromination was observed. The 1-phenylalkanes reacted with both reagents to give rates largely independent of substrate. Similarly, the rate of the reaction between...