Using supercritical CO₂ (sCO₂) as a working fluid has increasingly gained attention in the energy industry. sCO₂ power cycles has various advantages, such as high cycle efficiency, compact turbomachinery, and potential zero CO₂ emission. Along with these benefits, materials degradation issues have also been emphasized in the last decade. Aqueous...
The thermal degradation of structural materials is considered to be a key factor for evaluating the lifetime of current nuclear power plants. Ni-based and Fe-based alloys, such as 690, 625, 304, and 316, are widely used in nuclear industry as structural components due to the extraordinary corrosion resistance and mechanical...
New low enriched uranium (LEU) fuels are being developed for replacement of high enriched uranium (HEU) fuels in high power research reactors. U-Mo LEU plate fuels have been identified as a candidate for replacement of current HEU fuels. However, U-Mo fuels tend to exhibit accelerated swelling typically at fission densities...
The corrosion resistances of several alloys were investigated to optimize performance and cost in seawater and supercritical CO2 environments. Many alloys are prone to corrosion in seawater and/or supercritical CO2 containing impurity environments. Exposure and electrochemical experiments were conducted in both environments to evaluate alloys’ corrosion resistance. In seawater corrosion...
The corrosion behaviors of carbon and stainless steels were investigated in supercritical CO₂ (sCO₂ ) containing H₂O and O₂ simulating conditions that exist in direct sCO₂ power cycle heat exchangers. Thermodynamic properties of CO₂-H₂O-O₂ systems related to the corrosion phenomena were determined using NIST software. The exposure tests of the...
Mechanical property degradation due to isothermal ageing is of potential concern for alloys based on the Ni-Cr binary system (e.g., Inconel 690, 625), particularly in nuclear power applications where component lifetimes can exceed 40 years. In the present research, the disorder-order phase transformation, which is the primary mechanism of ageing,...
CPM-M4 tool steel is a commonly used knife blade material due to its high strength and wear resistance. The goal of this thesis is to understand how heat treatment parameters affect blade performance and microstructure.Five heat treatments were applied to CPM-M4 steel by varying austenitizing and tempering temperatures. The microstructures...
This work explores the mechanical properties of single-phase niobium alloy C103 from room temperature to 600°C for the purpose of expanding safe uses of the material into new applications. The study utilizes a symmetrically notched triaxial tensile specimens to manipulate the internal stress field in order to observe the changes...
Nickel (Ni)-based alloys with a high chromium (Cr) content are frequently employed in applications where elevated temperatures and/or corrosive environments are present due to their excellent corrosion resistance and mechanical properties. However, a gap exists around the formation, and kinetics of long-range order (LRO) Ni2Cr phase in both model binary...
This work explores the hypothesis that proton irradiation is a feasible alternative to simulate accelerated thermal aging for Ni2Cr long-range ordered phase formation within NiCr and NiCrFe alloys. In this study, various model alloys and commercial alloys 690 and 690+P (0.01 wt.% P) were subject to 2 MeV proton irradiation...