Water electrolysis plays a pivotal role in achieving a green hydrogen economy by sourcing electricity from intermittent renewable sources. However, the efficiency of the electrolysis process is limited by the sluggish oxygen evolution reaction (OER) kinetics, whereas the kinetics of the hydrogen evolution reaction (HER) are more facile. This thesis...
TiO2 is a versatile wide bandgap transparent semiconducting oxide with three well known polymorphs: Anatase, Rutile and Brookite. These crystal structures are desired for many industrial applications mainly for their photocatalytic activity, oftentimes in thin-film form. Thin-film crystalline polymorphs of TiO2 are often made by physical vapor deposition on a...
The development of ecohydrological frameworks and theories under the ongoing global climate crisis depends on the development of new and advanced ecohydrological measurements. Currently, numerous of datasets have been collected at plot and ecosystem levels to understand the complex interactions of along the soil, plant, and atmosphere continuum. The development...
The spread of nonnative species across the globe has contributed to biodiversity loss and changes in ecosystem structure and function. Monitoring the introduction, naturalization, and spread of introduced species is critical in abating negative impacts wrought by species invasions. However, providing basic information concerning the presence or spread of many...
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H. Spatial Patterns of Ventenata Probability Difference and
Percent Probability Difference
Urban agriculture (UA), or growing and producing food within urban areas, is rising in popularity across the United States. There are social and environmental benefits from growing food within urban neighborhoods. UA presents the opportunity for food security in neighborhoods that do not have access to safe and healthy foods,...
Coniferous trees are a major North American crop that has been intensively managed for its commercial value, while also serving as critical habitat for abundant wildlife and as carbon sinks. Having diverse functions, North American temperate coniferous forests have become a research hotspot for numerous scientific studies aiming to integrate...
This dissertation investigated potential ecological limitations to seedling regeneration in young, seasonally dry, evergreen forest restoration plantations in northern Thailand. We explored whether recruitment of colonizing tree species in the restoration plantations can be attributed to seed dispersal mode (i.e. abiotic or animal dispersal) and seed size. We did this...
Iodine-129 is a key risk driver at sites where nuclear materials have been fabricated or processed, and it is a predominant isotope of concern in long-term waste storage strategies. I-129 exists primarily as iodate in the subsurface at the Hanford Site in south-central Washington State. Between 15 and 40% of...
Aerogels are interesting material systems with outstanding properties such as low density, high surface area, and low thermal conductivity. They can be used for a variety of applications, such as solar cells, sensors, or catalysts. Additionally they provide a unique model system to study the properties of small particles. Cellulose...
Sustaining forest resources requires a better understanding of forest ecosystem processes, and how management decisions and climate change may affect these processes in the future. While plot and inventory data provide our most detailed information on forest carbon, energy, and water cycling, applying this understanding to broader spatial and temporal...