Carboxylic acids have played an important role in the field of actinide (An) and lanthanide (Ln) separations and the reprocessing of irradiated nuclear fuel. Recent bench-scale experiments have demonstrated that 3-carboxy-3-hydroxypentanedioic acid (citric acid) is a promising aqueous complexant that can effectively aid in the separation of transition metals from...
Aqueous complexation of Th(IV), U(IV), Np(IV), Pu(III/IV), and Ce(III/IV) with DTPA was studied by potentiometry, absorption spectrophotometry, and cyclic voltammetry at 1 M ionic strength and 25 °C. The stability constants for the 1:1 complex of each trivalent and tetravalent metal were calculated. From the potentiometric data, we report stability...
This thesis is a study of the shifting philosophical trends in the works of Samuel Beckett, Donald Barthelme, and Kurt Vonnegut as representations of a greater shift from modernism to postmodernism. I have chosen to explore Beckett's plays Waiting for Godot and Krapp's Last Tape, Barthelme's short stories "Nothing: A...
Well-defined fronts develop at the seaward edge of riverine plumes where suspended materials and planktonic organisms are concentrated by convergent water flows. Riverine plume fronts have been hypothesized to be favorable fish habitats because they can lead to localized prey
aggregations. We examined the spatial distribution of juvenile Pacific salmonids...
The genomes of five Cochliobolus heterostrophus strains, two Cochliobolus sativus strains, three additional Cochliobolus species (Cochliobolus victoriae, Cochliobolus carbonum, Cochliobolus miyabeanus), and closely related Setosphaeria turcica were sequenced at the Joint Genome Institute (JGI). The datasets were used to identify SNPs between strains and species, unique genomic regions, core secondary...
Correction
5 Mar 2013: Ohm RA, Feau N, Henrissat B, Schoch CL, Horwitz BA, et al. (2013) Correction: Diverse Lifestyles and Strategies of Plant Pathogenesis Encoded in the Genomes of Eighteen Dothideomycetes Fungi. PLOS Pathogens 9(3): 10.1371/annotation/fcca88ac-d684-46e0-a483-62af67e777bd
Epigenetic changes, including aberrant DNA methylation, result in altered gene expression and play an important role in carcinogenesis. Phytochemicals such as sulforaphane (SFN) and 3,3′-diindolylmethane (DIM) are promising chemopreventive agents for the treatment of prostate cancer. Both have been shown to induce re-expression of genes, including tumor suppressor genes silenced...
Spray impingement cooling has been shown to be a leading candidate for future high heat flux cooling applications. In general, spray cooling curves consist of three heat flux regimes; single-phase, two-phase and critical heat flux (CHF). CHF is considered the design limit for almost all two-phase cooling applications, as a...
The goal of Advanced Fuel Cycle Initiative program is to efficiently separate and recover actinides in attempts to reprocess irradiated nuclear fuel and reduce the necessary storage volume. In order to facilitate large-scale industrial
applications of liquid-liquid separation processes, knowledge of the thermodynamic constants associated with the distribution of metal...
Granulocytes are currently transfused as soon as possible after collection because they rapidly deteriorate after being removed from the body. This short shelf life complicates the logistics of granulocyte collection, banking and safety testing. Cryopreservation has the potential to significantly increase shelf life; however, cryopreservation of granulocytes has proven to...