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Radical and related reactions of aromatic species

Creator:: Truska, Scott
Abstract:: A three part study involving aspects of radical properties of various aromatic species was accomplished. Experiments to ascertain the importance of geometric and electronic effects on the intramolecular transfer of a pi-complexed radical to a terminal double bond was performed. Several 4-aryl-1-butenes were reacted in competition with 1-undecene with a...
Resource Type:: Dissertation
Full Text:: Reactions of Aromatic Species. Abstract approved: Gerald Jay Gleicher A three part study involving

P-xylene as a starting material in the preparation of P-toluic acid, terephthalic acid and their derivatives

Creator:: Yen, Shou-hsuan
Resource Type:: Masters Thesis

Homolytic aromatic substitution : substituent effects in the radical trichloromethylation of 9-X-anthracenes

Creator:: Arnold, James Charles
Resource Type:: Masters Thesis
Full Text:: Homolytic aromatic substitution : substituent effects in

The aromatic Cope rearrangement : energetics and reality

Creator:: Almond, Stephen W.
Resource Type:: Dissertation
Full Text:: Approximate Resonance Energies) from Heats of Combustion of Some Aromatic C(.mpounds (Ref. 26). Compound

An analytical and sensory evaluation of the aroma volatiles of Tuber gibbosum

Creator:: Marin, Anna B.
Abstract:: The aroma of Tuber gibbosum, a native Oregon truffle, was characterized using two distinct techniques. Volatile aroma constituents were identified by chemical analysis, and sensory characteristics were determined by examining response of the general populace to the truffle aroma. Truffle samples from four maturity ranges, as determined by microscopic examination...
Resource Type:: Masters Thesis
Full Text:: were identified from their mass spectra which were matched to known compound spectra via the

Zero Kinetic Energy Photoelectron Spectroscopy of Polycyclic Aromatic Hydrocarbons

Creator:: Harthcock, Colin
Abstract:: In this dissertation, I describe spectroscopic studies of jet-cooled polycyclic aromatic hydrocarbons (PAH) and one nitrogen substituted PAH (PANH) using pulsed field zero kinetic energy (ZEKE) photoelectron spectroscopy and resonantly enhanced multiphoton ionization (REMPI) spectroscopy. Recently, there has been a demand for far-infrared (FIR) spectral information of astrophysically relevant molecules...
Resource Type:: Dissertation
Full Text:: , O.; Oomens, J. Gas-phase infrared spectra of cationized nitrogen-substituted polycyclic aromatic

Dechlorination of p-chlorophenol on bimetallic Pd/Fe catalyst in a magnetically stabilized fluidized bed : experiment and theory

Creator:: Graham, Lisa Jean
Resource Type:: Dissertation

I. Infrared spectra of solid solutions in alkali halide crystals [and] Method for obtaining minimal kinematically complete sets of internal coordinates

Creator:: Conant, Donald Robertson
Abstract:: A study was made of the infrared absorption spectrum for cyanate ion in KCl and KBr host lattices containing small amounts of calcium or barium ion. Both pellets and single crystals were scanned during the course of this study. The spectra of the barium or calcium doped crystals contained many...
Resource Type:: Dissertation
Full Text:: I. Infrared spectra of solid solutions in alkali halide

Polarization spectroscopy and photodissociation studies of nitroaromatic compounds in the gas phase

Creator:: Abbott, James E.
Abstract:: The central purpose of this dissertation was to explore and expand the use of an uniform electric field for orientation and for subsequent spectroscopic investigation of asymmetric polar molecules in the gas phase. The systems of study were nitrobenzene (NB) and the nitrotoluene (NT) isomers. We were able to quantitatively...
Resource Type:: Dissertation
Full Text:: .......................................................... 158 LIST OF FIGURES Figure Page 1.1 Absorption Spectra of Nitrobenzene and the Three

Photochemistry of some bromoarenes

Creator:: Jang, Jung-suk
Abstract:: The photodebromination of selected bromoarenes has been studied at 300 nm to determine the the possible mechanistic pathways leading to product. Irradiation of 4-bromobiphenyl (BpBr) at this wavelength leads to the product biphenyl. The quantum yield of intersystem crossing (0.98) and quenching studies with cis-1 ,3-pentadiene suggest that the reaction...
Resource Type:: Dissertation
Full Text:: recording all the NMR spectra as well as to Donald Griffin for GC-MS analyses. I must acknowledge my

ScholarsArchive@OSU

Radical and related reactions of aromatic species

P-xylene as a starting material in the preparation of P-toluic acid, terephthalic acid and their derivatives

Homolytic aromatic substitution : substituent effects in the radical trichloromethylation of 9-X-anthracenes

The aromatic Cope rearrangement : energetics and reality

An analytical and sensory evaluation of the aroma volatiles of Tuber gibbosum

Zero Kinetic Energy Photoelectron Spectroscopy of Polycyclic Aromatic Hydrocarbons

Dechlorination of p-chlorophenol on bimetallic Pd/Fe catalyst in a magnetically stabilized fluidized bed : experiment and theory

I. Infrared spectra of solid solutions in alkali halide crystals [and] Method for obtaining minimal kinematically complete sets of internal coordinates

Polarization spectroscopy and photodissociation studies of nitroaromatic compounds in the gas phase

Photochemistry of some bromoarenes

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