The formation of solution and solid complexes with heavy metals
will partially determine their mobility and plant availability in soil
systems. Experiments were initiated to determine the effect of pH,
adsorbent and initial metal concentrations, and the presence of water
soluble ligands on the adsorption of Cd and Cu by...
Volatile hydrophobic compounds (HOCs) brought into soil and sediment
systems represent a serious threat to the environment. Dissolved
organic carbon (DOC) may exert an important influence over the total
aqueous solubility and mobility of organic pollutants through their
incorporation into micelles or the formation of soluble complexes.
To date, however,...
The emission of sulfur oxides from anthropogenic sources represents a potential threat to terrestrial ecosystems. Sulfate, the most highly oxidized form of sulfur, is the most common form of inorganic sulfur in most soil environments. The sorption of sulfate may influence the alkalinity of the soil solution and as a...
This study was initiated to characterize the distribution of Fe-Mn nodules and to elucidate trends of Fe, Mn, and P relative to the intensity of the annual cycles of reduction and oxidation. Nodules were enriched in Fe, Mn, and P relative to the soil matrix making them an integral part...
Biogeochemical data from four small watersheds in the Silver Creek study area, southwestern Idaho, provide the basis for: 1. An estimate of chemical and erosional denudation rates (CD and ED), 2. an estimate of plagioclase weathering rate, 3. a rational basis for estimating the rate of nutrient supply to soil...
Two studies concerning low molecular weight organic acids in soils were conducted. In the first study, anion exclusion chromatography was used to separate and identify 12 common organic acids, and the accuracy, precision and detection limits of the method were determined. The method was found to be sensitive and accurate...
Runoff from agricultural lands into Upper Klamath Basin rivers and lakes can
cause water quality problems affecting fish and wildlife. Excessive eutrophication
in Upper Klamath Lake is linked to high nutrient input (particularly phosphorus)
stemming from both lake sediments and watershed tributaries.
On a unit area load basis the Wood...
The kinetics of physical and chemical processes controlling the precipitation of iron oxide minerals in unsaturated media were investigated in this study. The characteristic morphology, mineralogy, and chemistry of iron oxides were also explored. Laboratory column experiments using fine and coarse grades of silica sand were conducted to compare the...
Halogenated organic compounds have had widespread and massive applications in industry, agriculture, and private households, for example, as degreasing solvents, flame retardants and in polymer production. They are released to the environment through both anthropogenic and natural sources. The most common chlorinated solvents present as contaminants include tetrachloroethene (PCE, perchloroethene)...