A present abundance of biomass and a decreasing supply of petroleum signal the need for efficient pathways from renewable feedstocks to high value chemicals. One such class of chemicals is oleofurans, molecules comprised of a furan ring and carbon chain which can be used to make powerful hard water surfactants....
Two distinct strategies were explored for the enantioselective synthesis of α-heteroatom substituted alkyl boronic esters by stereoselective reagent-controlled homologation using transient chiral carbenoid reagents CHYMX (Y = heteroatom, X = nucleofuge, M = electrofuge). In the first case, a stereospecific reagent-controlled homologation (sStReCH) approach to α-alkoxyalkylboronates using α-metalated S,O- and...