The corrosion resistances of several alloys were investigated to optimize performance and cost in seawater and supercritical CO2 environments. Many alloys are prone to corrosion in seawater and/or supercritical CO2 containing impurity environments. Exposure and electrochemical experiments were conducted in both environments to evaluate alloys’ corrosion resistance. In seawater corrosion...
The corrosion behaviors of carbon and stainless steels were investigated in supercritical CO₂ (sCO₂ ) containing H₂O and O₂ simulating conditions that exist in direct sCO₂ power cycle heat exchangers. Thermodynamic properties of CO₂-H₂O-O₂ systems related to the corrosion phenomena were determined using NIST software. The exposure tests of the...
The next generation of high temperature structural alloys must exhibit exceptional resistance to fracture, creep, oxidation, and fatigue at high temperatures. Chromium is being considered due to its high melting point (>1800°C), relatively low density (~7.2 g/cc), high temperature strength, and oxidation resistance. Limiting the use of chromium is its...
Using supercritical CO₂ (sCO₂) as a working fluid has increasingly gained attention in the energy industry. sCO₂ power cycles has various advantages, such as high cycle efficiency, compact turbomachinery, and potential zero CO₂ emission. Along with these benefits, materials degradation issues have also been emphasized in the last decade. Aqueous...
The corrosion resistance of steels and nickel based alloys was investigated in supercritical CO2 (sCO2). Two types of experiments were conducted. The first set of experiments were conducted in a low temperature aqueous environment to simulate conditions that would exist in direct sCO2 power cycle low temperature heat exchangers. The...
In the second chapter, a foam-core meniscus coating process was developed for retrofitting 100 nm-scale sol-gel anti-reflective coatings onto in-field solar panels through the deposition, evaporation, and curing of wet films.Advantages of this technique include the means to control fluid flow relative to substrate motion and the ability to conform...