A gas chromatographic procedure was developed for the determination
of nanogram quantities of hydrocyanic acid using a
flame ionization detector. Excellent chromatograms were obtained
on a porous polyaromatic polymer column (Porapak Q) at 60°C. The
procedure was employed for the analysis of HCN in aqueous cyanide
solutions. Solutions as low...
Techniques have been developed for measuring the
temperature, stable species concentrations, and atomic
radical concentrations during a transient combustion
event. They combine the features of direct sampling with
two spectroscopic techniques to produce relatively simple
diagnostic techniques to obtain time-resolved
measurements. In this study, a transient event was
provided by...
Volatile sulfur compounds have been reported to be
responsible for the sulfurous off-flavors generated during
the thermal processing of milk; however, their analysis
has been a challenge due to their high reactivity,
high volatility, and low sensory threshold. In this study,
reactive thiols were stabilized and the volatile sulfur
compounds...
Dietary cyclopropenoid fatty acids (CPFA) have long
been known to cause pronounced physiological disorders in
both farm and laboratory animals. Past work has shown
CPFA to be a powerful promoter of carcinogenesis in trout,
rats and mice. Sterculic and malvalic acids (CPFA's) are
found in seed lipids of plants from...
In this dissertation, I present electronic spectra of a few polycyclic aromatic hydrocarbons (PAHs): tetracene, pentacene, pyrene, benzo[g,h,i]perylene and benzo[a]pyrene using resonantly enhanced multiphoton ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The work of tetracene and pentacene also combine a laser desorption source with a ZEKE spectrometer, demonstrating...
Flame retardants are in many home products including couches, chairs, and electronics. The most commonly used flame retardants contained polybrominated diphenyl ethers (PBDEs) until 2004, when the majority of these chemicals were phased out. PBDEs were found to be persistent, bioaccumulative, and toxic to both humans and the environment. Organophosphate...