We analyzed the unsaturation ratio (U k/37 ) of long-chain ketones—a molecular sea-surface temperature (SST) indicator—concentrations of carbonate and organic carbon in sediments from Site 846 in the eastern equatorial Pacific Ocean. Based on an isotopic age model for the composite depth section of 0-46 m below seafloor and on...
Measurements of the U₃₇ K’ index and the absolute abundance of alkenones in marine sediments are increasingly used in paleoceanographic research as proxies of past sea surface
temperature and haptophyte (mainly coccolith-bearing species) primary productivity, respectively. An
important aspect of these studies is to be able to compare reliably data...
Crops were planted into tilled strips in an established perennial ryegrass
(Lolium perenne L. 'Manhattan II'), sod covering various portions (55%, 66%,
77%) of the row width. Italian beans (Phaseolus vulgaris L. 'Romano II')
biomass and yields showed a trend among sod strips with lower yields
produced in plots with...
Carbon isotopically based estimates of CO₂ levels have been generated from a record of the photosynthetic fractionation of ¹³C (≡εp) in a central equatorial Pacific sediment core that spans the last ~255 ka. Contents of ¹³C in phytoplanktonic biomass were determined by analysis of C37 alkadienones. These compounds are exclusive...
Recent technical progress has made new forms of controller
implementations on computers possible. Especially the technique of Fuzzy Logic
Control has found a growing number of applications. Also the development of fast
A/D converters has made the acquisation of data with vision based systems
possible. In this project we combine...
The structural architecture present in marine toxin azaspiracid - 20 stereocenters, 9 rings, 3 separated spirocenters - has attracted considerable synthetic attention. Our efforts toward the synthesis of azaspiracid have led to the completion of both C₁-C₂₆ northern and C₂₇-C₄₀ southern halves. Herein, the
synthesis of southern FGHI ring system...
More than 30 members of the diverse amphidinolide family of biologically active macrolides have been isolated over last three decades. From this family, amphidinolides C and F stand among the most complex and densely functionalized affiliates. Recently, we have accomplished the first total synthesis of amphidinolide F. The all-carbon framework...
Chemoreception is one of the dominant sensory modalities for many species of salamanders (reviewed in Chapter 2). At least seven of the ten currently recognized salamander families are known to respond to some sort of chemical cue. These responses are as varied as delaying hatching, seeking refuge, or initiating aggressive...
Recent works have investigated use of the hydrogen isotopic composition of C₃₇ alkenones (δD[subscript K37s]), lipid biomarkers of certain haptophyte microalgae, as an independent paleosalinity proxy. I discuss herein the factors impeding such an application and identify the potential alternative use of δD[subscript K37s] measurements as a proxy for non-thermal,...
The Harderian gland is a large cephalic gland present in most groups of terrestrial vertebrates. Although the Harderian gland has been the focus of numerous studies for more than 300 years, its physiological function has remained largely unresolved. Harderian gland secretions are diverse among different taxa, and many putative functions...
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Robert T. Mason
The Harderian gland is a large cephalic gland present in most groups of