This thesis examines the dielectric properties of two systems based on the perovskite materials
barium titanate and strontium titanate. A solid solution was created starting with these base
materials and then adding varying amounts of bismuth-zinc titanate and sodium niobate. These
compositions were calcined and sintered at temperatures determined to...
Spintronics is an emerging field of research dealing with devices that can potentially exploit the additional degree of freedom provided by the electron spin along with or instead of the conventional electronic charge. One of the most promising aspects of spintronics is the potential use of magnetostatic spin waves as...
Heavily acceptor doped Pb1.02Dx(Zr0.5Ti0.5)1-xO3 ceramics, where A is the dopant, were investigated in this research. Dopants studied included iron, magnesium and manganese at mole concentrations x ≤ 0.20. X-ray diffraction data along with scanning electron microscopy images revealed the solubility limits of these ceramics. All doped compositions exhibited a shift...
Amorphous multicomponent metals have promising applications in novel electronic devices because of their atomically smooth surface morphology and lack of grain boundaries. It is important to understand the thermal transport properties of amorphous metals and an accurate measurement of their thermal conductivity will be essential for further improvement of device...
Taking long-term electrical measurements of a large number of neurons simultaneously is required for many modern neuroscience experiments. However, such experiments are currently limited by the shortcomings of traditional neurosensing technology. For example, there is a significant mechanical mismatch between rigid silicon probes and soft biological tissues. This mismatch can...
This work investigates the relationship between the local structure and physical properties of a set of classical (MgTiO3, CaTiO3, SrTiO3, and BaTiO3) and complex ((1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3[BZT-BCT], Na0.5Bi0.5TiO3 [NBT]) perovskite electroceramics. The materials in this work were synthesized via standard solid state ceramic synthesis, the structure was investigated through a number of...
The advent of 3D Printing has invigorated research into metamaterials, synthetic composite material that produce properties generally not found in natural materials, requiring further studies into understanding the fundamental properties of these materials. This dissertation proposes a novel imaging technique to investigate the surface interactions occurring in an unsaturated packed...
Phosphate and peroxide stabilize new oxo-hydroxo niobium clusters in water at low pH. The clusters open a new chapter in aqueous niobium chemistry under acidic conditions. The clusters also produce atomically smooth, amorphous niobium oxide phosphate (NbPOx) thin films. Reaction pathways from cluster solutions to amorphous niobium oxide phosphate solids...
In the first part of this work, thin films of Al₂O₃ deposited via atomic layer deposition (ALD) are demonstrated to improve the thermal stability of cellulose nanocrystal (CNC) aerogels. ALD is a chemical vapor deposition (CVD) like method in which sequential precursor exposures and self-limited surface reactions produce a conformal...
CIGS and CdTe based commercial thin-film solar cells (TFSCs) require an absorber thickness greater than 2 µm and 4 µm, respectively, to adequately absorb the solar spectrum. To efficiently extract photoexcited electrons, these TFSCs require relatively defect-free absorbers with high-minority carrier mobility (> 100 cm2V−1s−1) and long lifetime (> 10...