One-electron oxidation of the μ-oxo dimer
(cis,cis-[Ruᴵᴵᴵ(bpy)₂(OH₂)]₂O⁴⁺, {3,3}) to {3,4} by S₂O₈²⁻ can
be described by three concurrent reaction pathways corresponding
to the three protic forms of {3,3}. Free energy
correlations of the rate constants, transient species dynamics
determined by pulse radiolysis, and medium and temperature
dependencies of the alkaline...
Full Text:
(bpy)2(OH2)]2O4+ “Blue Dimer”
James K. Hurst,† Margo Roemeling,‡ and Sergei V. Lymar
One-electron oxidation of the μ-oxo dimer
(cis,cis-[Ruᴵᴵᴵ(bpy)₂(OH₂)]₂O⁴⁺, {3,3}) to {3,4} by S₂O₈²⁻ can
be described by three concurrent reaction pathways corresponding
to the three protic forms of {3,3}. Free energy
correlations of the rate constants, transient species dynamics
determined by pulse radiolysis, and medium and temperature
dependencies of the alkaline...
Full Text:
Reactivity: Oxidation of the
cis,cis-[Ru(bpy)₂(OH₂)]₂O⁴˖ "Blue Dimer"
Hurst, J. K., Roemeling, M. D
One-electron oxidation of the μ-oxo dimer
(cis,cis-[Ruᴵᴵᴵ(bpy)₂(OH₂)]₂O⁴⁺, {3,3}) to {3,4} by S₂O₈²⁻ can
be described by three concurrent reaction pathways corresponding
to the three protic forms of {3,3}. Free energy
correlations of the rate constants, transient species dynamics
determined by pulse radiolysis, and medium and temperature
dependencies of the alkaline...
Pacific cod (Gadus macrocephalus) is an economically and ecologically important species in the southeastern
Bering Sea and Aleutian Islands, yet little is known about the spawning dynamics of Pacific cod in
these regions. To address this knowledge gap, we applied a gross anatomical maturity key for Pacific cod
to describe...
Five NAIA intercollegiate men's basketball teams and 53 players
served as subjects to determine the role pre-game anxiety played in
basketball game performance. The study involved four games in which
Western Oregon State College competed against other small colleges
in Oregon during the 19 -81 season. Performance in basketball was...
Bembidion (Sloanephila) tahitiense, sp. nov., is described from Mont Mauru, an isolated massif of Tahiti Nui volcano. Based upon evidence from seven genes (four nuclear protein-coding, one mitochondrial protein-coding, two nuclear ribosomal), its sister group is the Australian B. jacksoniense Guérin-Méneville, with which it shares a synapomorphic spur on the...
Bembidion (Sloanephila) tahitiense, sp. nov., is described from Mont Mauru, an isolated massif of Tahiti Nui volcano. Based upon evidence from seven genes (four nuclear protein-coding, one mitochondrial protein-coding, two nuclear ribosomal), its sister group is the Australian B. jacksoniense Guérin-Méneville, with which it shares a synapomorphic spur on the...
Full Text:
James K. Liebherr and David R. Maddison
Department of Entomology, Cornell University, Ithaca, NY 14853
Bembidion (Sloanephila) tahitiense, sp. nov., is described from Mont Mauru, an isolated massif of Tahiti Nui volcano. Based upon evidence from seven genes (four nuclear protein-coding, one mitochondrial protein-coding, two nuclear ribosomal), its sister group is the Australian B. jacksoniense Guérin-Méneville, with which it shares a synapomorphic spur on the...
Microstructure observations near upwelled fronts indicate considerable variation in the structure of
vertical mixing across the frontal region. Observations of cool filaments off northern California
indicate that within the cool (dense) core of filaments the raised pycnocline inhibits the penetration to
middepths of surface-generated mixing. The microstructure profiles are used...