The motivation for undertaking this research was to increase the understanding of processing colloidal semiconductor nanocrystals and thin films metallic glasses to enable their wider application in future devices. This research covered two unique materials, lead selenide (PbSe) nanocrystals and thin film metallic glass alloy of zirconium copper aluminum nickel...
A new, reproducible method of using electromigration to form
metallic nano-conductors is developed using gold and a tin-silver alloy.
Measurements revealed a quantization of the electrical conductance
consistent with the theory of quantum conductance. The theory of
quantum conductance is applied to show that a nano-conductor with a
cross-section of...
Organic semiconductors are used in a wide variety of applications including transistors,solar cells, and light emitting diodes. These materials are solution-processable,low cost, and tunable. Many successful organic optoelectronic materials utilizeblends of several types of molecules (such as donors and acceptors) in order topromote charge generation. As blends are an inherently...
The role of gold nanoparticles supported on ZnO in photocatalytic activity for dye degradation
was investigated. To do this, gold nanoparticles supported on ZnO (Au-ZnO) were prepared using a
simple co-precipitation method. The prepared nanocatalyst was characterized by high resolution
transmission electron microscopy, X-ray diffraction, temperature programmed reduction, X-ray
photoelectron...
This dissertation covers my work relating to the application of strong terahertz (THz) radiation to study the nonlinear properties of nano-scale material. It presents experimental and numerical studies on the optical and electronic properties of various material system including single-layer graphene, multi-walled carbon nanotubes (MWCNTs), nanoantenna-patterned gallium arsenide (GaAs) and...
Using a simple dry transfer process, I construct and characterize three nanoscale MoS2 devices using current-voltage curves, Raman spectroscopy, optical and atomic force microscopy. I compare these devices, the thinnest of which was few layer ( ≤ 10 nm) MoS₂ capable of showing photoconductance, with a current whose magnitude is...
Functional control at the nanoscale forms the foundation of biological systems. These work at the cellular level by manipulating ions and molecules. Nanoscale devices that give functional control at this scale are also becoming an important component in diverse fields such as electronics, medicine, engineering, and manufacturing. Moreover, scientific advances...
Nanoscale polymers (including nanoplastics) are widely present through commerce and make their way into the environment. As the improper disposal of plastic waste leads to continued accumulation and degradation of plastic pollution, the presence of plastic particles less than 1 micron (μm) in size (nanoplastics) will increase. Heightened concern over...
PN junctions in nanoscale materials are of interest for a range of technologies including photodetectors, solar cells, and light-emitting diodes. However, Schottky barriers at the interface between metal contacts and the nanomaterial are often unavoidable. The effect of metal-semiconductor interfaces on the behavior of nanoscale diodes must be understood, both...
Time-dependent electronic transport is increasingly important to the state-of-the-art device design and fabrication. The development of nanoscale sensing, the harnessing and control of structural fluctuations, and the advancement of next-generation materials all require a treatment of quantum dynamics beyond the level of traditional methods and a more nuanced approach to...