Native bees are critically important organisms that support biodiversity and crop production via their pollination services. Wildfires in temperate conifer forests can increase bee abundance and flowering plant density due to increased light exposure, but little information is available regarding how wildfire severity influences provisioning to bee offspring, which is...
This thesis describes a study of the synthesis, stereochemistry,
and reactivity of cobalt(III) cysteinato (CyS) and related thiolato complexes.
The preparation of [Co(en)₂CyS]⁺ resulted in a product solution
containing a mixture of diastereomers in the ratio 2.3:1 (Δ:A). The isomers were separated by ion exchange chromatography, and
their absolute configurations...
An investigation was made of the photoelectric emission from
sodium and the alteration in the emission produced by sulfur deposited
onto a sodium surface. Measurements were made at the temperature
of liquid nitrogen for photon energies between 2.0 ev and 4.5 ev. The
sodium was investigated in the form of...
The first part of this thesis describes a study of the
characteristics of oxidation of a 1:2 iron(III):thiolate system in
methanolic solution and in water. This system was investigated as a
potential analog for the cysteine- and cysteamine-dioxygenase catalyzed
0₂-oxidation of cysteine and cysteamine, respectively, to the
corresponding sulfinic acids....
Methods to improve the efficacy of swine barley rations were
evaluated. A literature review pertaining to the subject, three feeding
trials involving 104 swine, and a laboratory investigation were
used in the study.
The effects of pelleting with a new modified pellet die that
produces a dense pellet; supplementation with...
Part I describes the synthesis of bis(fac-S)((tris)2-aminoethanethiolatoiron( III))iron(III) chloride. The compound was first discovered during an attempt to prepare a ternary complex of iron, thiolate and pi-acid ligand. The compound is a reasonably air-stable iron(III)-thiolate that contains a linear tri-iron cluster with each iron bridged to the adjacent iron by...
In recent years, integrated circuit technology has
spawned the development of many low cost and high performance
microprocessors and microcontrollers. With these devices,
there is an increasing interest in the implementation of
distributed control networks, utilizing microprocessors in the
control nodes.
In this work, a low-cost liquid crystal display (LCD)...
The first asymmetric synthesis of (-)-7-epicylindrospermopsin via intramolecular nitrone cycloaddition is described. The synthesis utilized a convergent approach to prepare the cycloaddition precursor 176, which was assembled by condensation of hydroxylamine 175 with aldehyde 145. Hydroxylamine 175 was synthesized from ethylene glycol (166) in seven steps. Aldehyde 145 was completed...