Epitaxial LaRh₁/₂Mn₁/₂O₃ thin films have been grown on (001)-oriented LaAlO₃ and SrTiO₃ substrates using pulsed laser deposition. The optimized thin film samples are semiconducting and ferromagnetic with a Curie temperature close to 100 K, a coercive field of 1200 Oe, and a saturation magnetization of 1.7μB per formula unit. The...
The growth of YMn₀.₃₅In₀.₆₅O₃ thin films and their optical and magnetic behavior are reported. The YMn₀.₃₅In₀.₆₅O₃ thin film grows along the (0001) orientation with hexagonal structure similar to YMnO₃ on c-plane sapphire. The film shows paramagnetic behavior in the temperature range measured. The film exhibits a blue color due to...
Transition metal oxides are an important class of materials for the wide variety optical, electrical, dielectric, magnetic, and thermal properties observed. Their unique structure-property relationships allow for property tuning and often provide insight into the fundamentals of chemistry. The work in this thesis was focused on the design, synthesis and...
The crystal structure and multiferroic properties of single-phase (Bi₀.₉La₀.₁)FeO₃–Ba(Fe₀.₅Nb₀.₅)O₃ ceramics were investigated. The rhombohedral-type structure of 1.0(Bi₀.₉La₀.₁)FeO₃) was transformed to a monoclinic-type structure for the 0.5(Bi₀.₉La₀.₁)FeO₃–0.5Ba(Fe₀.₅Nb₀.₅)O₃) composition. It shows the coexistence of ferroelectricity and magnetism at room temperature, represented by a high dielectric constant with ferroelectric hysteresis and clear magnetic...
The electronic structure of the oxychalcogenides LaCuOSe and BiCuOSe has been studied using O K-edge x-ray emission spectroscopy, x-ray absorption spectroscopy, and density functional theory, in order to examine the effects of the M³⁺ ion configurations. The known distortion of the BiO layers in BiCuOSe compared to the LaO layers...
Transition metal oxides exhibit potential in various application fields due to the special d-electrons. Solid state chemistry focuses on discovering the structure-property relationships. The work in this thesis mainly discusses compounds with hexagonal or brownmillerite-type structure and their practical properties.
Hexagonal YIn[subscript 1-x]Fe[subscript x]O₃ (x = 0-0.3, 0.7-1.0) phases have...
Metal-oxides are very important in industrial applications such as thermal barrier coatings, corrosion protection, and heterogeneous catalysis. The wide variety of applications for metal-oxides are derived from the array of properties of metal-oxides. It is, therefore, important to understand and predict the conditions of synthesis and operation to optimize the...