Reaction of 4, 6-dimethoxy-5-nitropyrimidine [I], with refluxing
pyridine, was discovered to yield the methylpyridinium salt of
1, 6-dihydr -4-hydroxy-1-methyl-5-nitro-6-oxopyrimidine [III]. Possible
use of I as a general N-methylating agent was explored. No
appreciable reaction occurred between I and refluxing excess n-butyl
alcohol. Similar reaction involving quinoline failed to yield an...
The purpose of this project was to study the reactions of 1-(α-pyridyl)-3-buten-1-ol (compound I) and to determine whether or
not the products of some of its reactions are quinolizinium salts.
Reaction of compound I with bromine or iodine yields halide
salts (when no external cooling is applied) instead of the...
The relative rates of hydrogen atom abstraction from a series of 13 homoaryl
and heteroarylmethanes by the nucleophilic undecyl radical, thermally generated
from lauroyl peroxide, were determined at 70 °C. A reactivity range of 15 was
obtained. Substantial differences in reactivity among isomers were found. The
relative reactivities of the...