β-SiC is a semiconductor for high temperature devices, which exhibits several outstanding properties such as high thermal stability, good chemical stability and wide band gap. There is a possibility of fabricating a crack-free ultrathin SiC film on silicon wafers by pyrolysis of polymethylsilane (PMS) film.
This study looks into the...
Silicon carbide is an important and versatile nonoxide ceramic. Powder injection molding (PIM) is a method of high-speed fabrication of complex near-net shapes of SiC and other powders. Green micro-machining (GMM) is used to extend the shaping capability of green ceramics and powder metallurgy to smaller feature sizes. Debinding--removal of...
Nanostructured ceramics offer significant improvements in properties over the
corresponding materials with grain sizes on the order of tens to hundreds of microns.
Silicon carbide (SiC) is an important structural ceramic whose properties can
potentially be enhanced due to nanoscale microstructures. It has been suggested that
SiC samples with grain...
Combustive Synthesis or Self-Propagating High-Temperature
Synthesis (SHS), is an energy-efficient combustion
method of producing metallic, ceramic and composite
materials from their constituent powders.
This thesis presents the results of an experimental and
numerical evaluation of the propagation velocity for the SHS
solid-solid reaction of titanium and carbon, as well as...
An 89 mm-diameter vertical tubular-flow reactor was used to study the kinetics of nano-sized silicon nitride powder synthesis via the animonolysis of SiO vapor at temperatures ranging from 1300°C to 1400°C. The SiO generation rate was controlled by adjusting the mass of SiO particles initially charged in the SiO generator,...
Self-propagating high-temperature synthesis (SHS) is a new
method of producing advanced ceramic materials and offers an
attractive alternative to conventional methods of materials
processing.
An experimental investigation was carried out to determine
the SHS reaction wave propagation speed in a vertical cylindrical
compact made from a mixture of titanium and...
In a search for designed materials that mimic those found in biological systems, combining polymers with inorganic materials in sol-gel chemistry processes has gained momentum in the research world since the 1990's. This work methodically investigated the properties of several related polymer-SiO₂ hybrids prepared by a simple methodology that could...
Concentrically arranged multiple-tube reactors with different dimensions were
built for synthesizing nano-sized silicon nitride powder via the ammonolysis of SiO
vapor. The reaction was operated at temperatures ranging from 1350 to 1400°C and
pressure slightly above atmospheric pressure. Silicon monoxide (SiO) vapor was
generated by charging argon gas through a...