Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
The Cs-effect states Cs⁺ has more covalent character in bonding interactions than the lighter alkalis. It is exploited in organic synthesis and influences behavior in water, most notably radioactive ¹³⁷Cs in nuclear wastes or the environment. Niobium polyoxometalates (Nb-POMs) provide a unique opportunity to probe aqueous phase ion-pairing responsible for...
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Inorganic Chemistry
Distinctive Interactions of Cesium and Hexaniobate in
Water
DylanJ. Sures,[a] Sulata K
The Cs-effect states Cs⁺ has more covalent character in bonding interactions than the lighter alkalis. It is exploited in organic synthesis and influences behavior in water, most notably radioactive ¹³⁷Cs in nuclear wastes or the environment. Niobium polyoxometalates (Nb-POMs) provide a unique opportunity to probe aqueous phase ion-pairing responsible for...
Full Text:
. KGaA, 69451 Weinheim, 2016
Distinctive Interactions of Cesium and Hexaniobate in
Water
DylanJ. Sures
The Cs-effect states Cs⁺ has more covalent character in bonding interactions than the lighter alkalis. It is exploited in organic synthesis and influences behavior in water, most notably radioactive ¹³⁷Cs in nuclear wastes or the environment. Niobium polyoxometalates (Nb-POMs) provide a unique opportunity to probe aqueous phase ion-pairing responsible for...
Ion pairs and solubility related to ion-pairing in water influence many processes in nature and in synthesis including efficient drug delivery, contaminant transport in the environment, and self-assembly of materials in water. Ion pairs are difficult to observe spectroscopically because they generally do not persist unless extreme solution conditions are...
Eight years (1994-2000) of data from the TOPEX/Poseidon satellite altimeter
are used to investigate the variability of the sea surface height and geostrophic
velocity of the California Current system. The TOPEX/Posiedon satellite measures
SSH along an exact-repeat set of groundtracks with a 10-day repeat cycle.
In the domain studied here...
Published May 1977. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
Lead zirconate titanate (PZT) is well known to exhibit some of the strongest piezoelectric responses, explaining why it is at the heart of piezoelectric-based microelectromechanical systems (MEMS) research. The use of pulsed laser deposition (PLD) to synthesize PZT offers many advantages over alternative deposition techniques, mainly regarding its ability to...
Most data are associated with a place, and many are also associated with a moment in time, a time interval, or another linked temporal component. Spatiotemporal data (i.e., data with elements of both space and time) can be used to assess movement or change over time in a particular location,...
Time-dependent crack growth mechanisms in Alloy 617 at 800°C in air were studied using compact tension samples machined in the L-T direction, cracked at temperature using an induction furnace and servo-hydraulic load frame. The application of different loading waveforms, including triangular, hold time, and sustained loading, were studied with relation...