Hydrogen abstraction from substituted t-butylbenzenes

Graduate Thesis Or Dissertation

Público Deposited

Citeable URL: https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/kk91fp006

Descriptions

Attribute Name	Values
Creator	Harvey, Robert Louis
Abstract	A study of the relative rates of the alkyl hydrogen abstraction from a series of meta and para substituted t-butylbenzenes by the chlorine atom at 70°C has been carried out. Application of the Hammett equation yielded a ρ value of -0.44 for the para compounds. Possible explanations for the non-linearity of the meta compounds are offered. Application of the Kirkwood-Westheimer field-effect model for the transmission of substituent effects provides an excellent correlation with the observed relative rate constants.
Resource Type	Masters Thesis
Fecha Disponible	2014-04-02T22:22:09+00:00
Fecha de Emisión	1968-12-23
Degree Level	Master's
Degree Name	Master of Science (M.S.)
Degree Field	Chemistry
Degree Grantor	Oregon State University
Commencement Year	1969
Advisor	Gleicher, Gerald Jay
Academic Affiliation	Chemistry
Non-Academic Affiliation	Oregon State University. Graduate School
Subject	Hydrogen
Declaración de derechos	Copyright Not Evaluated
Publisher	Oregon State University
Peer Reviewed	No
Language	English [eng]
Digitization Specifications	File scanned at 300 ppi using ScandAll PRO 1.8.1 on a Fi-6770A in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
Replaces	http://hdl.handle.net/1957/46998

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