Index Catalog // ScholarsArchive@OSU

Reversible Covalent Binding of Desferrioxamine B (DFOB) to 2 Polystyrene Microspheres for the Chelation of Aqueous Iron Citrate

Creator:: Touma, Jad G., Kelly, Christine, Coblyn, Matthew, Jovanovic, Goran N., and Schilke, Kate
Abstract:: Desferrioxamine B (DFOB) was reversibly and covalently conjugated to polystyrene microspheres via N-succinimidyl 3-(2-pyridyldithio)propionate (SPDP) crosslinker. DFOB retained post-immobilization activity with at least 89% able to bind Fe(III)-citrate under pH 7.4 and a citrate:iron molar ratio = 100:1. Comparing iron capture by DFOB-activated beads and sulfhydryl (−SH) control beads demonstrated...
Resource Type:: Article
Full Text:: Cite This: https://doi.org/10.1021/acs.iecr.3c00812 Read Online ACCESS Metrics & More Article

Data-driven imputation of miscibility of aqueous solutions via graph-regularized logistic matrix factorization

Creator:: Behnoudfar, Diba, Simon, Cory M., and Schrier, Joshua
Abstract:: Aqueous, two-phase systems (ATPSs) may form upon mixing two solutions of independently water-soluble compounds. Many separation, purification, and extraction processes rely on ATPSs. Predicting the miscibility of solutions can accelerate and reduce the cost of the discovery of new ATPSs for these applications. Whereas previous machine learning approaches to ATPS...
Resource Type:: Article
Full Text:: NdFeB magnets. Ind. Eng. Chem. Res. 2018, 57, 16934–16943, DOI: 10.1021/acs.iecr.8b04549. (10) Sunder

Intensification of Solvent Extraction in an Additively Manufactured Microfluidic Separator

Creator:: Touma, Jad George, Coblyn, Matthew, Freiberg, Lucas Joseph, Kowall, Cliff, Zoebelein, Avaline, and Jovanovic, Goran Nadezda
Abstract:: Solvent extraction is an integral chemical and biochemical separation process that is drastically intensified in microfluidic systems. A novel high-throughput micro-separator was additively manufactured for the intensification of liquid–liquid separation. The micro-posts array within the flow plate generated a capillary pressure gradient on the non-wetting organic phase, enabling continuous, membrane-free,...
Resource Type:: Article

Controlling the Co-Precipitation of Colloidal PbSe Quantum Dots and Their Device Performance in a Diode Architecture

Creator:: McCrea, Tyler D.
Abstract:: In this work, colloidal PbSe quantum dots (QDs) are shown to be synthesized in a controlled manner by changing the growth time and reaction temperature in a microwave synthesis method. It is explained why quantum dots make such a unique material to create electronic devices and the specific benefits that...
Resource Type:: Masters Thesis

Addressing the Risks of Nanoscale Polymers: Exposure, Behavior, and Toxicity

Creator:: Stine, Jared
Abstract:: Nanoscale polymers (including nanoplastics) are widely present through commerce and make their way into the environment. As the improper disposal of plastic waste leads to continued accumulation and degradation of plastic pollution, the presence of plastic particles less than 1 micron (μm) in size (nanoplastics) will increase. Heightened concern over...
Resource Type:: Dissertation

Fundamental Investigations of Electrocatalysis: Mechanistic Implications of Catalyst Electronic Structure

Creator:: Carvalho, O. Quinn
Abstract:: Heterogeneous catalysis modulates the rate and selectivity of reaction processes by stabilizing a series of intermediate states on solid surfaces, facilitating the production of many commodity chemicals modern society relies upon. Conventional, thermal catalytic processes—conducted at elevated temperatures and pressures—source thermal, mechanical, and chemical potential energy from carbon-hydrogen bonds— combustion...
Resource Type:: Dissertation

Transformation of Carbon Tetrachloride and Chloroform by Trichloroethene Respiring Anaerobic Mixed Cultures and Supernatant

Creator:: Vickstrom, Kyle E.
Abstract:: Carbon tetrachloride (CT) and chloroform (CF) were transformed in batch reactor experiments conducted with anaerobic dechlorinating cultures and supernatant (ADC+S) harvested from continuous flow reactors. The Evanite (EV-5L) and Victoria/Stanford (VS-5L) cultures capable of respiring trichloroethene (TCE), 1,2-cis-dichloroethene (cDCE), and vinyl chloride (VC) to ethene (ETH) were grown in continuous...
Resource Type:: Masters Thesis

Investigating the Hemocompatibility of Blood-Contacting Biomaterials

Creator:: Hummel, Madeleine H.
Abstract:: Surface-associated thrombosis is a critical concern in medical device development. Current extracorporeal circulation units require systemic anticoagulation to avoid thrombosis, which can cause adverse effects such as thrombocytopenia, hypertriglyceridemia, and hyperkalemia. To address this issue, we combine the technology of polydopamine (PDA) functionalization with slippery liquid infused porous surfaces (SLIPS)....
Resource Type:: Masters Thesis
Full Text:: ,” Biomacromolecules, vol. 10, no. 10, pp. 2809–2816, Oct. 2009, doi: 10.1021/bm9006503. 18. Y. Chang, W.-J. Chang

A Graph Grammar Representation of Metal-Organic Frameworks for Computational Synthesis and Exploration

Creator:: Geringer, Mark K.
Abstract:: In this work, metal-organic frameworks (MOFs) are computationally represented, generated, and evaluated. The organic linker molecules are represented as graphs and use graph grammars where the atoms are represented by nodes and the bonds are represented by arcs. The grammar rules that dictate the graph generation process work on the...
Resource Type:: Masters Thesis

Exploring Colloid Transport in Unsaturated Porous Media Using X-Ray Microtomography

Creator:: Brueck, Chris L.
Abstract:: Understanding the mechanisms controlling colloid transport and deposition in the vadose zone is an important step in protecting our water resources. Colloid transport in unsaturated porous media was studied using X-Ray Microtomography (XMT), which is a non-destructive imaging technique that provides three-dimensional images at a resolution on the order of...
Resource Type:: Masters Thesis

ScholarsArchive@OSU

Reversible Covalent Binding of Desferrioxamine B (DFOB) to 2 Polystyrene Microspheres for the Chelation of Aqueous Iron Citrate

Data-driven imputation of miscibility of aqueous solutions via graph-regularized logistic matrix factorization

Intensification of Solvent Extraction in an Additively Manufactured Microfluidic Separator

Controlling the Co-Precipitation of Colloidal PbSe Quantum Dots and Their Device Performance in a Diode Architecture

Addressing the Risks of Nanoscale Polymers: Exposure, Behavior, and Toxicity

Fundamental Investigations of Electrocatalysis: Mechanistic Implications of Catalyst Electronic Structure

Transformation of Carbon Tetrachloride and Chloroform by Trichloroethene Respiring Anaerobic Mixed Cultures and Supernatant

Investigating the Hemocompatibility of Blood-Contacting Biomaterials

A Graph Grammar Representation of Metal-Organic Frameworks for Computational Synthesis and Exploration

Exploring Colloid Transport in Unsaturated Porous Media Using X-Ray Microtomography

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