Index Catalog // ScholarsArchive@OSU

Electrochemical studies of liquid chlorocuprates(I)

Creator:: Silkey, James R.
Abstract:: This research emphasized fundamental physical and electrochemical studies of systems based on the room temperature fused salt, triethyl-ammonium dichlorocuprate(I). Such systems, which must be maintained under a protective atmosphere, were also used in some preliminary battery studies. Spectra of dark green solutions of copper (II) chloride in triethylammonium dichlorocuprate(I) obey...
Resource Type:: Masters Thesis
Full Text:: typical of chlorocuprate(II) complexes. No special behavior due to intervalence transfer absorption is

Comparison between lichen, conifer needles, resin-based passive air sampling devices (PASDs), and snow to monitor semi-volatile organic compounds (SOCs) in the atmosphere

Creator:: Schrlau, Jill E.
Abstract:: The purpose of this research was to compare four different media that were used to monitor SOC atmospheric concentrations in remote ecosystems. The accumulation of semi-volatile organic compounds, including pesticides, polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), was investigated in lichen, 2-year old conifer needles, resin-based passive air sampling...
Resource Type:: Masters Thesis
Full Text:: needles, PASDs, and snow were collected (82, 85, 33, and 30 sites, respectively). These SOC physical

The biosynthetic precursor of ethylene in Penicillium digitatum Saccardo

Creator:: Jacobsen, Donald Weldon
Abstract:: An attempt has been made to elucidate the biosynthetic precursor of ethylene in the mold P. digitatum. By application of basic radiotracer methodology and the utilization of several specifically labeled radiochemical substrates, it has been possible to demonstrate that the internal carbon atoms of C-4 dicarboxylic acids such as succinate,...
Resource Type:: Masters Thesis
Full Text:: radiochernical substrates, it has been possible to dernon- strate that the internal carbon atorns of. C-4

Low-Dose X-Ray Radiation Effects On the Proteomic Profiles of Hippocampus, Cortex, and Cerebellum of Contextual Fear Conditioning and Novel Object Recognition Trained Mice

Creator:: Koluda, Rony
Abstract:: Radiation exposure to the brain can occur from a variety of events, including space missions, nuclear accidents, and clinical treatments. The effects of high dose radiation are well studied, but those of lower dosage are more elusive. Decline of memory and cognition is observed in patients exposed to low dose...
Resource Type:: Masters Thesis
Full Text:: in contextual fear memory, while no effect is seen on novel object recognition. Mass spectrometric

Synthesis of polybenzimidazoles from monomers containing flexible linkages

Creator:: Azmus, Dora J. Taylor
Abstract:: Polybenzimidazoles were synthesized from 3, 3', 4, 4'-tetraminobiphenyl (diaminobenzidine, or DAB) with orthoesters, carboxylic acid derivatives (an ester and an acid) and with m-benzenedialdehyde. The products were of low molecular weight, as evidenced by low inherent viscosity, except in the case of the dialdehyde plus DAB. The product of that...
Resource Type:: Masters Thesis
Full Text:: internal sulfonate linkages, which were intended to increase the flexibility of the target

The infrared and far-infrared spectra of sublimed films of formaldehyde

Creator:: Held, Andrew Mackie
Abstract:: The infrared spectra of liquid and solid films of formaldehyde were taken over the range of 35 to 4,000 cm⁻¹ using Beckman IR 7 and IR 11 spectrometers. A new overtone band and a new combination band were found as well as three fundamental peaks due to lattice vibrations and...
Resource Type:: Masters Thesis
Full Text:: internal and external modes of vibration. The peak at 180-195 cm-1 is very strong and appears to be due

Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Creator:: Tilton, Mary Lehman
Abstract:: Isomerically pure cis,cis,trans-1-pheny1-1,3,5- heptatriene was prepared and cyclized. Ring closure was followed by a 1,5 hydrogen shift, and the only product observed was 1-phenyl -6-methyl -1,3-cyclohexadiene. Rough first order rate constants for thermolysis and the hydrogen shift were determined. Kinetic estimates indicate that the report of disallowed product in a...
Resource Type:: Masters Thesis
Full Text:: thermolysis and the hydrogen shift were determined. Kinetic estimates indicate that the report of disallowed

Towards the Perfect Marriage Between Theory and Experiments in Drug Discovery and Synthesis : Insights into Structure Determination of Complex Natural Products and Mechanistic Understandings of Lactam Synthesis

Creator:: Snyder, Kevin M.
Abstract:: In this report, three studies are presented that aid in the development of drug discovery and their synthesis. In each, the importance of the marriage between computations and experiments is highlighted. Continued efforts in this vein are essential for future efforts towards improving human health. The first case study investigated...
Resource Type:: Masters Thesis
Full Text:: -Yeon Cheong In this report, three studies are presented that aid in the development of drug

Electrochemistry at a reticulated vitreous carbon flow electrode

Creator:: Fahey, Jefferson Vincent
Abstract:: The electrochemistry of cadmium at a Reticulated Vitreous Carbon (RVC) electrode has been studied to determine the suitability of RVC as a working electrode for the electrochemical preconcentration of cadmium in the corrosive environment of zirconium dissolved in hydrofluoric acid. The electrochemistry in this investigation deals with deposition of solid...
Resource Type:: Masters Thesis
Full Text:: nucleation and no over potential effects. Cadmium, however, has a significant nucleation over potential at

Using Computational Methods to Elucidate Reaction Mechanisms for Copper Catalyzed Reactions

Creator:: Caspary, Katherine E.
Abstract:: In this report, two studies are presented that utilize computations to predict and elucidate the reaction mechanisms of two different copper catalyzed reactions. Each study provides insight into the various chemical transformations, as well as the how and why behind regioselectivity and isotopic selectivity. The importance of this research is...
Resource Type:: Masters Thesis
Full Text:: report, two studies are presented that utilize computations to predict and elucidate the reaction

ScholarsArchive@OSU

Electrochemical studies of liquid chlorocuprates(I)

Comparison between lichen, conifer needles, resin-based passive air sampling devices (PASDs), and snow to monitor semi-volatile organic compounds (SOCs) in the atmosphere

The biosynthetic precursor of ethylene in Penicillium digitatum Saccardo

Low-Dose X-Ray Radiation Effects On the Proteomic Profiles of Hippocampus, Cortex, and Cerebellum of Contextual Fear Conditioning and Novel Object Recognition Trained Mice

Synthesis of polybenzimidazoles from monomers containing flexible linkages

The infrared and far-infrared spectra of sublimed films of formaldehyde

Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Towards the Perfect Marriage Between Theory and Experiments in Drug Discovery and Synthesis : Insights into Structure Determination of Complex Natural Products and Mechanistic Understandings of Lactam Synthesis

Electrochemistry at a reticulated vitreous carbon flow electrode

Using Computational Methods to Elucidate Reaction Mechanisms for Copper Catalyzed Reactions

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