Index Catalog // ScholarsArchive@OSU

A micro study of the reduction of organic hydroxyl compounds with hydriodic acid

Creator:: Mitchell, Herschel K.
Resource Type:: Masters Thesis
Full Text:: Present Found Reduction Substitution Detrnns. Tertiary Amyl Ale- ohol 100°C. .70 0. .70 2 134° J

Spectrophotometry of molybdenum, tungsten and chromium chelates of quercetin

Creator:: Mitchell, Lloyd James
Abstract:: Quercetin (3, 3', 4', 5, 7-pentahydroxyflavone) reacts with hexavalent molybdenum, tungsten and chromium to form chelates soluble in an ethanol-water medium. This color reaction has been investigated with a view to its possible application in the spectrophotometric determination of trace amounts of these metals. In the development of the method,...
Resource Type:: Dissertation
Full Text:: chelates of quercetin AN ABSTRACT OF THE THESIS OF Lloyd James Mitchell for the Ph. D. in Analytical

The metabolism of C¹⁴ labeled 2, 4-dichlorophenoxyacetic acid in bean plants

Creator:: Jaworski, Ernest George
Resource Type:: Dissertation
Full Text:: . Mitchell, J. · • and J. • Brown. Movement of 2,4 dicblorophenoxyacetlc acid stimulus and its relation to

Chiral synthesis of monic acid C

Creator:: Theramongkol, Parinya
Abstract:: Bromoalkoxylation of dihydropyran with bromine and 1-borneol, followed by dehydrobromination and epoxidation, afforded trans-2-1- bornyloxy-3,4-epoxytetrahydropyran as a major product. This was treated with sodium phenylselenide to give a 1:1 mixture of (2R,3R,4R)- 2-1-bornyloxy-3-hydroxy-4-phenylselenotetrahydropyran and its (2S,3S, 4S) diastereomer. Elimination of the selenoxide, derived from oxidation of the former with hydrogen...
Resource Type:: Dissertation
Full Text:: d,e,f,g Se Ph Bn0 0 --OBn 18 b,c i,j,k 21 ( R = SiPh2t-Bu ) 19 15 10 Reagents: a) PhSeCl

The synthesis of 2-C¹⁴ labeled DDT

Creator:: Buhler, Donald Raymond
Resource Type:: Masters Thesis
Full Text:: The synthesis of 2-C¹⁴ labeled DDT THE SYNTHESIS OF 2

Preparation of C-14 labeled isopropyl phenylcarbamate

Creator:: Murray, Joseph
Resource Type:: Masters Thesis
Full Text:: degrees C. for a period J-o of fifteen minutes (2, pp 402-403). The acetone was renioved by vacuu

Comprehensive, Low-Cost Wicking Microfluidic Analytical Devices for Clinical Diagnostics and Environmental Analysis

Creator:: Bandara, Gayan C.
Abstract:: Analytical techniques are utilized in a wide variety of applications. Traditionally, analytical measurements are achieved by trained personnel in a laboratory setting using expensive scientific instruments, which limits their applicability in resource-limited areas and point-of-care applications. Therefore, the concept of enabling these laboratory-based qualitative and quantitative assays in microfluidic device...
Resource Type:: Dissertation
Full Text:: . He is the co-first author of the one publication related to the work in Chapter 3. David J. Bemis

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Creator:: Erickson, Blake Alexander, Ju, X., Nibler, Joesph W., Beaudry, C. M., and Blake, T. A.
Abstract:: Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
Resource Type:: Article
Full Text:: . Staroverov, T. Keith, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar

Thermodynamics of hydrazine in aqueous solution at 25⁰ C

Creator:: Bushnell, Vernon Clifford
Resource Type:: Masters Thesis
Full Text:: »?Iel ______ I -- II 1 J lb o- -Faiil-, hok C ; I t ______ p- - -k TOP ASSEH8Y

Mechanistic studies on Re(V) mediated C-O bond transformations

Creator:: Zhuravlev, Fedor
Abstract:: In situ, reduction of Cp*ReO₃ by PPh₃ to form (Cp*ReO)₂(μ-O)₂ allows catalytic deoxygenation of epoxides, however, conproportionation between Reⱽ and Reⱽᴵᴵ species to form clusters of ((Cp*Re)₃(μ-O)₆}²⁺(ReO₄⁻)2 and new compound {(Cp*Re)₃(μ²-O)₃(μ³-O⁾³ReO₃}⁺(ReO₄⁻) leads to removal of rhenium from the catalytic cycle and loss of activity, The epoxide deoxygenation mediated by (Cp*ReO)₂(μ-O)₂...
Resource Type:: Dissertation
Full Text:: -1 12°C); the following cycloreversion leads to a formation of Cp*Re03 and alkene, Primary 1 3c and

High resolution spectroscopy of BeB₂H₈ and C₂H₆

Creator:: Al-Kahtani, Abdullah A.
Resource Type:: Masters Thesis
Full Text:: High resolution spectroscopy of BeB₂H₈ and C₂H₆ AN

Preparation and decomposition of C-14 labeled Mannich base

Creator:: Dorward, Donald Lyle
Resource Type:: Masters Thesis
Full Text:: Mennich ReìctionN, Journe1 of Organic Chemistry, j}4, 1001-12 (l949) 7. Mannich, C, end Dannehl, M

A synthesis of 6-n-propyl-7-methyltetralin-5-C¹⁴

Creator:: Odell, Norman Raymond
Resource Type:: Dissertation
Full Text:: . SYNTHESIS OF 146-n- PROPYL-7-.M.ETBYLTETRALIN- 5- C by NORMAN RAYMOND ODELL A THESIS submitted 'Lo

The synthesis of C¹⁴ labellel 2,4-dichlorophenoxyacetic acid

Creator:: Jaworski, Ernest George
Resource Type:: Masters Thesis
Full Text:: þÿ THE SYNTIIE$IS OP C LABELLED 2, 4-DICI LOROi

The formation of radioactive lysine and histidine from CH₃C¹⁴OOH and CH₃C¹⁴O COOH in yeast

Creator:: Davis, James Wendell
Resource Type:: Masters Thesis
Full Text:: . 3prinEfield, Illinois, Charles C. Thomas, 1951. 576 p. 3. Borsook, Henry, Clara Deasy, A. J. Haagen-mit

Infrared investigation of some ferroelectric and related compounds : NH₄NCS, (NH₄)₂SO₄, RbHSO₄, and NH₄HSO₄

Creator:: Oden, L. L. (Laurance L.)
Abstract:: At liquid nitrogen temperature the spectra of sublimed films of NH₄NCS, both as phase I (the usual form stable at room temperature) and phase II (the low temperature form), exhibit detail usually reserved for gases at low pressures. In both phases the symmetry of ammonium ion has degenerated from tetrahedral...
Resource Type:: Dissertation
Full Text:: conductance of this work is gladly shared with Professor J. C. Decius, Dr. R. K. Khanna, and with my many

The infrared spectrum of the nitrate ion in various crystalline environments

Creator:: Stewart, Julie Lingscheid
Abstract:: The infrared absorption spectra in the out-of-plane bending (v₂) region of potassium nitrate were studied for three phases. Several types of sampled were used: nujol mulls, fused samples, and N¹⁴-N¹⁵ isotopic mixtures. The existence of three of the reported polymorphic phases was confirmed by the spectra. The transitions between phase...
Resource Type:: Masters Thesis
Full Text:: in alkali halide lattices. Journal of Chemical Physics 37:1069-1077. 1962. -15 4. Decius, J. C. m

Application of the least squares criterion to the determination of molecular compliance constants

Creator:: Ottinger, Robert Stanley
Abstract:: The development of a least squares model for the determination of compliance constants from various combinations of vibration frequency, mean square amplitudes of vibration and centrifugal distortion data is discussed. The resultant model is applied to frequency and mean square amplitude data for NO₂ and N₂O₄ and to frequency and...
Resource Type:: Dissertation
Full Text:: Cross (23,102 -145) may be applied just by writing C for F and K for G . S = US . .. . J

Hyperpolarizability and forbidden Raman lines

Creator:: Rauch, John Edward
Resource Type:: Masters Thesis
Full Text:: presented Typed by Mrs. V. L 1iite, Jr. This thesis is dI«t.d to Profossai J. C. Decius whose

Integrated intensities of carbon dioxide in Nujol solutions

Creator:: Hofeldt, Robert Herman
Abstract:: The ratio of the absolute infrared intensity, A₃/A₂, for the parallel mode (2336 cm⁻¹) and the perpendicular mode (658 cm⁻¹) of a nonpolar solute molecule, carbon dioxide, has been determined in a nonpolar solvent, Nujol. The solution ratio (5.0) which has been extrapolated to zero concentration is less than the...
Resource Type:: Masters Thesis
Full Text:: sincere gratitude to Professor J. C. Decius. I have been most fortunale to have been granted the

Vibrational relaxation time studies on carbon monoxide by the infrared spectrophone method

Creator:: Jones, Walter Denny
Resource Type:: Dissertation
Full Text:: ACKNOILEDG .f To Dr. J. C. Decius I extend my deepest gratitude. He hs been considerbiy more thin . very

The rotational motion of molecules in crystalline solids

Creator:: Miller, R. E.
Abstract:: Theoretical studies and experimental results are presented for the rotational motion of molecule's in crystalline solids. The group theory is solved for molecules of any symmetry matrix isolated at a site in a crystal field of any symmetry. As the potential terrier to rotation of the molecule relative to the...
Resource Type:: Dissertation
Full Text:: Molecules in Crystalline Solids Abstract approved s Redacted for privacy Professor J. C. Decius

A study of the infrared intensities of some small molecular anions

Creator:: Pastorek, Christine
Resource Type:: Dissertation
Full Text:: Privacy 1 Dr. J. C. Decius In infrared reflectance experiments with single crystals, we have measured

Spectral investigation of the molecular vibration region of single crystalline potassium sulfate

Creator:: Meserole, F. B.
Abstract:: A spectral investigation of the molecular vibration region of the potassium sulfate crystal system was undertaken. This study was initiated to establish the feasibility of using this crystal as a host matrix for ammonium sulfate. Since these two systems are isomorphic and have unit cells of nearly equal volume the...
Resource Type:: Dissertation
Full Text:: POTASSIUM SULFATE Abstract approved: Redacted for privacy J. C. Decius A spectral investigation of the

The infrared absorption of phthalocyanine and related compounds

Creator:: Karasek, Francis W., 1919-
Resource Type:: Dissertation
Full Text:: to produce • E • (v + ~) h c Wo -t and use of the selection rules governing J and v transitions

Vibrational relaxation phenomena in triatomic gases

Creator:: Montan, Donald Noel
Resource Type:: Dissertation
Full Text:: / Typed by Lilah N. otter À CKNOLEDGNENT I wish to thank .ûr. J. C. .Decius for the help, advice

Molecular intensity parameters in the solid state

Creator:: Fredrickson, Larry R.
Resource Type:: Dissertation
Full Text:: : Redacted for privacy / J. C. Decius Theoretical and experimental results are presented for calcu- lation

The vibrational spectrum of polyoxymethylene

Creator:: Snyder, Robert Gene
Resource Type:: Dissertation
Full Text:: . Page 23 27 k8 52 55 58 7k ACKNOWLEDGEMENT The author wishes to thank Dr. J. C

The infrared spectrum of porphin

Creator:: Nelson, Harry Martin
Resource Type:: Dissertation
Full Text:: wishes to express his thanks to Professor J. c. Decius f'or advice and en couragement tendered

A spectrophone study of vibrational relaxation in methane

Creator:: Breshears, Wilbert Dale
Abstract:: The spectrophone method for the study of vibrational relaxation has been claimed to possess a distinct advantage over the more commonly used ultrasonic techniques in that it permits the relaxation of the various infrared-active vibrational modes in a polyatomic molecule to be studied separately. A discussion of the rate equations...
Resource Type:: Dissertation
Full Text:: Typed by Marion F. Palmateer /7, ACKNOWLEDGMENT I wish to express my gratitude to Dr. J. C

Optical diffraction study of ultrasonic sound velocity in nitrous oxide and ammonia gases

Creator:: Strauch, Joseph George
Abstract:: The velocity of sound in gases was measured, using an ultrasonic wave train as a diffraction grating. The fundamental problems involved in the optical technique are discussed. An apparatus utilizing an objective lens of focal length 1.5 m and aperture f/20 was constructed and used at an ultrasonic frequency close...
Resource Type:: Dissertation
Full Text:: , Dr. J. N. Gayles, Jr. , Dr. Joseph V. Martinez, and Mr. C. V. Woods. Finally I wish to thank my

Absolute infrared intensities of the cyanate ion in KC1, KBr and KI lattice environment

Creator:: Seshadri, Kalkunte Srinivasa Iyengar
Resource Type:: Dissertation
Full Text:: * at yr r ) l*,, I r, nf ,- tt, f l+r, [ firr^fw acnJr J +n, E 4!8. o(n 'f f f 4,'' Fs{'' {c,TT

The dipole moment of trioxane vapor

Creator:: Turrell, George Charles
Resource Type:: Masters Thesis
Full Text:: express his sincere appre ciation to Dr. J .. c. Decius for h1s helpful advice and encouragement

The infrared spectrum of cyanate ion in different environments

Creator:: Maki, Arthur G.
Resource Type:: Dissertation
Full Text:: , namely: rl/1:Q£· Q_ja.1/4, d., ==- o l;t-J f 1/C Q:· l/£r d_ T = 0 r1Vv-~Qi Qj 91(1/{,. d.?" === 0

A theoretical study of vibrational relaxation in gaseous ammonia

Creator:: Starr, Duane Frank
Resource Type:: Dissertation
Full Text:: approved: 7 J. C. Decius By means of simple collision models, we have tested the hypothesis that the

Vibrational and reorientational lifetimes in liquids determined by Raman spectroscopy

Creator:: Morgan, Larry G.
Abstract:: Studies of anisotropic and isotropic Raman line shape yield information about the rotational motion (rotational correlation function) and non-reorientational (vibrational) lifetimes. The rotational motion of carbon disulfide has been studied previously by the techniques of Raman spectroscopy (6, 43), Rayleigh scattering (43, 46) and direct measurement (47). This work was...
Resource Type:: Dissertation
Full Text:: , Manager, Applied Chemistry Section. Special recognition is due Dr. J. C. Decius who has acted as my

Integrated intensities of methyl iodide in carbon tetrachloride solution and correction of slit error

Creator:: Khidir, Abdul Latif
Resource Type:: Dissertation
Full Text:: sincere gratitude to Professor J. C. Decius whose guidance and help has been an inspiration to me

Absolute intensity of the bending mode of chloroform in n-hexane

Creator:: Singh, Surendra Khatry
Resource Type:: Masters Thesis
Full Text:: ,~'J' is the ad• sorption coefficient tor the trequenc7 '{ • c is the con• cent.ratipn ot the

Ultrasonic dispersion in gaseous allene, ammonia and carbon suboxide observed by optical diffraction

Creator:: Hancock, James Kent
Resource Type:: Dissertation
Full Text:: OPTICAL DIFFRAC- TION Abstract approved Redacted for privacy J. C. Decius Experimental sound

I. Infrared spectra of solid solutions in alkali halide crystals [and] Method for obtaining minimal kinematically complete sets of internal coordinates

Creator:: Conant, Donald Robertson
Abstract:: A study was made of the infrared absorption spectrum for cyanate ion in KCl and KBr host lattices containing small amounts of calcium or barium ion. Both pellets and single crystals were scanned during the course of this study. The spectra of the barium or calcium doped crystals contained many...
Resource Type:: Dissertation
Full Text:: presented May 15, 1963 Typed by Nancy Kerley ACKNOWLEDGMENT I would especially like to thank Dr. J

The infrared and far-infrared spectra of sublimed films of formaldehyde

Creator:: Held, Andrew Mackie
Abstract:: The infrared spectra of liquid and solid films of formaldehyde were taken over the range of 35 to 4,000 cm⁻¹ using Beckman IR 7 and IR 11 spectrometers. A new overtone band and a new combination band were found as well as three fundamental peaks due to lattice vibrations and...
Resource Type:: Masters Thesis
Full Text:: SUBLIMED FILMS OF FORMALDEHYDE Redacted for Privacy Abstract approved: )6r. J. C. Decius The infrared

The infrared absorption and force constants of the borate ion

Creator:: Steele, Warren Cavanaugh
Resource Type:: Dissertation
Full Text:: wishes to express his sin- cere grstitude to Dr. J. C. Decius for his ercoursgement, inspirrtion md

Infrared absorption and force constants of the isotopic nitrate ions, N¹⁴O₃- and N¹⁵O₃-

Creator:: Inami, Yonemaru Harry
Resource Type:: Masters Thesis
Full Text:: inverso kinetic energy matrix elements in acyclic molecules has been worked out by J. C. Dodus. of

The infrared absorption of some hydrazine monohalides

Creator:: Pearson, David Petri
Resource Type:: Masters Thesis
Full Text:: his appreciation tor the guidance and inspiration reoe1Te4 troa Dr. J. c. Deo1us during the

Studies of ultrasonic dispersion in gases by the diffraction of light

Creator:: Martinez, Joseph Vergara
Resource Type:: Dissertation
Full Text:: author expresses his deep gratitude and sincere appreciation due Dr. J. C. Decius in extending his

Lattice effects of lithium hydroxide : isotopic effects and factor group analysis

Creator:: Lilley, Suetta Albin
Abstract:: The infrared absorption spectrum from 3200 cm⁻¹ to 4025 cm⁻¹ of thin crystals of ⁶LiOH (99%⁶Li.) is presented and compared to the spectrum of [superscript]NLiOH (93%⁷Li). A shift in only one of the band pairs supports the lattice combinations model and assists in making assignments for the major features of...
Resource Type:: Masters Thesis
Full Text:: Privacy J. C. Decius The infrared absorption spectrum from 3200 cm-1 to 4025 cm-1 of thin crystals of

A variable frequency spectrophone study of carbon monoxide

Creator:: Woodmansee, Wayne Earl
Resource Type:: Dissertation
Full Text:: Lilah N. Potter ACKNOWLEDGNN T I would like to extend to Dr. J. C. Uecius my thanks for his

Determination of the vibrational lifetime of carbon monoxide by the spectrophone method

Creator:: Turrell, George Charles
Resource Type:: Dissertation
Full Text:: Evelyn Kanzelnieyer ACOWLDGiENT I would like to express my apprecia- tion to .L)r. J. C. uecius

Infrared, reflection and Raman spectra of sodium and potassium biflouride

Creator:: Cooke, Rodney Dean
Resource Type:: Dissertation
Full Text:: ACKNOWLEDGEMENTS First I wish to express my gratitude to Dr. J. C. Decius for his assistance and inspiration in

Infrared and Raman spectra of solid phosphine

Creator:: Huang, Tzer-hsiang
Resource Type:: Dissertation
Full Text:: approved: Redacted for privacy jDr. J. C. Decius, The IR spectra of the liquid and the of phases of PH3

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