Index Catalog // ScholarsArchive@OSU

Protein Adducts of Aldehydic Lipid Peroxidation Products: Identification and Characterization of Protein Adducts Using an Aldehyde/Keto Reactive Probe in Combination with Mass Spectrometry

Creator:: Maier, Claudia S., Chavez, Juan, Wang, Jing, and Wu, Jianyong
Abstract:: This chapter describes a mass spectrometry-based strategy that facilitates the unambiguous identification and characterization of proteins modified by lipid peroxidation-derived 2-alkenals. The approach employs a biotinylated hydroxyl amine derivative as an aldehyde/keto reactive probe in conjunction with selective enrichment and tandem mass spectrometric analysis. Methodological details are given for model...
Resource Type:: Part of Book
Full Text:: find some applicability in the area of oxidative stress insults by metal-catalyzed oxidations

Synthetic studies on alkaloids : part I, an approach toward the synthesis of (̳+)-koumine : part II, an approach toward the synthesis of (̳+)-morphine

Creator:: Stappenbeck, Frank
Resource Type:: Dissertation
Full Text:: submitted to Oregon State University in partial fulfillment of the requirements for the degree of Doctor

The Electrochemical Synthesis of the Graphite Intercalation Compounds Containing Tetra-n-alkylammonium Cations

Creator:: Sirisaksoontorn, Weekit and Lerner, Michael M.
Abstract:: The electrochemical intercalation of tetra-n-alkylammonium (TAA) cations into graphite is investigated using galvanostatic reduction and cyclic voltammetry in TAABr/ dimethylsulfoxide (DMSO) electrolytes. Structural and compositional analyzes by X-ray diffraction, thermogravimetric and elemental analyzes show that stable graphite intercalation compounds (GICs) are formed with highly-flattened TAA cation bilayers for (C₅H₁₁)₄N⁺, (C₆H₁₃)₄N⁺,...
Resource Type:: Article
Full Text:: Synthesis of the Graphite Intercalation Compounds Containing Tetra-n-alkylammonium Cations Weekit

Proline sulphonamide-catalysed Yamada–Otani condensation: reaction development, substrate scope and scaffold reactivity

Creator:: Yang, Hua, Banerjee, Somdev, and Carter, Rich G.
Abstract:: The development of a proline sulphonamide-catalysed method for enantioselective and diastereoselective construction of functionalized cyclohexenones is described. Impact of catalyst structure as well as solvent effects and additives are explored. A significant substrate scope is demonstrated by variation of both the aldehyde and the enone components. Diastereoselective derivatization of the...
Resource Type:: Article
Full Text:: effects and additives are explored. A significant substrate scope is demonstrated by variation of both the

The atmospheric chemistry of particulate-bound polycyclic aromatic hydrocarbons : concentration, prediction, laboratory studies, and mutagenicity

Creator:: Jariyasopit, Narumol
Abstract:: The trans-Pacific atmospheric transport of particulate matter (PM)-bound polycyclic aromatic hydrocarbons (PAHs) to remote sites in western North America has been well documented and has triggered research questions regarding to atmospheric transformation of PM-bound PAHs and the potential impacts on human health from their inhalation exposure. In this dissertation, field...
Resource Type:: Dissertation
Full Text:: dissertation will become part of the permanent collection of Oregon State University libraries. My signature

Surface areas of graphite regenerated from graphite oxide

Creator:: Vander Zanden, Eugene Justin
Resource Type:: Masters Thesis
Full Text:: submitted to OREGON STATE UIIVERSITY in partial fulfillment of the requirements for the degree of

Determination of ethyl glucuronide and ethyl sulfate as human biomarkers of alcohol exposure in urine by liquid chromatography/electrospray tandem mass spectrometry with large volume injection

Creator:: Hu, Yan
Abstract:: This research was undertaken to develop a sensitive, selective, and rapid analytical method to measure ethyl glucuronide (EtG) and ethyl sulfate (EtS) in urine as urinary biomarkers of alcohol exposure. Large-volume injection (LVI) coupled with liquid chromatography / electrospray tandem mass spectrometry was used to eliminate the need for either...
Resource Type:: Masters Thesis
Full Text:: Submitted to Oregon State University in partial fulfillment of the requirements for the

Chemical composition of layered gabbros and mineral separates from the Red Sea area

Creator:: Miller, Donald Ashley
Resource Type:: Masters Thesis
Full Text:: Oregon from the Picture Gorge area of Central Oregon, Oregon, U.S. A. Samples SAB 486-492, SAB 215

Part I: Synthetic Studies toward C10-functionalized Lycopodium Alkaloids. Part II: Exploration of the Pummerer Cyclization and Its Application to the Total Syntheses of the Abietane Diterpenoids

Creator:: Li, Xin
Abstract:: This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
Resource Type:: Dissertation
Full Text:: understand that my dissertation will become part of the permanent collection of Oregon State University

CO₂ capture from wet flue gas using a water-stable and cost-effective metal-organic framework

Creator:: Loughran, Ryan P.
Abstract:: We report the use of MIL-120 as a water-stable and cost-effective metal-organic framework (MOF) for selectively capturing CO₂ from wet flue gas. Synthesized using inexpensive and environmentally benign reagents in water, MIL-120 possesses one-dimensional pores decorated with hydroxyl-bridged Al(III) ions and benzene rings with an interstitial spacing of 4.78 Å....
Resource Type:: Masters Thesis
Full Text:: manuscript and reformatted it to meet the requirements of Oregon State University’s Graduate School. I have

Trace analysis of halogenated polycyclic aromatic hydrocarbons from an electronic waste recycling area and Guangzhou, China

Creator:: Gonzales, Leah R.
Abstract:: Halogenated Polycyclic Aromatic Hydrocarbons (X-PAHs) are ubiquitous contaminants that are thought to be generated by processes such as chemical industries and incomplete combustion, including waste incineration and electronic waste (e-waste) burning. X-PAHs are a concern for environmental and human health because they are toxic, mutagenic, and are expected to be...
Resource Type:: Masters Thesis
Full Text:: ) inlet, using environmental samples from an e-waste area and in Guangzhou, China. The concentrations of

Influence of Asian and Western U.S. Urban Areas and Fires on the Atmospheric Transport of PAHs, PCBs, and FTOHs in the Western U.S.

Creator:: Primbs, Toby, Piekarz, Arkadiusz, Wilson, Glenn, Schmedding, David, Higginbotham, Carol, Field, Jennifer, and Simonich, Staci
Abstract:: Atmospheric measurements of semivolatile organic compounds (SOCs) were made at Mt. Bachelor Observatory (MBO), located in Oregon’s Cascade Range, to understand the trans-Pacific and regional transport of SOCs from urban areas. High volume air sampling (~644 m³ for 24 hour periods) of both the gas and particulate phases was conducted...
Resource Type:: Article

Influence of Asian and Western United States Agricultural Areas and Fires on the Atmospheric Transport of Pesticides in the Western United States

Creator:: Primbs, Toby, Wilson, Glenn, Schmedding, David, Higginbotham, Carol, and Simonich, Staci Massey
Abstract:: Historic and current use pesticides (HUPs and CUPs), with respect to use in the United States and Canada, were identified in trans-Pacific and regional air masses at Mt. Bachelor Observatory (MBO), a remote high elevation mountain in Oregon’s Cascade Range located in the United States, during the sampling period of...
Resource Type:: Article

The identification and quantitation of complex polycyclic aromatic hydrocarbon mixtures in environmental samples using comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry

Creator:: Manzano, Carlos A.
Abstract:: Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous contaminants and are mostly products of the incomplete combustion of organic material. PAHs are often found in environmental samples as a complex mixture of isomers. In addition, the same sources that produce complex PAH mixtures also produce other poorly characterized mixtures of organic compounds,...
Resource Type:: Dissertation
Full Text:: A DISSERTATION submitted to Oregon State University in partial fulfillment of the

Chemical composition studies of Oregon and Washington coastal basalts

Creator:: Hill, Dale Wayne
Abstract:: Basalts of both Eocene and Miocene age from several groups along the Oregon and Washington coasts have been analyzed for some major, minor, and trace elements using instrumental neutron activation analysis (INAA). The rare earth element (REE) patterns observed in these samples are used for comparisons within the groups studied...
Resource Type:: Masters Thesis
Full Text:: along the Oregon coast. The basalts of this area and time are given the following names from North to

Inclusively Recognizing Faculty Innovation and Entrepreneurship Impact Within Promotion and Tenure Considerations

Creator:: Bouwma-Gearhart, Jana, Lenhart, Cindy, Carter, Rich, Mundorff, Karl, Cho, Holly, and Knoch, Jessica
Abstract:: Faculty research has led to a plethora of innovations and entrepreneurial resources (I&E), allowing for enhancements to the greater social good including, but not limited to, technological and economic advancements. Faculty I&E also enhances faculty competitiveness for funding, institutional image and fundraising, and supports students’ workforce preparation. Over time institutions...
Resource Type:: Preprint
Full Text:: , and the evolving realities of the workforce, this is surely an area for improvement across

A Call For Promoting Faculty Innovation & Entrepreneurship

Creator:: Bouwma-Gearhart, Jana, Carter, Rich, and Mundorff, Karl
Abstract:: We call for the promotion of faculty innovation & entrepreneurship (I&E), across disciplines, and its recognition in promotion and tenure processes– thereby enabling universities to better serve as a talent and idea engine for the Nation’s innovation economy, and evolve and respond in a time of enhanced societal needs and...
Resource Type:: Preprint
Full Text:: innovation economy in Oregon, the nation, and the world. *This is an original manuscript of an

Heats of immersion and swelling of quaternary ammonium complexes of montmorillonites

Creator:: St. Clair, Akos Dominic
Abstract:: Heats of immersion were obtained for four different organophilic clay complexes in a series of normal alcohol-heptane mixtures with alcohols of increasing chain length. The immersion calorimeter employed was the Dewar type with a sensitivity of approximately 5 x 10⁻⁵°C. Gel volumes were determined for two of the clay complexes...
Resource Type:: Masters Thesis
Full Text:: Oregon State University in partial fulfillment of the requirements for the degree of Master of

The Total Kinetic Energy Release in the Fast Neutron-induced Fission of ²³²Th

Creator:: King, Jonathan W.
Abstract:: The post-emission total kinetic energy release (TKE) in the neutron induced fission of ²³²Th was measured (using white spectrum neutrons from LANSCE) for neutron energies from En = 3 to 91 MeV. In this energy range the average post-neutron total kinetic energy release decreases from 162.3 ± 0.3 at En...
Resource Type:: Dissertation
Full Text:: Oregon State University in partial fulfillment of the requirements for the degree of Doctor of

Part I: Synthetic studies toward the southern portion of Azaspiracid-1; Part II: Total synthesis of amphidinolide B₁ and the proposed structure of amphidinolide B₂

Creator:: Lu, Liang
Abstract:: The structural architecture present in marine toxin azaspiracid - 20 stereocenters, 9 rings, 3 separated spirocenters - has attracted considerable synthetic attention. Our efforts toward the synthesis of azaspiracid have led to the completion of both C₁-C₂₆ northern and C₂₇-C₄₀ southern halves. Herein, the synthesis of southern FGHI ring system...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE DISSERTATION OF Liang Lu for the degree of

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Creator:: Vellucci, Jessica K.
Abstract:: Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
Resource Type:: Dissertation
Full Text:: understand that my dissertation will become part of the permanent collection of Oregon State University

The composition and purity of vinegar sold in various parts of the state of Oregon

Creator:: Howard, Joseph William and Struve, Marcus
Resource Type:: Undergraduate Thesis
Full Text:: of the state of Oregon THESIS on THE COMPOSITION AND PURITY OF VINEGAR SOLD IN VARIOUS PARTS OF

Trans-Pacific and regional atmospheric transport of anthropogenic semivolatile organic compounds in the western U.S.

Creator:: Primbs, Toby
Abstract:: The atmospheric transport of anthropogenic semivolatile organic compounds (SOCs) from Asian sources to the Western U.S. was investigated. In addition, the SOC extraction method was optimized. Hansen solubility parameter plots were used to aid in the pressurized liquid extraction (PLE) solvent selection of air sampling media in order to minimize...
Resource Type:: Dissertation
Full Text:: concentrations increased with the percentage of air mass time in Oregon and during regional fire events

Mass Spectrometry-based Detection of Neonicotinoids on Honey Bees

Creator:: Trevor, Shear, Morré, Jeff, and Hooven, Louisa
Abstract:: With increasing use of new pesticide formulations worldwide to repel and kill unwanted organisms, negative consequences on non-target species such as honey bees and other pollinators are of increasing concern and not well studied. This study compares the nanotechnology based pesticide (NBP) Safari and its base neonicotinoid, dinotefuran, and their...
Resource Type:: Poster
Full Text:: Safari on the exterior of bees in preparation for analysis, 5 bees were placed in 5 mL of distilled

Gas phase x-ray photoelectron spectroscopy of some ketone compounds

Creator:: Situmeang, Rudy T. M.
Abstract:: The photoelectron spectra of a series of ketone compounds have been investigated in the gas phase. Core ionization energies were measured to probe the effects of molecular size and connectivity number on core ionization energies. It was found that core ionization energies roughly decrease with increasing connectivity number as expected....
Resource Type:: Masters Thesis
Full Text:: , peak area, as well as width parameters describing the relative contributions of gaussian and

Time-of-flight scattering and recoil spectrometry (TOF-SARS) applied to molecular liquid surfaces : a new approach to surface composition and orientation

Creator:: Gannon, Thomas J.
Abstract:: In spite of their importance in many systems, liquid surfaces have been explored at the microscopic level to a much lesser extent than solids. Most surface analysis must take place in vacuum, a major drawback for liquids. The technique of time-of-flight scattering and recoil spectrometry (TOF-SARS) has been applied to...
Resource Type:: Dissertation
Full Text:: understand that my thesis will become part of the permanent collection of Oregon State University libraries

Vibrational relaxation phenomena in triatomic gases

Creator:: Montan, Donald Noel
Resource Type:: Dissertation
Full Text:: OREGOI' STATE COLLEGE in partial fulfillment of the requirements for the degree of DOCTOR OF

The microstructure of marine sediments

Creator:: Stump, Arthur Darrell
Abstract:: The surface areas and pore size distributions of a series of terrigenous marine sediments were measured by gas adsorption. The sediment samples were taken from the continental terrace off the coast of Oregon near Newport. Sampling stations ranged up to 35 miles off shore between 44°20' and 45° north latitude....
Resource Type:: Dissertation
Full Text:: - nental terrace off the coast of Oregon near Newport. Sampling stations ranged up to 35 miles off shore

The adsorption of water by cements

Creator:: Johnson, Raymond Hawley, 1905-
Resource Type:: Masters Thesis
Full Text:: Adsorption of Water by Cements Submitted to the OREGON STATE AGCULTURAL C3LLEGE In partial fulfillment

The structure of the fission transition nucleus ²³⁵U

Creator:: Bouchard, Mary Joseph
Resource Type:: Dissertation
Full Text:: probability integrates to unity for limits 0 and Ti. The area of the angular ring on a sphere of radius R

The structure of the fission transition nucleus ²²⁷Ra

Creator:: Groening, Hugo Rafael
Resource Type:: Dissertation
Full Text:: Rafael Groening A THESIS submitted to Oregon State University in partial fulfillment of the

An investigation of the oil of Lavandula vera cultivated in Oregon

Creator:: Gibbon, Clarence Irwin
Abstract:: The purpose of this work was to investigate possibilities of raising lavender in Oregon of desirable qualities and. yield. This was carried out by analysis and study of the properties of the oil obtained therefrom in order that a comparison with other kinds of lavender oil might be made. It...
Resource Type:: Masters Thesis
Full Text:: in Oregon / AN ABSTRACT OF TBE THESIS OF for the-- (Name) (Degree) (MaJr) Date Thesis

The investigations of the methods for the reduction of chloropyrimidines

Creator:: Ladpli, Vimolvan
Abstract:: This thesis investigated on the dehalogenation of 2, 4- dichloropyrimidine in various different conditions. These conditions were changed by varying the solvents, the amount of catalysts and the hydrogen chloride acceptors in order to study the effects on the yields. It was found that the ether-aqueous sodium hydroxide medium with...
Resource Type:: Masters Thesis
Full Text:: Oregon State University in partial fulfillment of the requirements for the degree of Master of Science

Theory of negative thermal expansion

Creator:: Tao, Ju Zhou
Abstract:: Two framework oxide materials of the MO₃ network type have been synthesized and structurally characterized by synchrotron and X-ray powder diffraction and the Rietveld method in the temperature range 25~500 K. The results show one of them to be a low thermal expansion material. Theoretical studies of negative thermal expansion...
Resource Type:: Dissertation
Full Text:: to Oregon State University In partial fulfillment of The requirement for the degree of Doctor of

The diffusion of gelatin

Creator:: Broadbooks, Martin Robert
Resource Type:: Masters Thesis
Full Text:: araount diffusing per interval of time dt. A is the effective area of the pores. The diffusion

Surface composition and orientation of room temperature ionic liquids

Creator:: Law, George
Abstract:: In this thesis, we investigated the surface composition and orientation of both pure room-temperature ionic liquids (Ils) and binary mixtures of the ILs of the type consisting of the 1-alkyl-3-methylimidazolium ([C[subscropt n]mim]⁺, n=4, 8, and 12) cation coupled with either [PF₆]⁻, [BF₄]⁻, [Cl]⁻, or [Br]⁻. The surfaces of the ILs...
Resource Type:: Dissertation
Full Text:: who made the journey to and through the five years of graduate studies at Oregon State University

The photodebromination of polybromobenzenes

Creator:: Couch, Tara Lin
Resource Type:: Dissertation
Full Text:: submitted to Oregon State University in partial fulfillment of the requirements for the degree of Doctor

Large volume (1,800 µL) injection HPLC/MS/MS for the quantitative determination of illicit drugs and human urinary biomarkers in municipal wastewater

Creator:: Chiaia Hernandez, Aurea C.
Abstract:: A sensitive, selective, rapid analytical method based on large-volume injection (LVI) liquid chromatography/ tandem mass spectrometry was developed using commercially-available hardware that eliminates the need for either off-line or on-line solid phase extraction. Centrifugation followed by the direct injection of 1,800 µL was used for the quantification of illicit drugs,...
Resource Type:: Masters Thesis
Full Text:: THESIS Submitted to Oregon State University in partial fulfillment of the

The role of iron-oxides in U(VI) adsorption and the kinetics of contaminant organic reduction

Creator:: Logue, Brian A.
Abstract:: Contaminant transport in ground water is an important environmental process that affects a host of natural systems. Transport of contaminants is affected by many processes, including aqueous complexation, adsorption, and redox reactions. One of the most important components of an aquifer that controls transport is iron-oxide. In this study, the...
Resource Type:: Dissertation
Full Text:: understand that my thesis will become part of the permanent collection of Oregon State University libraries

The effect of hydrogen ion concentration upon the absorption of dyes by cellulose and fillers

Creator:: Kuykendall, Delman Vernon
Abstract:: The dyeing of paper is one of the most important processes in the manufacture of that material. Fully 95 percent of the paper that is produced is colored to a greater or lesser extent, and in many eases the reproduction of a shade is essential. That pH is an important...
Resource Type:: Masters Thesis
Full Text:: supplied by the Portland Branch of the Papermaker's Chemical Corporation. After they were received

The chemical composition of the bast fibers of Douglas fir bark, Pseudotsuga taxifolia (Poir.) Britt

Creator:: Kiefer, Harry John
Resource Type:: Dissertation
Full Text:: The chemical composition of the bast fibers of Douglas fir

Determination of the vibrational lifetime of carbon monoxide by the spectrophone method

Creator:: Turrell, George Charles
Resource Type:: Dissertation
Full Text:: cross- sectional area of the 1iht beam. This is particularly important when the carbon arc is used

Natural and semi-synthetic compounds with biocidal activity against arthropods of public health importance

Creator:: Khasawneh, Mohammad A.
Abstract:: This study identified new compounds with pest control activities. The two sources of candidates that were followed here were the main heartwood extract of Alaska Yellow Cedar (AYC) constituents and several semi-synthetic counterparts. Five compounds were isolated and identified for the first time in AYC heartwood in this research: two...
Resource Type:: Dissertation
Full Text:: Submitted to Oregon State University in partial fulfillment of the requirements of the degree of Doctor

Relative influence of trans-Pacific and regional atmospheric transport of polycyclic aromatic hydrocarbons (PAHs) in the Pacific Northwest (PNW), USA

Creator:: Lafontaine, Scott
Abstract:: The relative influences of trans-Pacific and regional atmospheric transport on measured concentrations of polycyclic aromatic hydrocarbons (PAHs), PAH derivatives [Nitro- (NPAH) and Oxy-(OPAH)], organic carbon (OC), and Particulate Matter (PM) less than 2.5 μm in diameter (PM₂.₅) were investigated in the Pacific Northwest, USA in 2010-2011. Ambient high volume PM₂.₅...
Resource Type:: Masters Thesis
Full Text:: the Oregon Cascade Range (2763 m above sea level (asl)) and 2.) Confederated Tribes of the Umatilla

The adsorption of uranium ions from seawater

Creator:: Fyke, David Ray
Abstract:: The adsorption of uranium ions from seawater could be of importance as reserves of uranium are depleted. The structure, chemical state, and concentration of uranium in seawater have been previously determined. Uranium exists as a charged ion, UO₂(CO₃)₃⁴⁻. The concentration in seawater is 3.3 parts per billion. Previous studies with...
Resource Type:: Masters Thesis
Full Text:: potentially good adsorbents of uranium. Tests were carried out at the Oregon State University Marine Science

The chemistry and device applications of amorphous thin-film interfaces

Creator:: Knutson, Christopher C.
Abstract:: Solid-state amorphous materials show amazing promise in thin-film electronics. The interface-to-bulk ratio of thin films makes interfacial chemistries of these systems of utmost importance. Thin films of amorphous metals, dielectrics and semiconductors have novel chemistries that are not only based upon their elemental constituent makeup, but also based upon the...
Resource Type:: Dissertation
Full Text:: are located near volcanoes due to the large amount of heat present in volcanoes, however the

Investigations into the mechanism of the photodechlorination of pentachlorobenzene

Creator:: Schmidt, Robert Dean
Abstract:: Several experiments were undertaken to investigate the mechanism of photodechlorination of pentachlorobenzene. The thermal methoxydechlorination reaction of pentachlorobenzene was studied. In DMSO at 50 °C sodium methoxide reacts smoothly with pentachlorobenzene to give three tetrachloroanisole isomers. A second-order kinetic plot for this reaction is linear to high precision, indicating that...
Resource Type:: Masters Thesis
Full Text:: Robert Dean Schmidt A THESIS submitted to Oregon State University in partial fulfuliment of the

The evaluation of the function of pathways in tomato metabolism

Creator:: Doyle, William Patrick
Resource Type:: Dissertation
Full Text:: A THESIS submitted to OREGON STATE COLLEGE in partial fulfillment of the requirements for the

Some quantitative aspects of the chromatography of the permanganate iron

Creator:: Gill, Philip Ivan
Resource Type:: Masters Thesis
Full Text:: Some quantitative aspects of the chromatography of the

The nature and stabilities of the fluo-complexes of tantalum

Creator:: Varga, Louis Paul
Resource Type:: Dissertation
Full Text:: THESIS submitted to OREGON STATE COLLEGE in partial fulfillment of the requirements for the

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