Non-equilibrium photocarriers in multilayer WSe2 injected by femtosecond laser pulses exhibit extraordinary nonlinear dynamics in the presence of intense THz fields. The THz absorption in optically excited WSe2 rises rapidly in the low THz field regime and gradually ramp up at high intensities. The strong THz pulses drive the photocarriers...
Cell signaling under external stimulation is a critical mechanism that governs many biological processes such as cell proliferation, cell migration, and cell apoptosis, etc. For multicellular organisms, the ability to synchronize heterogeneous individual cellular responses through intercellular communication is crucial to maintain normal functionality. However, even though the biological pathways...
The utility of high-throughput, computational screening has become an invaluable asset to the field of materials science. In the hierarchy of computational methods, the most accurate methods are often the most computationally expensive. However, as both the efficiency and fidelity of numerical techniques advance, high-quality screening of large materials datasets...
Quantum mechanics is increasingly being taught with a spins-first approach where instructors use simple spin systems to introduce the principles of quantum mechanics rather than systems with wavefunctions. One of the defining characteristics of a spins-first approach is that systems studied have discrete bases, whereas systems with wavefunctions have continuous...
Transparent conductive oxides (TCO) are at the forefront of technology with their uses in
touch screen phones and televisions, solar cells and more. Titanium dioxide and tin dioxide are two TCOs that have been studied in depth on their own, so to further explore these TCOs, this project focuses on...
Physicists solve problems and communicate their work using many external representations, such as equations, words, diagrams, graphs, sketches, pictures, and more. To learn physics, then, students must learn to use external representations. In this dissertation, I present three manuscripts. Each manuscript discusses how upper-division Paradigms in Physics students use multiple...
Given the recent advancements in the field of pulsar timing pertaining to the detection of a stochastic gravitational wave background (GWB), it is now the perfect time to perform tests of gravity via exploration of the correlation signature between the timing data of pairs of pulsars induced by the polarization...
The North American Nanohertz Observatory for Gravitational Waves (NANOGrav) is an international collaboration that seeks to use perturbations in the time of arrivals of pulsar signals to detect gravitational waves in the nanohertz range of frequencies. The 15-year data set will be released as of June 2023. It is a...
Crystals are solid materials with periodic and symmetric molecular patterns. The structure of a crystalline solid determines its properties, making it essential to study its structures. From the principle of minimum energy, a crystal will choose a structure with the lowest free energy F = U – TS. At low...
Brownian motion is the movement of a particle in a fluid resulting from collisions with surrounding molecules. It has modern applications in simulating fluid dynamics and the motion of proteins in biophysics. Brownian motion simulations generally evolve the initial state by applying Newton’s second law to every particle. These simulations...
Semiconductors serve an integral role in our technologies today. However, with new advancements in ultra-fast electronics, we are approaching the fundamental speed limits of traditional silicon-based semiconductors. Silicon-based semiconductors typically exhibit photocarrier dynamics in nanosecond timescales. Transition metal dichalcogenides (TMDs) are 2D materials shown to exhibit photocarrier dynamics in picosecond...
Organic semiconductors are a promising alternative to the traditional inorganic semiconductors, such as silicon. Organics are solution-processable, low-cost, sustainable, and have interesting optoelectronic properties. One such property is the formation of exciton-polaritons, quantum quasi-particles formed by an electron-hole pair in the semiconductor and a photon. This process can be induced...
I examine the strong co-variability between the surface divergence and vorticity and how it varies with latitude in the Pacific Ocean using surface vector winds from reanalysis and satellite scatterometer observations. This analysis was motivated in part by a significant correlation between divergence and vorticity over the global oceans that...
I had to write again. My research lay in science, and it was a science of three parts. The first part made a careful, introductory chapter, begged for by things that were lacking. It summarizes the von Neumann measurement model, derived from the Stern-Gerlach experiment, and it explains how weak...
We present a classical density functional to model the soft, repulsive potential of a Weeks-Chandler-Andersen (WCA) fluid using Soft Fundamental Measure Theory (SFMT) with temperature-dependent parameters inspired by the Barker-Henderson method. Our functional uses soft spheres to model the soft-sphere WCA potential, and gives results that are in good agreement...
I led a collaborative project involving a search for an evidence of a gravitational wave background (GWB) with all the spatial correlations allowed by general metric theories of gravity using NANOGrav’s 12.5 year data set. The search found no substantial evidence in favor of the existence of such correlations.
The...
Computational statistical mechanics leans heavily on the class of Markov Chain Monte Carlo Algorithms. Many such algorithms exist, and simulations can run for several weeks, making the selection of algorithms a difficult, but critical task. In this work, we introduce a benchmark system of two quadratic wells with an analytical...
In this thesis, we explore a general method for constructing path sums in a discrete spacetime using a jump amplitude matrix. This is accomplished by deriving a composition law that relates jump amplitudes to the propagator. Then properties of causal sets are used to average this relationship over sprinklings. This...
Fast neutron detection is important to the detection of illicit nuclear materials and can help prevent those materials from being used or transported without discovery. Previous research has shown that Heavy Oxide Inorganic Scintillator crystals can be used to detect fast neutrons by capitalizing on their high inelastic scattering cross...
TiO₂ typically crystallizes into three polymorphs: brookite, rutile, and anatase. The phase selection problem in TiO₂ is the lack of understanding what conditions cause amorphous TiO₂ to crystallize into one of its three polymorphs during an annealing process. It has been recently shown that phase selection in TiO₂ is highly...
Future quantum technologies will require high-efficiency, on-demand sources of entangled photons. A possible route to building such light sources employs two-dimensional (2D) semiconductors interfaced with a source of Cooper pairs. To investigate the possibility of such devices, we are testing methods to make high transparency n-type contacts, p-type contacts, and...
I am a physics education researcher. My ‘laboratory’ is a year-long Introductory Algebrabased Physics sequence taught at Oregon State University (OSU). While not technically a hybrid class, it has most of the aspects of a hybrid learning environment, as the course is “flipped,” and includes a combination of pre-lecture online...
This thesis conveys the key technical features and scientific applications of a particle-particle ballistic simulation tool (SpaceLab) as well as a high level overview of experiments it was designed for and executed on. SpaceLab simulates spherical particle interactions under any combination of self-gravity, sliding friction, rolling friction, Van-Der-Waals (VDW) cohesion...
Electrostatic gating of nanomaterials allows researchers to control carrier density and shape potential barriers that confine carriers. Lithographic patterning followed by metal deposition is the standard technique to define electrostatic gates; however, the methods of fabricating these devices often involve harsh processing. For example, taking a material to high temperatures...
Organic semiconductors have attracted considerable attention due to their applications in low-cost, solution-processable (opto)electronic devices. An important class of high-performance organic semiconductors is pentacene derivatives, which exhibit high charger carrier mobilities in field-effect transistors and ultrafast singlet fission in photovoltaic devices. These derivatives have served as benchmark materials for systematic...
Taking long-term electrical measurements of a large number of neurons simultaneously is required for many modern neuroscience experiments. However, such experiments are currently limited by the shortcomings of traditional neurosensing technology. For example, there is a significant mechanical mismatch between rigid silicon probes and soft biological tissues. This mismatch can...
At the intersection of basic science research and clinical relevance, cancer metastasis and cell invasion is a multifaceted problem that has been investigated for the past several decades. Importantly, cancer cell plasticity, the ability of a single cell to change its phenotype without genetic mutations in response to environmental cues,...
Gamma Ray Bursts (GRBs) are the most energetic explosions in the Universe, producing up to $\sim10^{53}$ ergs of energy in the first few seconds of their emission -- the so-called prompt phase that is dominated by high energy X-ray and $\gamma$-ray photons. The very large luminosities released in these events...
Fluorescent proteins have emerged as an essential toolset for bioimaging, creating a demand for engineering proteins with new and improved fluorescent properties. In this thesis, I explore the atomistic structure of REX-GECO1, a newly engineered protein biosensor that has unique optical properties. Since this protein has no available crystal structure,...
Carbon nanotube (CNT) photodiodes are a promising system for high-efficiency photocurrent generation due to the strong Coulomb interactions that can drive carrier multiplication. If the Coulomb interactions are too strong, however, exciton formation can hamper photocurrent generation. Here, we explore, experimentally and theoretically, the effect of the environmental dielectric constant...
In this work, we systematically explore the effectiveness of optical aberration correction over a wide range of optical depths using the Segmented and Zernike Polynomial bases. We manufacture a set of 16 optical phantom samples consisting of a clear polyester resin substrate embedded with varying concentrations of aluminum oxide (Al₂O₃)...
Solutions to Einstein's equations are usually found by considering ideal, simplified models. However, if the real world always matched ideal physics models, then farmers would milk black and white spheres. To combat this, Regge calculus was developed as a numerical approximation scheme for general relativity. In Regge calculus curved manifolds...
Different models show the effects of environmental decoherence on a quantum system
due to various environments of interest. One important quantity within these models is
the decoherence time, which tells us how quickly environments wash away the coherence of
local measurements. We can describe this effect as the quantum system...
The purpose of this project is to verify scattering mechanisms in semiconductors by measuring transport properties and producing data that reflects existing research. The Hall effect is utilized to measure the resistivity, mobility and charge carrier concentration of the semiconductors: indium tin oxide (ITO), p-type silicon, and n-type silicon. By...
A new class at Oregon State, PH 317: Experimental Physics, is designed to simulate a traditional laboratory research experience for undergraduate students. Several weeks of the class is devoted to Brownian motion experiments. Although this is a common topic for undergraduate lab classes, the experiment still needed some basic exploration...
Detecting gravitational waves is a topic at the forefront of physics. The first gravitational wave was detected by LIGO in 2015. This wave had a frequency in the 10s of Hz. This project is focused on detecting gravitational waves on the nanohertz spectrum using a pulsar timing array. This array...
Gravitational wave (GW) astronomy is a key ingredient in confirming Einstein’s theory of General Relativity and showing how the universe sends ripples through spacetime, distorting distances between two points. The confirmation of high-frequency GWs observed by The Laser Interferometer Gravitational-Wave Observatory (LIGO) in 2015 was a breakthrough in our understanding...
Impedance spectroscopy is a method of modeling materials with equivalent circuits to determine electrical properties, such as the resistivity and the dielectric constant. We explore impedance spectroscopy, both theoretically and experimentally through applying the method to samples of BaCuS1-xSexF. Grain boundary effects were dominant in the results, and although they...
This study used SCOUT optical modelling software to create models of the reflectance and transmittance spectra generated by mixtures of titanium dioxide (TiO2) and tin oxide (SnO2). These models enabled identification of how altering the ratio of a mixture changes the optical response. By being able to identify how altering...
Terahertz (THz) frequencies of the electromagnetic spectrum have been underutilized when compared to neighboring microwave and infrared frequencies, largely due to the difficulties controlling and detecting these fields. In a step toward gaining control over THz frequencies, my advisor Dr. Yun-Shik Lee’s group experimentally demonstrated optical-pulse THz-control over a plasmonic...
Organic semiconducting materials have emerged in the last few decades as viable alternatives to inorganics in broad applications from field effect transistors to LEDs to solar cells. Organics provide many benefits over inorganics such as flexibility, sustainability, and reduced cost. However, these materials are more susceptible to degradation in the...
Cell division, arguably the most important event during the life cycle of the eukaryotic cell, is achieved through a complicated yet beautiful machinery. The mitotic spindle — a microtubule-based bipolar structure—is the cellular machinery responsible for the correct segregation of the genetic material, chromosomes. The protein-based nanomachines termed molecular motors...
Type I collagen fibers, the connective tissue that makes up the human breast, can be easily manipulated by cells or other outside factors. In previous studies, the alignment of collagen has been associated with the beginning of metastatic cancer, possibly influencing cancerous cells to migrate from the tumor. In this...
The motor protein dynein is responsible for cellular processes such as axonal transport and cell division by delivering vital information along the microtubule track. A failed delivery can cause severe damage to the cell’s functionality and lead to neurological diseases. Despite dynein’s rich history in cellular research, the mechanism of...
Physics problems that require integration, such as finding the center of mass of an object or finding the electric field from a continuous distribution of charge, are one type of problem that is difficult for introductory physics students to solve. These problems require students to define a coordinate system in...
Physicists who study semiconductor devices are fascinated by the fundamental limits of device performance. From the sub-threshold swing of transistors to the power conversion efficiency of photocells, performance is limited by the electronic structure of the materials used to build them. To surpass traditional device limits, we must turn to...
Understanding the impact of inter-molecular orientation on the optical proper-ties of organic semiconductors is important for designing next-generation organic (opto)electronic and photonic devices. However, fundamental aspects of how various features of molecular packing in crystalline systems determine the nature and dynamics of excitons have been a subject of debate. Toward...
The discovery of GW170817 provided the first empirical evidence that merging binary neutron star systems are both progenitors of short gamma-ray bursts, as well as the primary sites of the nucleosynthetic rapid-neutron capture process. Initially detected as gravitational wave (GW) and gamma-ray burst (GRB) triggers, GW170817 was well-localized and follow-up...
One of the biggest open questions in physics is the prevalence of matter over anti-matter in the present universe. One of possible answers lies in the violation of charge and parity symmetry in the lepton sector that would favor matter over anti-matter so that the universe becomes dominated by matter...
We use Classical Density Functional Theory (cDFT) to predict the freezing of a Weeks-Chandler-Anderson (WCA) fluid, and construct pressure-temperature and temperature-density phase diagrams. A WCA fluid consists of soft spheres that exhibit the repulsive portion of the Lennard-Jones potential widely used to model the interaction of two neutral atoms. Our...
Metal organic frameworks(MOFs) are a class of crystalline materials utilized in gas storage, chemicalsensing, and other engineering applications. Recently chemists have begun synthesizing MOFs withmoving parts in order to further these applications. A wide array of dynamic MOFs have been created andtheorized. Among them is the interlocking of a ring...
Spectroscopic ellipsometry (SE) is used to characterize amorphous and crystalline thin films of TiO2. Amorphous precursor films of TiO2 are deposited by radio frequency magnetron sputtering on fused silica and silicon substrates. Annealing the amorphous precursor films induces them to crystallize into either pure or mixed phases of the three...
Exciton-polaritons are a form of light-matter coupling that have potential applications as photonic transistors and logic gates. In order for a photonic transistor or logic gate to be integrated with room temperature fiber-optic technology, excitons-polaritons need to be stable at room temperature and compatible with the red and near-infrared wavelengths...
As responsible energy usage is becoming more and more a part of the public conscience, a key practice of this idea emerges. Specifically, using the energy we do have with maximum efficiency. While the laws of thermodynamics remain a limiting factor, research has been done to show that properties of...
This work introduces the novel flat-histogram Monte Carlo (MC) method stochastic approximation with a dynamic update factor (SAD) and explores the convergence properties of a variety of related weight-based MC methods. The new method is applied to a number of physical `test’ systems including the 2D Ising model, a square-well...
In nanoscale materials, the Coulombic interaction between electrons are stronger than in bulk materials. These stronger interactions, caused by confinement and reduced dielectric screening, have interesting consequences for light-matter interactions. In carbon nanotubes (CNTs), strong interactions can enhance the impact ionization process, and thus assist photocurrent generation in CNTs. Conversely,...
I construct and examine the properties of Lie and Clifford algebras which are used to describe certain types of particles. These algebras are then related to the traditional theory of division algebras. Quaternions are applied to these algebras and their properties are exploited to model physical properties of particles. The...
We explore the interactions between charge transfer exciton states (CTEs) and an optical microcavity by testing the effects that cavity resonance has on the CTEs and if CTEs can be coupled with a photon to create quasiparticles known as polaritons. Exciton polaritonics is becoming a booming area of research mainly...
Standard quantum mechanics makes foundational assumptions to describe the measurement process. Upon interaction with a “classical measurement apparatus”, a quantum system is subjected to postulated “state collapse” dynamics. We show that framing measurement around state collapse and ill-defined classical observers leads to interpretational issues, and artificially limits the scope of...
The electrical properties of amorphous and crystalline titanium dioxide polymorphs are reported. Titanium dioxide is a widely used transparent semiconductor and it is a useful oxide model. Using variable temperature transport measurements of thin films, it was possible to establish the activation energy barrier for conduction. This was accomplished using...
The spalting fungus Scytalidium cuboideum secretes a red pigment that produces naphthoquinonic crystals that are a photonic material candidate. The molecule can pack together in different configurations resulting in amazingly different optical properties. I developed a procedure (slowly evaporating the solvent) to preferentially grow two of these configurations, which have...
In industry, there is considerable interest in finding sustainable, renewable materials for use in electronic devices. Pigments derived from spalting fungi are of particular interest due to their longevity in diverse environmental conditions. The focus of my project was to characterizethe properties of a novel, fungi-derived pigment, and to discover...
Monte Carlo methods are used to explore vapor-liquid phase transitions. However, current models are computationally expensive when identifying these phase transitions. Traditionally, Monte Carlo simulations are run across a range of temperatures at a fixed number of atoms/molecules. The Number Monte Carlo method (NMC), our proposed Monte Carlo method, runs...
Microelectrode array (MEA) dissolved-oxygen (DO) sensors were built and electrochemically tested in a solution of potassium ferricyanide. MEAs are becoming more popular as DO sensors because of their small size and capacity for simultaneous measurements with multiple recording sites. The ability to measure DO with multiple recording sites is useful...
Units and dimensions are seldom addressed formally in science classrooms, despite being one of the most fundamental and ubiquitous tools available to scientists. Even worse, science and engineering graduates are often moving into careers without fundamentally understanding units and their importance, leading to struggles in developing scientific literacy and to...
Physics sensemaking is a growing topic of study within the physics education community. Many lenses have been used to study sensemaking but few have considered how time and instruction can impact student sensemaking practices and ideas. In this dissertation, I present four studies that address four major questions: What sensemaking...
Terahertz (THz) time-domain spectroscopy provides insight into electron dynamics in semiconductor heterostructures. High-field THz spectroscopy probes the excitonic nonlinear response of GaAs quantum well (QW) systems and enables the measurement of its coherent dynamics in the time-domain. Consequently, THz spectroscopy allows one to explore the fundamental properties of many-body interactions...
The optical and electronic properties of amorphous oxide thin films depend crucially on chemical composition, and deposition process variations which give rise to sub-gap defect states. Consequently, there is a need for a reliable, high-throughput method to extract sub-gap defect densities of states in amorphous oxide thin films. We present...
Carbon nanotube (CNT) photodiodes have potential to convert light into electrical current with high efficiency. However, previous experiments have revealed photocurrent quantum yield (PCQY) well below 100%. In this work, we show that axial electric field increases the PCQY of CNT photodiodes. In optimal conditions our data suggest PCQY >...
Cell migration is fundamental for physiological processes such as immune re-sponses, wound healing and development. It is also a critical characteristic of metastatic cancer cells. An extensive amount of studies have focused on 2D sub-strates in order to understand the mechanism of cancer metastasis. However, much less is known about...
Thermodynamic potentials are energies that can describe a thermodynamic system in terms of different mathematically independent variables. Some of these potentials describe particular thermodynamic systems or processes in particularly convenient ways. In this dissertation, I discuss the different ways that students and experts reason about quantities in thermodynamics within the...
Motivated by the Navier-Stokes equations, which are a set of unsolved equations related to fluid motion in R^3, we explored the incompressibility condition and the Neumann boundary problem. After exploring, we noticed that using iterated Riesz transforms of the boundary data could be used to get information about the velocity...
In 1877 John Kerr described an experiment that demonstrated a quadratic change in refractive index in a plate glass placed in a strong external electric field. This results in a nonlinear relationship between the average electric polarization within the materials and the intensity of the applied electric field. This opened...
Since the advent of graphene, research on 2D materials has exploded. Countless experiments have uncovered novel properties that emerge when different layered crystals are cleaved down to only a few atomic layers in thickness. The most popular of these non-graphene 2D materials is MoS2, a semiconductor which has been of...
Exciton polaritons are quasiparticles composed of a quantum superposition of matter and light states that arises from the coupling of a standing wave photon and an exciton. This research has two primary objectives: to design and fabricate a Fabry-Perot microcavity system in which to produce exciton polaritons; and to show...
Terahertz (THz) spectroscopy is a great tool not only to study fundamental physical processes such as many-body Coulomb interaction but also to develop ultrafast electronic devices. More specifically, intense THz fields interacting with semiconductors have exhibited strong nonlinear effect involving extreme carrier dynamics. In this experiment, intense THz radiation was...
Gamma ray bursts are some of the brightest events in the entire observable universe. Since the late 1960’s, thousands of gamma ray bursts have been observed and they have been researched extensively. However, there are still many mysteries which remain unsolved. One such mystery is whether or not the viewing...
Currently multi-canonical, and grand canonical Monte Carlo simulations exist, but do not always give all of the necessary information of the system. When using a 1-D (only changing in one variable) broad histogram Monte Carlo method a user would need to run a range of simulations in order to get...
The relationship between the index of refraction and the porosity of a material is that the index decreases with respect to the porosity. This property can be used to change the index of refraction of films which allows control of the reflection of the material. This is important because being...
Multivariable functions permeate physics, mathematics, and other sciences. Understanding how quantities in multivariable relationships change together – or co-vary – is important for studying physical systems. In this project, we asked junior-level physics majors to describe the covariation of quantities in a multivariable context given a 2D graph. We identified...
The ability to focus light through strongly scattering materials is opening up exciting new avenues in many fields, such as optics, computer vision, biology, and medicine, which utilize light delivery and imaging techniques. Efficient, high resolution wavefront shaping and optimization methods are crucial to enabling this new capability.
In this...
Using a plastic bottle, we explore the capabilities of a reflective phase-only Spatial Light Modulator (SLM) in removing wavefront aberrations using a Zernike polynomial phase mask, with the modulators phase depth limited to 0.8π radians. Wavefront aberrations, which can be modeled with Zernike polynomials, distort image transmission through various optical...
Plasmon induced transparency (PIT) describes a spectral response of coupled plasmonic resonators in that coupling between bright and dark modes leads to a destructive interference resulting in a narrow transparency window. This process has many applications in material characterization and advanced optical devices such as slow light devices or ultrafast...
The dynein molecule is a peculiar motor protein recognized for its unique stepping behavior. Sometimes it steps forwards. Other times it steps backwards. It has even been observed to occasionally shuffle by beginning a step with the same domain many times in row. These motions make dynein an interesting object...
Past studies have shown that students struggle with main concepts of potential energy, such as reading graphs, understanding that potential energy can be negative, and, most pertinent to this research project, connecting potential energy to force. I designed an activity to help introductory physics students address these struggles. The activity...
A great variety of topologically protected defects exist in ordinary and exotic states of matter. Some of them are promising candidates for technological applications such as magnetic memory or quantum computers. Others possess some properties of elementary particles that could lead to potential applications in quantum fields. Nematic liquid crystals...
A small eddy viscosity or mass diffusivity that varies with height has been found to have unexpected effects on the Kelvin-Helmholtz (KH) instability of a stably stratified shear layer near the neutral stability boundary. In particular, varying viscosity can increase the growth rate of the instability in contrast to the...
This dissertation covers my work relating to the application of strong terahertz (THz) radiation to study the nonlinear properties of nano-scale material. It presents experimental and numerical studies on the optical and electronic properties of various material system including single-layer graphene, multi-walled carbon nanotubes (MWCNTs), nanoantenna-patterned gallium arsenide (GaAs) and...
Polarization-dependent absorption spectra of two functionalized derivatives of fluorinated anthradithiophene, diF TES-ADT and diF TDMS-ADT, were studied in the crystal phase using a Holstein-like Hamiltonian. For both molecules, the primary contribution to the lowest energy absorption was found to be the S-0-S-1 excitonic transition perturbed by an intermolecular coupling of...
The neutron capture cross sections of ¹⁰⁶Cd, ¹⁰⁸Cd, ¹¹⁰Cd, ¹¹²Cd, ¹¹⁴Cd and ¹¹⁶Cd
were determined in the present project. Four different OSU TRIGA reactor facilities were
used to produce redundancy in the results and to measure the thermal cross section and
resonance integral separately. When the present values were compared...
The thermal cross sections and resonance integrals for neutron capture by ⁷⁴,⁷⁸,⁸⁰,⁸²Se were measured using the same procedure and equipment for all of the isotopes. Uncertainty and absence of accurate previous values for several isotopes introduces a need of measuring these parameters using similar techniques. This was done using OSU’s...
We measure the charging and discharging of two organic materials, PCBM and ADT-TES-F. These materials are studied through the noncontact method of particle trapping known as Optical Tweezers, where an IR laser is used to constrain the motion of a coated or noncoated silica sphere while its positional data is...
Xylindein is an organic pigment derived from Chlorociboria aeruginascens and C. aeruginosa fungi that has shown promise as an organic semiconductor. Preliminary estimates of charge carrier mobilities (CCMs) on the order of 0.1 cm2/Vs were calculated from early tests on xylindein thin films, and photocurrents were also observed under laser...
This work explores the synthesis and characterization of the metastable alloys Sn1-xCaxCh (Ch= S, Se) and nitride compounds Zn-W-Mo-N, which have recently been predicted by theorists. Single phase thin films of Sn1-xCaxS are prepared by pulsed laser deposition and radio-frequency magnetron sputtering and of Sn1-xCaxSe are prepared by pulsed laser...
Physicists seek to understand the world and often use mathematics to aid in attaining that goal. Thus when doing mathematics they often interrogate their results in order to ensure that they align with their expectations and to gain new insight into how the world works. This seeking of coherence between...
Structure-specific synthesis processes are of key importance to the growth of polymorphic functional compounds such as TiO₂, where material properties strongly depend on structure as well as chemistry. The robust growth of the brookite polymorph of TiO₂, a promising photocatalyst, has been difficult in both powder and thin-film forms due...
Several topics are presented in this dissertation, each of which has applications to solar cells and photodetectors. First, we discuss the growth of Cu10Te4S13, copper tellurium tetrahedrite. This material has interesting optical properties; it has a large joint density of states at the conduction band maximum and valence band minimum,...
Cancer cell migration in three-dimensional extracellular matrix is a major cause of death for cancer patients. Although extensive studies have elucidated detailed mechanism of single cell 3D invasion and cell-ECM interaction, 3D collective cancer invasion is still poorly understood. 3D collective migration models have unveiled unexpected degrees of diversity and...