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  • Evaluation of Stress Corrosion Cracking of 316L Stainless Steel in FLiNaK Using the Slow Strain Rate Technique

    Creator:
    Quintana, Xavier A.
    Abstract:
    Molten salts have been targeted as a promising coolant for next generation reactors due to their high boiling point, heat capacity, and thermal conductivity. Despite these benefits, molten salt systems present unique materials compatibility issues, highlighted by the aggressive corrosion attack and dealloying typically seen on materials in these environments....
    Resource Type:
    Masters Thesis
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    . Quintana for the degree of Master of Science in Materials Science presented on June 1 2023. Title

  • Fabrication and geometrical characterization of metal and metal-dielectric composite periodic nanostructures

    Creator:
    Bhowmik, Siddhartha
    Abstract:
    Periodic metal and metal-dielectric composite nanostructures have been of interest from the field of plasmonics and metamaterial fabrication. In order to exploit the behavior of these unique materials in the visible region of the optical spectrum, these structures need to be significantly shorter than the wavelength of response, and hence...
    Resource Type:
    Dissertation
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    DISSERTATION OF Siddhartha Bhowmik for the degree of Doctor of Philosophy in Materials Science presented on

  • Study of creeping, inertial and turbulent flow regimes in porous media using particle image velocimetry

    Creator:
    Patil, Vishal A.
    Abstract:
    Porous media flows are encountered in many natural and man-made systems such as gas adsorption, filtration, heat exchangers, combustion, catalytic reactors and groundwater hydrology. This study experimentally investigates these flows as function of pore Reynolds number, Re[subscript pore]. The pore Reynolds number is based on the porous bed hydraulic diameter,...
    Resource Type:
    Dissertation
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    a manuscript submitted for publication in Physics of Fluids journal. Chapter 5 utilizes

  • Functional Materials and Techniques for Additive Manufacturing in Soft Robotics

    Creator:
    Walker, Stephanie
    Abstract:
    This thesis outlines the development of new elastomeric materials and manufacturing processes for soft robotics. Specifically, this work describes the development of custom material formulations for use in additive manufacturing, additive manufacturing processing techniques for silicone elastomers, and multi-component additive manufacturing techniques. Material synthesis and processing is a gap in...
    Resource Type:
    Dissertation
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    elastomeric material, control of the elastomeric material, and combining the multiple materials in custom

  • High-Field Terahertz Spectroscopy of Nanoscale Materials

    Creator:
    Mousavian, Ali
    Abstract:
    This dissertation covers my work relating to the application of strong terahertz (THz) radiation to study the nonlinear properties of nano-scale material. It presents experimental and numerical studies on the optical and electronic properties of various material system including single-layer graphene, multi-walled carbon nanotubes (MWCNTs), nanoantenna-patterned gallium arsenide (GaAs) and...
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    Dissertation
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    -Field Terahertz Spectroscopy of Nanoscale Materials. Abstract approved

  • Influence of processing parameters on diffusion of divalent nickel in wet silica sol-gel monoliths

    Creator:
    Dickson, David J.
    Abstract:
    The diffusion of divalent nickel (Ni²⁺) from wet silica gels was investigated. Silica gel is gaining interest as an encapsulation matrix for biological components. The transport of biologically relevant species within the gel is determined by the structural characteristics of the gel, which are in turn governed by synthesis parameters....
    Resource Type:
    Masters Thesis
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    the degree of Master of Science in Materials Science, presented on June 9th, 2010. Title

  • Development of Cu-based Thin Films for Optoelectronic Applications

    Creator:
    Angelos, Gregory S.
    Abstract:
    CIGS and CdTe based commercial thin-film solar cells (TFSCs) require an absorber thickness greater than 2 µm and 4 µm, respectively, to adequately absorb the solar spectrum. To efficiently extract photoexcited electrons, these TFSCs require relatively defect-free absorbers with high-minority carrier mobility (> 100 cm2V−1s−1) and long lifetime (> 10...
    Resource Type:
    Dissertation
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    material properties of CdTe and CIGS make the investigation of new, non-toxic materials chosen from earth

  • Computational nanooptics in hyperbolic metamaterials and plasmonic structures

    Creator:
    Thongrattanasiri, Sukosin
    Abstract:
    This dissertation concerns several problems in the fields of light interaction with nanostructured media, metamaterials, and plasmonics. We present a technique capable of extending operational bandwidth of hyperbolic metamaterials based on interleaved highly-doped InGaAs and undoped AlInAs multilayer stacks. The experimental results confirm theoretical predictions, exhibiting broadband negative refraction response...
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    Dissertation
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    source [19, 46-56]. However, the resolution of image is highly sensitive to losses inside the material

  • Exchange interaction studies in magnetic semiconductors by neutron scattering

    Creator:
    Wiren, Zachary Quincy
    Abstract:
    Theories predict that making a dilute magnetic semiconductor strongly p -type would allow it to remain ferromagnetic at room temperature. This is of intrest as a ferromagnetic semiconductor would allow for a great many applications in the field of spintronics. Neutron scattering experiments were undertaken to better understand the antiferromagnetic...
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    Dissertation
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    for that of the overall trend and the individual materials. Farther analysis of the data obtained

  • Application and Validation of Geant4 Modeling for Optimization of Complex Structures for Fast Neutron Detection

    Creator:
    Capps, Jacob W.
    Abstract:
    Fast neutron detection is important to the detection of illicit nuclear materials and can help prevent those materials from being used or transported without discovery. Previous research has shown that Heavy Oxide Inorganic Scintillator crystals can be used to detect fast neutrons by capitalizing on their high inelastic scattering cross...
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    Dissertation
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    . . . . . . . . . . . . . . . . . . . . . 197 Chapter 1 Introduction 1.1 Background and Motivation Detection of illicit nuclear material

  • Terahertz Induced Non-linear Electron Dynamics in Nanoantenna Coated Semiconductors at the Sub-picosecond Timescale

    Creator:
    Stickel, Andrew
    Abstract:
    This dissertation is an exploration of the material response to Terahertz (THz) radiation. Specifically we will explore the ultrafast electron dynamics in the nonperturbative regime in semiconductors that have been patterned with nanoantenna arrays using broadband, high intensity, THz radiation. Three main semiconductor materials will be studied in this work....
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    Dissertation
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    Abstract approved: Yun-Shik Lee This dissertation is an exploration of the material response to Terahertz

  • An Ising-like model to predict dielectric properties of the relaxor ferroelectric solid solution BaTiO3 - Bi(Zn1/2Ti1/2)O3, An Ising-like model to predict dielectric properties of the relaxor ferroelectric solid solution BaTiO₃ − Bi(Zn₁/₂Ti₁/₂)O₃

    Creator:
    Jackson, Dennis L.
    Abstract:
    We developed a model to investigate the dielectric properties of the BaTiO₃ − Bi(Zn₁/₂Ti₁/₂)O₃ (BT-BZT) solid solution, which is a relaxor ferroelectric and exhibits long range disorder. The model uses ab initio methods to determine all polarization states for every atomic configuration of 2 x 2 x 2 supercells of...
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    Dissertation
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    of materials. The term comes from the mineral CaTiO3, commonly known as perovskite, which was

  • On-chip crosstalk suppression schemes using magnetic films for RF/microwave applications

    Creator:
    Sligar, Arien
    Abstract:
    The primary objective of the thesis research is to study novel schemes of on-chip crosstalk suppression employing magnetic films at microwave frequencies. Since extraction of various material properties of the magnetic films is essential for successful application of the proposed method, the research also involves development of a new material...
    Resource Type:
    Masters Thesis
    Full Text:
    use magnetic materials and require knowledge of several material properties such as complex

  • The optical properties of multi-scale plasmonic structures and their applications in optical characterization and imaging

    Creator:
    Kuhta, Nicholas Anthony
    Abstract:
    The optical response of metallic structures is dominated by the dynamics of their free electron plasma. Plasmonics, the area of optics specializing in the electromagnetic behavior of heterogeneous structures with metallic inclusions, is undergoing rapid development, fueled in part by recent progress in experimental fabrication techniques and novel theoretical approaches....
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    Dissertation
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    . In this thesis I outline the behavior of four plasmonic material systems, and discuss the underlying

  • Conformational Consequences: Calcium Regulates the Association Between Dysferlin C2A & PI(4,5)P2

    Creator:
    Otto, Shauna C.
    Abstract:
    Dysferlin is a ∼230 kDa terminally anchored membrane protein that is ubiquitously expressed, but is particularly enriched in skeletal and cardiac muscle tissue. Mutations covering the length of the protein have been linked to muscle wasting diseases including limb-girdle muscular dystrophy and Myoshi myopathy. Dysferlin has been shown to play...
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    Dissertation
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    dependence of this interaction is yet unknown. In this work, nuclear magnetic resonance spectroscopy and

  • Label free biosensing with carbon nanotube transistors

    Creator:
    Leyden, Matthew R.
    Abstract:
    As electronics reach nanometer size scales, new avenues of integrating biology and electronics become available. For example, nanoscale field-effect transistors have been integrated with single neurons to detect neural activity. Researchers have also used nanoscale materials to build electronic ears and noses. Another exciting development is the use of nanoscale...
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    Dissertation
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    field effect transistors to absorbed material, and the mass transport of proteins. Field effect

  • Expediting the Generation and Analysis of Amorphous Oxide Computational Models: Modeling Complex Systems Swiftly

    Creator:
    Buchanan, Jacob C.
    Abstract:
    In this dissertation, the process of computational modeling of amorphous oxide materials is studied. Amorphous oxides have random atomic arrangements with no long-range structural order which makes it difficult to study structure-property relationships. Despite the difficulties, amorphous oxides have great uses as semiconductors and dielectrics in thin-film transistors. The ability...
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    Dissertation
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    Amorphous materials have long range random atomic arrangements, making the study of the structure-property

  • Terahertz imaging and spectroscopy of carbon-based and semiconductor nanostructures

    Creator:
    Tomaino, Joseph L.
    Abstract:
    This thesis will cover work that I have completed relating to the field of terahertz (THz) science. My work has consisted of generating tunable, narrowband THz pulses in a table-top optical setup and using both narrow- and broadband THz pulses to study various material systems. Broadband THz pulses were used...
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    Dissertation
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    reflector, and an output coupler. Materials usually absorb light instead of amplify it, so a material must

  • Evaluation of amorphous oxide semiconductors for thin film transistors (TFTs) and resistive random access memory (RRAM) applications

    Creator:
    Rajachidambaram, Jaana Saranya
    Abstract:
    Thin-film transistors (TFTs) are primarily used as a switching element in liquid crystal displays. Currently, amorphous silicon is the dominant TFT technology for displays, but higher performance TFTs will become necessary to enable ultra-definition resolution high-frequency large-area displays. Amorphous zinc tin oxide (ZTO) TFTs were fabricated by RF magnetron sputter...
    Resource Type:
    Masters Thesis
    Full Text:
    related to the defect states and material properties of metal and insulator layers, and their interfaces

  • Synthesis and Analysis of Heterostructural Semiconductor Alloy Sn1-xCaxCh (Ch=S, Se) and Nitrides Zn1-xWxN and Zn1-x(W1-yMoy)xN

    Creator:
    Matthews, Bethany E.
    Abstract:
    This work explores the synthesis and characterization of the metastable alloys Sn1-xCaxCh (Ch= S, Se) and nitride compounds Zn-W-Mo-N, which have recently been predicted by theorists. Single phase thin films of Sn1-xCaxS are prepared by pulsed laser deposition and radio-frequency magnetron sputtering and of Sn1-xCaxSe are prepared by pulsed laser...
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    Dissertation
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    understanding of metastable materials. Spatially resolving the composition of a material is very important in

  • Properties of Large Superfluid Helium Droplets

    Creator:
    Alghamdi, Maha
    Abstract:
    In this dissertation, I describe the experimental investigation of large superfluid helium droplets. The goal and direction of this thesis is to facilitate the use of these droplets as part of our project ss-EDI. The overall scheme of ss-EDI is to dope proteins inside helium droplets and collect a diffraction...
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    Dissertation
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    Steric Effects. Journal of Chemical Physics 1990, 93 (7), 4779-4790. 18. Friedrich, B.; Herschbach, D

  • Growth and characterization of the p-type semiconductors SnS and BiCuOSe

    Creator:
    Francis, Jason
    Abstract:
    BiCuOSe and SnS are layered, moderate band gap (ε[subscript G] ≈ 1 eV) semiconductors that exhibit intrinsic p type conductivity. Doping of BiCuOSe with Ca results in a slight expansion of the lattice and an increase of the hole concentration from 10¹⁸ cm⁻³ to greater than 10²⁰ cm⁻³. The large...
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    Dissertation
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    Zakutayev for his prelim- inary work with the material towards the end of his time at OSU. Brady Gibbons

  • Synthesis and catalytic applications of derivatives of 7,7'-dihydroxy-8,8'-biquinolyl (azaBINOL)

    Creator:
    Wang, Chao
    Abstract:
    The synthesis of axially chiral polyfunctional derivatives of 8,8'-biquinolyl was explored and the catalytic action of appropriate derivative types investigated in three separate processes: (1) the silylcyanation of carbonyl groups and imines, (2) alkylation of a glycine Schiff-base via phase transfer-catalysis, and (3) direct amide bond formation from simple amines...
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    Dissertation
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    reported that proceeded from 7-hydroxyquinoline, a material of great expense and limited commercial

  • Heterojunction Assisted Impact Ionization at the ZnS/Si Interface and Cu_10Te_4S_13 Photodiodes

    Creator:
    Reidy, Christopher F.
    Abstract:
    Several topics are presented in this dissertation, each of which has applications to solar cells and photodetectors. First, we discuss the growth of Cu10Te4S13, copper tellurium tetrahedrite. This material has interesting optical properties; it has a large joint density of states at the conduction band maximum and valence band minimum,...
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    Dissertation
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    photodetectors. First, we discuss the growth of Cu10Te4S13, copper tellurium tetrahedrite. This material has

  • Total Synthesis of Isotopologues of Xanthohumol and its Congeners for Biological Studies

    Creator:
    Plagmann, Layhna S.
    Abstract:
    Xanthohumol [XN, (E)-6´-methoxy-3´-(3-methylbuten-2-yl)-2´,4´,4´´-trihydroxychalcone], the principal prenylated chalcone from hops, and its 2,3-dihydro- (DXN) and O6-desmethyl-2,3-dihydro- (DDXN) congeners, are of potential utility for the amelioration of metabolic syndrome; however, their complex bioactivity profiles cannot be properly studied and understood without access to appropriately produced synthetic materials. In the first part of...
    Resource Type:
    Masters Thesis
    Full Text:
    appropriately produced synthetic materials. In the first part of the thesis (Chapter 2), total syntheses of

  • Development of Amorphous Metal Thin Films for Thermal Inkjet Printing and Microelectronics

    Creator:
    McGlone, John M.
    Abstract:
    Due to a lack of grain boundaries, an amorphous metal thin film (AMTF) possesses advantageous mechanical properties and enhanced chemical stability that is potentially useful for thermal inkjet (TIJ) printing applications. The use of an AMTF as a TIJ resistor or cavitation plate could lead to a thinner TIJ cavitation...
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    Dissertation
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    diodes and deposited Al2O3. Dr. Brady Gibbons in the Material Science provided the use of his

  • Terahertz Imaging and Nonlinear Spectroscopy of Semiconductors using Plasmonic Devices

    Creator:
    Thompson, Zachary James
    Abstract:
    In this dissertation, a series of studies in the field of terahertz (THz) science are presented, specifically using nonlinear THz spectroscopy. We exploit huge field enhancement and subwavelength confinement in plasmonic structures. There are three distinct projects which will be discussed: nonlinear THz spectroscopy using plasmonic induced transparency (PIT), THz-triggered...
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    Dissertation
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    material, and ETHz is the THz electric field. . 21 3.2 A cartoon of the walk-off length. Figure 3.35 from

  • Theoretical study of beryllium borohydride Be(BH₄)₂

    Creator:
    Alghamdi, Maha D.
    Abstract:
    Ab initio calculations using the B3LYP and CCSD(T) methods were employed in this work to explore the most stable structure of the intriguing compound Be(BH₄)₂, for which as many as seven different structures have been proposed in the literature. Use of the B3LYP density functional method with several large basis...
    Resource Type:
    Masters Thesis
    Full Text:
    AN ABSTRACT OF THE THESIS OF Maha D. Alghamdi for the

  • BaCuChF (Ch = S, Se, Te) p-type transparent conductors

    Creator:
    Zakutayev, Andriy
    Abstract:
    BaCuChF (Ch = S, Se, Te) materials are chalcogen-based transparent conductors with wide optical band gaps (2.9 – 3.5 eV) and a high concentration of free holes (10¹⁸ – 10²⁰ cm⁻³) caused by the presence of copper vacancies. Chalcogen vacancies compensate copper vacancies in these materials, setting the Fermi level...
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    Dissertation
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    electronic structure of the materials and on the DFT calculations. Separate acknowledgements also go to my

  • Scanning photocurrent microscopy study of photovoltaic and thermoelectric effects in individual single-walled carbon nanotubes

    Creator:
    DeBorde, Tristan
    Abstract:
    Carbon Nanotubes are a unique family of nanostructures that have shown remarkable promise for mechanical, electrical, and optical applications. Fundamentally similar to the earlier discovered Buckminsterfullerene (C₆₀), carbon nanotubes are hollow cylinders formed from a single sheet of carbon atoms. The research presented in this dissertation investigates several carbon nanotube...
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    Dissertation
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    results of this work were published in the journal Nano Letters. During this time I was also learning

  • Experimental Study of Nucleate Boiling Bubble Dynamics and Heat Transfer Enhancement on Printed Bi-functional Surfaces

    Creator:
    David, Michele
    Abstract:
    Boiling heat transfer is studied for its ability to dissipate high fluxes and achieve heat transfer coefficients two orders of magnitude greater than single-phase heat transfer systems. Heater surface enhancement with increased surface area, varied geometry, wettability contrast and micro/nano-structures can further enhance boiling heat transfer performance through bubble nucleation...
    Resource Type:
    Masters Thesis
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    : Process scheme for superhydrophobic PTFE/PPS material ........................... 70 Figure 6.5: Size of

  • Monte Carlo studies of classical Heisenberg spins on face-centered-cubic lattices : effects of strain, interlayer coupling, and dilution of lattice

    Creator:
    Park, Seongweon
    Abstract:
    This thesis presents the results from Monte Carlo calculations on classical vector spins in face-centered-cubic (FCC) lattices. The goal of the study was to understand the effect of interlayer coupling, dilution of magnetic atoms in the lattice, and symmetry-changing strain. Experimental work by T. M. Giebultowicz et al. and J....
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    Dissertation
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    FM layers separated by a spacer layer that is made of a different material. The second subproject

  • Generating and using terahertz radiation to explore carrier dynamics of semiconductor and metal nanostructures

    Creator:
    Jameson, Andrew D.
    Abstract:
    In this thesis, I present studies in the field of terahertz (THz) spectroscopy. These studies are divided into three areas: Development of a narrowband THz source, the study of carrier transport in metal thin films, and the exploration of coherent dynamics of quasi-particles in semiconductor nanostructures with both broadband and...
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    Dissertation
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    cryogenic temperatures. Pyroelectric materials undergo a change in the polarization of the material due

  • Method development for characterizing the hydrophobicity of engineered nanoparticles

    Creator:
    Lee, Fang Yu
    Abstract:
    Characterizing the hydrophobicity of nanoparticles can help us understand their fate and transport in the environment, as well as how nanoparticles may interact with biological systems. However, contact angle and partition coefficient have limitations in measuring the hydrophobicity of nanoparticles, thus promising methods to measuring the hydrophobicity of nanoparticles are...
    Resource Type:
    Masters Thesis
    Full Text:
    Concern in Toxicology The reactivity and surface area of nano-sized materials are vastly greater than

  • Gene Expression, Structure Elucidation, and Bioactivity of Aspergillus Natural Products

    Creator:
    Neuhaus, George F.
    Abstract:
    The study of natural products (NPs) and their application has shaped humanity. Starting with the idea of using plants as medicine, it has now grown into the science of purifying and identifying organic molecules from nature to study their inherent biological activities. Understanding the molecular structures of NPs is the...
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    Dissertation
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    allowed chemists to build NPs from scratch and with more material, they enabled better evidence of

  • Comprehensive depletion-mode modeling of oxide thin-film transistors

    Creator:
    Zhou, Fan
    Abstract:
    The primary focus of this thesis is modifying the comprehensive depletion-mode model and extending its applicability to p-channel thin-film transistor (TFT) behavior and subthreshold (subpinchoff) operation. The comprehensive depletion-mode model accurately describes depletion-mode TFT behavior and establishes a set of equations, different from those obtained from square-law theory, which can...
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    Masters Thesis
    Full Text:
    of an oxide TFT-based complementary-like inverter using a single channel material. However, they

  • Zero Kinetic Energy Photoelectron Spectroscopy of Polycyclic Aromatic Hydrocarbons

    Creator:
    Harthcock, Colin
    Abstract:
    In this dissertation, I describe spectroscopic studies of jet-cooled polycyclic aromatic hydrocarbons (PAH) and one nitrogen substituted PAH (PANH) using pulsed field zero kinetic energy (ZEKE) photoelectron spectroscopy and resonantly enhanced multiphoton ionization (REMPI) spectroscopy. Recently, there has been a demand for far-infrared (FIR) spectral information of astrophysically relevant molecules...
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    Dissertation
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    Zero Kinetic Energy Photoelectron Spectroscopy of Polycyclic

  • Broadband modeling of on-chip transformers for silicon RFICs

    Creator:
    Rapolu, Kavitha
    Abstract:
    Magnetically coupled passive transformers are increasingly integrated on-chip for various analog and radio frequency (RF) applications including direct current (DC) isolation, impedance transformation/matching, and conversion between single-ended and differential signals. A primary motivation for the on-chip integration of transformers is the overall size reduction and reduced cost. However, the performance...
    Resource Type:
    Masters Thesis
    Full Text:
    physical dimensions/geometry and type of materials of the transformer structure whereas the behavioral

  • Liquid-gated carbon nanotube transistor noise sources and sensitivity limits

    Creator:
    Sharf, Tal
    Abstract:
    Low-dimensional electronic materials offer a platform to observe biological processes with unprecedented spatial and temporal resolution. Carbon nanotubes (CNTs) are the closest physical analog to an ideal 1D system and can be scaled and integrated into multiplexed electronic circuitry. The molecular structure of a CNT is also biocompatible, making them...
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    Dissertation
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    stochastic fluctuation of charge traps, which are inherent to nanometer scale material interfaces at

  • Electronic and Optical Properties of Defects in Amorphous Oxide and Transition Metal Dichalcogenide Semiconductors

    Creator:
    Vogt, Kyle
    Abstract:
    The optical and electronic properties of amorphous oxide thin films depend crucially on chemical composition, and deposition process variations which give rise to sub-gap defect states. Consequently, there is a need for a reliable, high-throughput method to extract sub-gap defect densities of states in amorphous oxide thin films. We present...
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    Dissertation
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    measurement and characterization of defects in two types of materials: amorphous oxide semiconductors (AOSs

  • DC/AC Stability of In-Ga-Zn-O Thin-Film Transistors

    Creator:
    Zhou, Fan
    Abstract:
    The electrical stability of amorphous indium-gallium-zinc oxide (a-IGZO) thinfilmtransistors (TFTs) is investigated for flat-panel display applications. Althoughproducts incorporating a-IGZO TFT backplanes are already commercially available,e.g., iMac with 5K retina display, technical challenges need to be addressed for nextgenerationapplications, e.g., active-matrix organic light-emitting diode displays.Device stability is one crucial issue. The...
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    Dissertation
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    information regarding TFT types, materials, and a literature review of IGZO TFT stability. Chapter

  • Investigation of bipolar resistive switching in zinc-tin-oxide for resistive random access memory

    Creator:
    Murali, Santosh
    Abstract:
    Resistive random access memory (RRAM) is a non-volatile memory technology based on resistive switching in a dielectric or semiconductor sandwiched between two different metals. Also known as memristors, these devices are potential candidates for a next-generation replacement for flash memory. In this thesis, bipolar resistive switching is reported for the...
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    Masters Thesis
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    , MRAM, PCM and RRAM [36]. .............................. 8 Table 3: RRAM choice of material used by

  • Multi-scale Investigation of Bidirectional Feedback Mechanism Between Breast Cancer Cells and Extracellular Matrix

    Creator:
    Kim, Jihan
    Abstract:
    Cell migration is fundamental for physiological processes such as immune re-sponses, wound healing and development. It is also a critical characteristic of metastatic cancer cells. An extensive amount of studies have focused on 2D sub-strates in order to understand the mechanism of cancer metastasis. However, much less is known about...
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    Dissertation
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    AN ABSTRACT OF THE DISSERTATION OF Jihan Kim for the degree of

  • Cis-2,5-diaminobicyclo[2.2.2]octane : a novel C₂-symmetric scaffold for asymmetric catalysis

    Creator:
    Shaw, Subrata
    Abstract:
    This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
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    Dissertation
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    catalyst are required for the synthesis of large amounts of enantioenriched material. Transition metal

  • Thermally-stable amorphous metal thin films

    Creator:
    McGlone, John M.
    Abstract:
    Amorphous metal thin films (AMTFs) are of potential use for metal-insulator-metal (MIM) tunnel diode applications due to their ultra-smooth surfaces, a consequence of their amorphous microstructure. The objective of this thesis is to design a thermally-stable AMTF capable of maintaining MIM tunnel diode performance after a post-deposition anneal in excess...
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    Masters Thesis
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    and provides a brief background of these materials. An analysis of driving forces giving rise to

  • Reflection and Dissection in Engineering Education : Exploring Critical Elements of Active Learning and their Roles in Course Structures

    Creator:
    Keeler, Jessie
    Abstract:
    This thesis focuses on active learning through four different studies that include metacognitive and cognitive aspects of learning designs to support active learning and a contextual analysis of the implementation of teaching tools used in active learning. The first three investigate important elements of active learning whereas the fourth study...
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    Masters Thesis
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    negative connotations. most of the lecture material is easy to understand but the work part seems

  • Computational and experimental investigation of steady flow fields, turbulence, and hemodynamic wall stresses in patient-specific abdominal aortic aneurysm models

    Creator:
    Edgar, Erik S.
    Abstract:
    Steady flow fields and flow-induced wall stresses have been evaluated by experimental measurements and computational fluid dynamics (CFD) analysis in a series of patient-specific abdominal aortic aneurysm (AAA) models, over a range of Reynolds numbers (Re) from 125 to 3000 (500 to 3000 for CFD). Experimental methods used particle image...
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    Masters Thesis
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    consumed by any non-nuclear processes. This is of vital importance to physics, fluid dynamics, and

  • Immune radio architecture for platform interference

    Creator:
    Alban, Eduardo
    Abstract:
    The decrease of switching times accompanied by the corresponding increase of clock speeds and data rates, contributes to improve the overall system computational performance. At the same time, they also affect wireless communications due to an increment in the emissions of electromagnetic radiation on the radio bands. In this dissertation...
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    Dissertation
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    the emergence of newer techniques, such as shielding, and materials, such a change 16 from copper

  • Tracking Photoinduced Primary Events with Femtosecond Stimulated Raman Spectroscopy and Calculations

    Creator:
    Wang, Yanli
    Abstract:
    Femtosecond stimulated Raman spectroscopy (FSRS) is a powerful ultrafast technique which can track photoinduced excited state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high temporal and spectral resolutions, FSRS provides a broad spectral window from ca. 100—2000 cm-1 for detection, enabling the direct mapping of...
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    Dissertation
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    energy, and also changes the electronic configuration and nuclear motions of reactant molecules. Light

  • Mode patterns in quadrupole resonator with anisotropic core

    Creator:
    Thongrattanasiri, Sukosin
    Abstract:
    This thesis deals with applications of uniaxial anisotropic crystals for microcavity resonators with partially chaotic underlying ray dynamics. We develop an implementation of the scattering matrix formalism, and relate the eigenvalues and eigenvectors of the scattering matrix to the field distribution of inside the system. Using the developed technique, we...
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    Masters Thesis
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    = , corresponding to non-magnetic and transparent materials in a given optical range of frequencies. The solution