Index Catalog // ScholarsArchive@OSU

Total synthesis of sparteine alkaloids from a common tetraoxobispidine intermediate

Creator:: Melbardis, John
Abstract:: In previous work (Blakemore et al. Org. Lett. 2005, 7, 4721; Heterocycles 2006, 70, 609), successful elaborations of the lupine alkaloids (±)-α-isosparteine (dl-2) and (±)-β-isosparteine (dl-3) were realized from a common tetraoxobispidine precursor, 3,7-diallyl -2,4,6,8-tetraoxo-3,7-diazabicyclo[3.3.1]nonane (93). Herein, the tetraoxobispidine approach to lupine alkaloids was extended to a total synthesis of...
Resource Type:: Masters Thesis

Fabrication and geometrical characterization of metal and metal-dielectric composite periodic nanostructures

Creator:: Bhowmik, Siddhartha
Abstract:: Periodic metal and metal-dielectric composite nanostructures have been of interest from the field of plasmonics and metamaterial fabrication. In order to exploit the behavior of these unique materials in the visible region of the optical spectrum, these structures need to be significantly shorter than the wavelength of response, and hence...
Resource Type:: Dissertation

Computational nanooptics in hyperbolic metamaterials and plasmonic structures

Creator:: Thongrattanasiri, Sukosin
Abstract:: This dissertation concerns several problems in the fields of light interaction with nanostructured media, metamaterials, and plasmonics. We present a technique capable of extending operational bandwidth of hyperbolic metamaterials based on interleaved highly-doped InGaAs and undoped AlInAs multilayer stacks. The experimental results confirm theoretical predictions, exhibiting broadband negative refraction response...
Resource Type:: Dissertation

Terahertz imaging and spectroscopy of carbon-based and semiconductor nanostructures

Creator:: Tomaino, Joseph L.
Abstract:: This thesis will cover work that I have completed relating to the field of terahertz (THz) science. My work has consisted of generating tunable, narrowband THz pulses in a table-top optical setup and using both narrow- and broadband THz pulses to study various material systems. Broadband THz pulses were used...
Resource Type:: Dissertation

Investigation of bipolar resistive switching in zinc-tin-oxide for resistive random access memory

Creator:: Murali, Santosh
Abstract:: Resistive random access memory (RRAM) is a non-volatile memory technology based on resistive switching in a dielectric or semiconductor sandwiched between two different metals. Also known as memristors, these devices are potential candidates for a next-generation replacement for flash memory. In this thesis, bipolar resistive switching is reported for the...
Resource Type:: Masters Thesis

The optical properties of multi-scale plasmonic structures and their applications in optical characterization and imaging

Creator:: Kuhta, Nicholas Anthony
Abstract:: The optical response of metallic structures is dominated by the dynamics of their free electron plasma. Plasmonics, the area of optics specializing in the electromagnetic behavior of heterogeneous structures with metallic inclusions, is undergoing rapid development, fueled in part by recent progress in experimental fabrication techniques and novel theoretical approaches....
Resource Type:: Dissertation

Hydrogen/deuterium exchange mass spectrometry as a technology platform for studying conformational dynamics in large protein complexes

Creator:: Nirudodhi, Sasidhar N.
Abstract:: Proteins are essential to all biological systems. Proteins participate in numerous cellular processes by interacting with other proteins, other metabolites and membranes in a dynamic environment. Studying the structural and conformational properties of proteins in the solution phase is necessary to understand their protein folding and interaction dynamics. This research...
Resource Type:: Dissertation

Method development for characterizing the hydrophobicity of engineered nanoparticles

Creator:: Lee, Fang Yu
Abstract:: Characterizing the hydrophobicity of nanoparticles can help us understand their fate and transport in the environment, as well as how nanoparticles may interact with biological systems. However, contact angle and partition coefficient have limitations in measuring the hydrophobicity of nanoparticles, thus promising methods to measuring the hydrophobicity of nanoparticles are...
Resource Type:: Masters Thesis
Full Text:: AN ABSTRACT OF THE THESIS OF Fang Yu Lee for the degree of Master of Science in Chemical

Cis-2,5-diaminobicyclo[2.2.2]octane : a novel C₂-symmetric scaffold for asymmetric catalysis

Creator:: Shaw, Subrata
Abstract:: This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
Resource Type:: Dissertation
Full Text:: , No. 2. 4. Chen, C. S.; Shieh, W. R.; Lu, P. H.; Harriman, S.; Che, C. Y. Biochimica et Biophysica

Comprehensive depletion-mode modeling of oxide thin-film transistors

Creator:: Zhou, Fan
Abstract:: The primary focus of this thesis is modifying the comprehensive depletion-mode model and extending its applicability to p-channel thin-film transistor (TFT) behavior and subthreshold (subpinchoff) operation. The comprehensive depletion-mode model accurately describes depletion-mode TFT behavior and establishes a set of equations, different from those obtained from square-law theory, which can...
Resource Type:: Masters Thesis

ScholarsArchive@OSU

Total synthesis of sparteine alkaloids from a common tetraoxobispidine intermediate

Fabrication and geometrical characterization of metal and metal-dielectric composite periodic nanostructures

Computational nanooptics in hyperbolic metamaterials and plasmonic structures

Terahertz imaging and spectroscopy of carbon-based and semiconductor nanostructures

Investigation of bipolar resistive switching in zinc-tin-oxide for resistive random access memory

The optical properties of multi-scale plasmonic structures and their applications in optical characterization and imaging

Hydrogen/deuterium exchange mass spectrometry as a technology platform for studying conformational dynamics in large protein complexes

Method development for characterizing the hydrophobicity of engineered nanoparticles

Cis-2,5-diaminobicyclo[2.2.2]octane : a novel C₂-symmetric scaffold for asymmetric catalysis

Comprehensive depletion-mode modeling of oxide thin-film transistors

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