In recent years, non-renewable and non-biodegradable plastic packaging forms the majority of landfilled waste. These products, mainly made from Polyethylene Tetraphlatate (PET) and other polyolefins, have excellent durability and barrier properties, but take hundreds of years to degrade.
Much focus has been put on developing environmentally friendly alternatives to polyolefins...
The rapid accumulation of plastic waste in landfill, waterways and oceans is becoming a critical problem, one that current recycling technologies are not capable of solving. Recent proposed approaches in the depolymerization of waste plastics employ an Olefin-Intermediate Process (OIP), where feedstocks like polyolefin plastics are ‘activated,’ producing an olefin...
The oxidation of carbon monoxide (CO) to carbon dioxide (CO2) is ubiquitous throughout many industrial processes and is a common probe reaction used to help understand catalytic systems in research settings. The reaction is essential in power generation and transportation exhaust gas treatment technologies to ensure environmental safety, because CO...
Heterogeneous catalysis modulates the rate and selectivity of reaction processes by
stabilizing a series of intermediate states on solid surfaces, facilitating the production
of many commodity chemicals modern society relies upon. Conventional, thermal
catalytic processes—conducted at elevated temperatures and pressures—source
thermal, mechanical, and chemical potential energy from carbon-hydrogen bonds—
combustion...
The anticonvulsant drug carbamazepine (CBZ) is a commonly prescribed drug that is used to treat patients with neurological disorders including epilepsy and bi-polar disorder. CBZ has a narrow range of efficacy: Below the therapeutic dose, seizures and other conditions are not controlled, and above the recommended window, patients experience side...
This thesis presents an experimental study of radial porosity in a manually filled cylindrical container with glass spheres. The symmetric distribution of bead diameter allowed for normalization of container properties and porosity models. The aspect ratio of the container was approximately 3.9, with tube-to-particle-diameter ratio λ ≈ 24.6 and height-to-particle-diameter...
Post-Consumer Recycled (PCR) resin grades have been successfully incorporated into plastic ink supply cartridges, with 80% of cartridge products containing 45% to 70% recycled polyethylene terephthalate (rPET). With this tremendously successful experience, incorporation of recycled polypropylene (rPP) into Injection Stretch Blow Molding (ISBM) bottles has been attempted to increase sustainability...
Hydrogen is of great interest as a fuel, as its oxidation produces benign water (without CO₂ emissions), its gaseous form can be transported in existing pipe infrastructure, and it can be obtained via renewable electricity from water. However, current hydrogen production is mainly produced from fossil fuels (e.g. methane), exacerbating...
Oxides are a versatile class of materials with a wide range of electronic, optical, and magnetic properties. This makes them ideal for use in a multitude of functional devices for oxide electronics, electrochemical conversion, and storage. The overall performance of these devices is governed by atomic scale charge and mass...
This paper describes the construction and use of a cost-effective custom-built atomic layer deposition (ALD) system, as well as the investigation of aluminum oxide atomic layer deposition using trimethylaluminum and water. For this research, a cost-effective ALD system was constructed for less than $8,000 using existing parts that were given...