Index Catalog // ScholarsArchive@OSU

Electrochemical Advancement of Solid State Ion Selective Electrodes

Creator:: Bahro, Christopher
Abstract:: The general theme of this dissertation is the development of new analytical sensors to quantitatively study biological and environmental samples in aqueous and non-aqueous environments. A platinum ultramicroelectrode (UME) and a unique carbon-based pH microprobe were used to design a new SECM-based electrochemical bioassay. The Pt UME was used to...
Resource Type:: Dissertation
Full Text:: (22), 13234–13278. https://doi.org/10.1021/acs.chemrev.6b00067. (2) Bard, A. J.; Fan, F. R. F

Alternating Between Amperometric Copper Detection and Potentiometric Calcium Detection on a Carbon-based Ion-selective Electrode

Creator:: Park, Suji
Abstract:: The unique capability of carbon-based ion-selective electrode (ISE) to perform highly sensitive anodic stripping voltammetry, while maintaining all the properties of an ISE, is demonstrated in terms of sensitivity, detection limit, response time and selectivity. Square wave anodic stripping voltammetry involves deposition and dissolution steps of metal ions, which means...
Resource Type:: Masters Thesis
Full Text:: /10.1021/ed100407u. [3] E. Bakker, P. Bühlmann, E. Pretsch, Carrier-based ion-selective electrodes and

Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

Creator:: Rahman, Tasnim
Abstract:: Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
Resource Type:: Dissertation
Full Text:: . ACS Appl. Mater. Interfaces 2021, 13 (16), 19497–19506. https://doi.org/10.1021/acsami.1c03269

New Inorganic Pigments from Mineral Structures

Creator:: Schettini Mejia, Carlo A.
Abstract:: The discovery of new blue pigments is a field of great interest, as commercially available pigments present properties that make them undesirable such as poor sustainability, cost, and stability. By researching solid solutions with the melilite structure, we discovered a new solid solution Sr2Zn1-xNixGe2O7, with 0.1 ≤ x ≤ 0.6,...
Resource Type:: Honors College Thesis
Full Text:: . https://doi.org/10.1021/acsomega.9b03255. (4) Li, J.; Subramanian, M. A. Inorganic Pigments with

Formation of hybrid supramolecular assemblies using biological molecules and transition metals

Creator:: Smith, Rachelle M. S.
Abstract:: Naturally occurring assemblies, such as DNA and proteins, utilize intermolecular forces (i.e H-bonding and van der Waals) to assemble. Utilizing these electrostatic interactions has only just started in the past five decades to be a tool used in synthetic chemistry in what is known as supramolecular chemistry. Supramolecular chemistry has...
Resource Type:: Dissertation

Per- and Polyfluoroalkyl Substances (PFAS) in Environmental Air-Water Matrices and Light Non-Aqueous Phase Liquids (LNAPL)

Creator:: Schwichtenberg, Trever J.
Abstract:: The presence of per- and polyfluoroalkyl substances (PFAS), organic contaminants first synthesized in the 1940s, has been reported worldwide in a variety of environmental matrices and ultimately in biological systems including humans. Ongoing research into PFAS has included identifying novel PFAS, assessing their fate and transport in the environment, and...
Resource Type:: Dissertation

Using Computational and Statistical Methods as an Aid to Study Environmentally Relevant Organic Molecules

Creator:: Dorn, Shelby E.
Abstract:: In this report, three studies are presented that utilize computations to predict transformations, identities, and properties of environmental organic molecules. Each study shows how computations can lead to models of chemical behavior. The importance of this research is rooted in the need for understanding how human behavior and health intersect...
Resource Type:: Masters Thesis

Uranyl Peroxide Cluster Formation Pathway and the Role of the Alkali Counterion

Creator:: Arteaga, Ana
Abstract:: Uranyl peroxide clusters are the newest family of polyoxometalates, discovered in 2015. Although this family is new, over 70 topologies have been reported. However, we lack the fundamental understanding of assembly mechanisms, particularly the role of the alkali countercations. Here, we use a wide range of solution and solid-state characterization...
Resource Type:: Dissertation
Full Text:: - Peroxide Capsules from Monomers. Inorg. Chem. 2014, 53 (19), 10506–10513. https://doi.org/10.1021

Chemistry of High-Resolution Organotin Patterning Materials

Creator:: Kenane, Nizan
Abstract:: Organotin clusters have attracted notable attention for use as inorganic photoresists. This dissertation discerns dimeric and dodecameric organotin clusters, [(n-C₄H₉Sn)(OH)(H₂O)Cl₂]₂ (Sn₂) and [(n-C₄H₉Sn)₁₂O₁₄ (OH)₆ ]+ (Sn₁₂), both of which are stable hydrolysis and condensation products of n-C₄H₉SnCl₃. This work identifies Sn₂ as a superior precursor choice for solution deposition of...
Resource Type:: Dissertation

Optimizing the Membrane Architecture and Interrogating the Stability of Hybrid Lipid-coated Gold Nanoparticles for Biological Studies and Applications

Creator:: Kmetz-Gonzalez, Gemma
Abstract:: Nanoparticles are a hugely diverse category of material that have a wide variety of biomedical applications, and developing tools for biological research with high cellular uptake is critical to their effective application. However, rarely is attention paid to the exact mechanism by which this is occurring, with most studies focusing...
Resource Type:: Capstone Project

ScholarsArchive@OSU

Electrochemical Advancement of Solid State Ion Selective Electrodes

Alternating Between Amperometric Copper Detection and Potentiometric Calcium Detection on a Carbon-based Ion-selective Electrode

Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

New Inorganic Pigments from Mineral Structures

Formation of hybrid supramolecular assemblies using biological molecules and transition metals

Per- and Polyfluoroalkyl Substances (PFAS) in Environmental Air-Water Matrices and Light Non-Aqueous Phase Liquids (LNAPL)

Using Computational and Statistical Methods as an Aid to Study Environmentally Relevant Organic Molecules

Uranyl Peroxide Cluster Formation Pathway and the Role of the Alkali Counterion

Chemistry of High-Resolution Organotin Patterning Materials

Optimizing the Membrane Architecture and Interrogating the Stability of Hybrid Lipid-coated Gold Nanoparticles for Biological Studies and Applications

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