The next generation of high temperature structural alloys must exhibit exceptional resistance to fracture, creep, oxidation, and fatigue at high temperatures. Chromium is being considered due to its high melting point (>1800°C), relatively low density (~7.2 g/cc), high temperature strength, and oxidation resistance. Limiting the use of chromium is its...
Mullite-zirconia composites have been slated for use in a novel miniature ceramic turbine engine components developed for unmanned air vehicle (UAV) engine applications. Economically feasible production of these complex components requires the use of a near-net shape process such as powder injection molding (PIM). This thesis explores the development and...
Having a series of excellent properties, the oxide dispersion-strengthened (ODS) steels provide promising solutions for the challenges of structural materials in nuclear energy, especially the development of future advanced nuclear fission and even fusion reactors. The current manufacturing route for ODS alloys includes mechanical alloying (MA) of master alloys or...
Powder injection molding (PIM) is widely used to manufacture complex-shaped ceramic and metal components in high production volumes. In order to design and fabricate PIM components, it is important to know a number of material properties at different powder- polymer compositions. In this thesis, several predictive models for estimating rheological,...
The development of amorphous metal alloys with high glass forming ability allows the fabrication of amorphous samples with thickness greater than 1mm, known as bulk metallic glasses(BMGs). Outstanding mechanical properties and ease in processing due to low melting points, low solidification shrinkage and higher supercooled liquid region make BMG a...
Ceramic injection molding (CIM) is a high volume, near net shaping process used to manufacture ceramic parts with complex features and shapes. In CIM design it is important to understand the molding behavior as a function of powder-polymer (feedstock) composition in order to achieve desired part dimensions and properties, at...
High entropy alloys (HEAs) are well known for their excellent mechanical properties compared to conventional metallic alloys. The application of High-Pressure Torsion (HPT) processing reduces grain size of materials away below 1 µm. This significant grain refinement leads to an improvement in mechanical properties, such as strength and ductility. In...
Aluminum and copper and their alloys have been widely used due to relatively high strength-to-weight ratios compared with conventional steels. Processing of these alloys is typically conducted at high temperatures over extended time periods. High-pressure torsion (HPT) is a promising processing technique for introducing significant grain refinement leading to excellent...
The thermal degradation of structural materials is considered to be a key factor for evaluating the lifetime of current nuclear power plants. Ni-based and Fe-based alloys, such as 690, 625, 304, and 316, are widely used in nuclear industry as structural components due to the extraordinary corrosion resistance and mechanical...
High-pressure torsion (HPT) is an effective severe plastic deformation (SPD)
technique to produce bulk nanostructured materials (BNMs). These BNMs often show a combination of exceptional mechanical and physical properties. Processing of single metals and alloys by HPT has been understood that the homogenous microstructures can be achieved throughout the disk...
Directed energy deposition and laser cladding technologies are suitable advanced manufacturing techniques for applying corrosion-resistant claddings to large carbon steel components. In this work, we clad 309L stainless steel wire onto carbon steel substrates and examine the effects of cladding parameters (laser power and travel speed) on metallurgical bonding, composition,...
Processing of metals through the application of high-pressure torsion (HPT) provides significant grain refinement in bulk metals at ambient temperatures. The ultrafine-grained (UFG) materials processed by HPT generally demonstrate the superior physical and mechanical characteristics. For utilizing the benefit of HPT, the feasibility of conventional HPT processing was demonstrated recently...
The influence of shear rate and temperature on the viscosity and fragility of the Zr₄₁.₂Ti₁₃.₈Cu₁₂.₅Ni₁₀.₀Be₂₂.₅ (Vit1) metallic glass forming liquid is measured in the liquid and undercooled liquid state between 907 and 1300 K. The results show a complex rheological behavior of Vit1. The viscosity of Vit1 is about three...
The effect of ambient environment on the fatigue behavior of two Zr-Ti-Cu-Ni-Be bulk metallic glasses (BMGs) is examined in the present study. The first metallic glass, Zr₄₄Ti₁₁Ni₁₀Cu₁₀Be₂₅, was tested to establish the presence of an environmental effect in the fatigue growth curve measured in ambient air. Fatigue growth curves produced...
There is a growing need for individualized instructional designs in 4-year institutions due to: 1) growing undergraduate enrollment trends across the U.S., 2) broader diversity in students backgrounds, and 3) the growing prevalence of asynchronous remote learning. With the growth in computer technology in education, tools such as adaptive intelligent...
Metallic glasses (MGs), also called amorphous metals, are metals or metallic alloys trapped in a disordered glassy state. Their amorphous nature and absence of features such as crystal lattices and defects (dislocations, grain boundaries etc.) endows them with a host of properties that far surpass those of common crystalline materials....
The corrosion resistance of steels and nickel based alloys was investigated in supercritical CO2 (sCO2). Two types of experiments were conducted. The first set of experiments were conducted in a low temperature aqueous environment to simulate conditions that would exist in direct sCO2 power cycle low temperature heat exchangers. The...
The advent of supercritical CO2 as a new heat-exchange medium has seen strong interest from the power industry and the energy research field recently. It is advan- tageous in comparison with other heat-exchange cycles, as it can be operated safely at much higher temperatures and pressures, thus increasing the thermal...
Natural fibers are gaining popularity as reinforcement materials for thermoset resins over the last two decades. Natural fibers are inexpensive, abundant, renewable and environmentally friendly. Kenaf fibers are one of the natural fibers that can potentially be used for reinforcing unsaturated polyester (UPE). As a polymer matrix, UPE enjoys a...
Phase change memory materials are a set of chalcogenide or pnictogenide materials systems currently being researched for use in optical and resistive based memory systems due to their large change in optoelectronic properties between the amorphous and the crystalline states. For these materials systems to be considered as a suitable...