Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
This study was conducted to assess whether healthy adults compared with those with Metabolic Syndrome (MetS) have different mean oxidative-reductive potentials. Static oxidation-reduction potentials and capacity oxidation reduction potentials (sORP and cORP, respectively) were measured in plasma samples. The RedoxSYS® measures sORP in millivolts (mV), which is proportional to the...
Single nucleotide polymorphisms (SNPs) can be used as markers to infer population genetic structure. For Mycoplasma cynos, a pathogen associated with infectious respiratory disease among canines and other animals, SNPs may help to elucidate ecological and evolutionary relationships among the strains that reside in the upper respiratory tract of canines...
Optical trapping is a tool used throughout a wide variety of disciplines rang- ing from precisely probing and manipulating sub-micron organisms in biol- ogy to analyzing fundamental charge transfer in colloidal physics. This thesis presents research involving optical tweezer force measurements of polystyrene and silica microspheres. In addition, preliminary work...
Objective: Cell phone use while driving (CPUWD) is an increasingly predominant form of distracted driving. Given the widespread prevalence of CPUWD, it is important for researchers to identify who is more likely to engage in this risky behavior. Prior research has focused largely on adolescent and young adult populations, and...
Amphiphilic gold nanoparticle surfactants can self-assemble at oil-water interfaces to form stable Pickering emulsions. These nanoparticle surfactants have previously been synthesized by functionalizing gold nanoparticles with thiol terminated polyethylene glycol (PEG-thiol), and subsequently with an alkane-thiol. It is necessary to improve the bio-compatibility of the nanoparticles if they are to...
Five solvents were used to resolubilize the fungal pigments of Chlorociboria aeruginosa and Scytalidium cuboideum, two common fungi used in the spalting of wood pieces. These solvents were tested as a replacement for dichloromethane in the pigment application process, via analysis of their ability to increase internal color coverage inside...
The spalting fungus Scytalidium cuboideum secretes a red pigment that produces naphthoquinonic crystals that are a photonic material candidate. The molecule can pack together in different configurations resulting in amazingly different optical properties. I developed a procedure (slowly evaporating the solvent) to preferentially grow two of these configurations, which have...
Transects were run at five locations in the Benton County area searching for
samples of Chlorociboria spp. on dead wood, with fifteen total samples found. Of
these samples, eight samples had the wood species identified, with the majority found
on Acer macrophyllum and one on Salix spp. The density of...