Turbulent flows with suspended, non-spherical particles are common in many natural and industrial processes. To identify the effects of anisotropic geometry on particle dynamics, a one-way coupled Lagrangian direct numerical simulation solver was written, verified, and used to collect data on particles simulated in multiple flows. This thesis explains the...
T. pseudonana biosilica and live cells was explored as a biosensor for detection of the explosive compound 2,4,6-trinitrotoluene (TNT) in aqueous solution. The diatom frustule is an intricately nanostructured, highly porous biogenic silica material derived from the shells of microscopic algae called diatoms. This material emits strong visible blue photoluminescence...
Red raspberry markets in both Chile and Oregon are affected by factors in each other‟s production processes. As seen in the late 1990‟s changes in pricing and supply can hinder the competitive edge of markets, pushing producers into economic hardship. Thus, the need to know the competition‟s methods is presented....
As new cost-effective cultivation methods are needed for macrophytic red algae, this experiment expands upon a previously studied land-based approach. The experiment aimed to determine how the fluid dynamics of a previously researched land-based method affected the growth of the macrophytic red alga, Gracilaria Vermiculophylla. A clonal culture of G....
Metal-organic frameworks (MOFs) are crystalline porous material distinguished for high free empty volume and pore tunability. MOF-74(Ni) was previously shown to be effective in adsorbing carbon dioxide, methane, and hydrogen. Microwave-assisted synthesis of MOF-74(Ni) was shown to lower reaction time from days to hours. In this thesis, experimental conditions of...
Water-soluble quantum dots obtained through ligand exchange are widely applicable for biological imaging and marking, LEDs, and photovoltaics. Lipoic acid (LA) was reduced to dihydrolipoic acid (DHLA) using 365-nm soft UV light in a process known as photoligation, and ligand exchange with dodecanethiol-capped CuInS₂-ZnS core-shell quantum dots occurred. The reaction...
Molybdenum disulfide (MoS2) has potential applications as a low-cost catalyst for the hydrogen evolution reaction (HER). Defects on MoS2, such as edge sites and sulfur vacancies, are known to be the major active sites for HER. Controlling the formation of these defects allows for the enhancement in reactivity of MoS2...
Organic aggregates and transparent amorphous metals are transforming opto-electronic devices such as highly efficiency solar cells and flexible displays. We present a fundamental optical study of how local morphology critically impacts the device performance of both stacked, conjugated organics and In-Ga-Zn-O (IGZO) transparent metallic materials. Derivatives of anthradithiophene (ADT): ADTTES-F,...
The symbiotic sea anemone Exaiptasia diaphana (Aiptasia) is a model organism used to better understand cnidarian-algal symbiosis and coral bleaching (dysbiosis). Many biological processes are hypothesized to be involved in coral dysbiosis, and the innate immunity is a key area of interest. Rab proteins are small proteins with GTPase domains,...
Childhood obesity is an extensively research topic as it effects a large number of individuals and has serious consequences on those effected. Current statistics estimate roughly 17% of the youth population is now obese. However, the spread of these cases is not equally distributed. Certain populations are at increased risk...
There is significant evidence that an increase in social media usage causes changes to mood and feelings about the self. It has also been found that there is a significant relationship between the extent of social media usage consumption and self-perception. Mimicking social media exposure, I focused on how participants...
Platinum and palladium surfaces are utilized as catalytic surfaces in the chemical industry. Understanding how hydrogen atoms interact with the metal surfaces will allow for further advancement in this area. Specifically, the interaction of hydrogen on the surface and subsurface of these metals was investigated using density functional theory calculations...
ASD is characterized primarily by deficits in social and communicative skills, however recent studies show differences in motor skills as well when compared to typically developing children. Because of these differences, parents of children with ASD may portray different behaviors than parents of typically developing children. This research aims to find...
Introduction: Swim-up has been considered a preferred method for separating non-motile sperm in an ejaculate. However, the long incubation time and equipment necessary for swim-up make this process clinically impractical. It was hypothesized that these problems could be avoided for canine applications with a shorter incubation time at room temperature...
Freeze desalination poses as a potential solution to many of the issues that accompany current desalination methods. The research detailed in this manuscript involves creating and analyzing a numerical model of the freezing operation of an indirect contact freeze-melting (FM) desalination system. In this initial analysis, pure water is frozen...
Ovarian steroidogenesis is heavily controlled by the formation and function of the theca cells. A condition known as polycystic ovarian disease in humans and cystic ovarian disease in cattle is due to abnormal steroidogenesis. Knowing more about theca cell formation and function can aid in gaining further knowledge about polycystic...
We found that a strains of Yersinia pestis (KIM5) which lacked the nhaA gene was fully attenuated in a plague model. This gene produces a protein of the sodium-proton antiporter family which expel sodium ions from the bacterial cytoplasm in exchange for hydrogen ions, or protons, from the surrounding environment....
The fundamental physics of turbulence in plasma is not well understood. Recent studies of the plasma deflagration accelerator in the High Temperature Gasdynamics Lab at Stanford University have demonstrated the presence of small scale instabilities that limit the lifetime of the jet/Z pinch and are not reproduced by coaxial plasma...
I investigate the feasibility of a micron-sized biosensor designed to measure neural activity. The circuitry of the biosensor is composed of graphene, some photodiodes, and a light-emitting diode. Many of these biosensors would be injected into a subject’s brain, and when powered by near-infrared light, they would glow in response...