In this dissertation, my research work on excited state dynamics of small organic molecules in solutions is presented. Using femtosecond stimulated Raman spectroscopy (FSRS) as the main experimental tool, the excited state hydrogen-bonding dynamics (ESHBD) of Coumarin 102, a common laser dye molecule, in ethanol solution is examined with <150...
Ultrafast spectroscopy has recently gained momentum as a powerful, noninvasive characterization toolset capable of studying a diverse array of samples with applications in chemistry, physics, biology, engineering, and more. Two popular ultrafast spectroscopic techniques include femtosecond transient absorption (fs-TA) and femtosecond stimulated Raman spectroscopy (FSRS). The latter of these techniques...
Ultrafast spectroscopy can exploit the structure-function relationship of chemical- and biological-based systems. More specifically, femtosecond stimulated Raman spectroscopy (FSRS) provides ground- and excited-state vibrational information with simultaneously high spectral (spatial) and temporal resolutions. The electronic counterpart, femtosecond transient absorption (fs-TA), complements FSRS data analysis as part of a comprehensive approach...
Soils and other resource programs in both public land management agencies and private industry are continually being adapted to the challenges of evolving knowledge and experience in the field of forestry. This dissertation explores new ways of thinking about and using soils information in forest planning and management, with a...
The purpose of this exploratory study was to develop an instrument to measure perceived food autonomy (PFA) among cognitively alert residents in state licensed Assisted Living (AL) facilities, and to investigate the influence of PFA on food satisfaction, while controlling for functional (physical, social, and psychological) status, general health, and...
Femtosecond stimulated Raman spectroscopy (FSRS) is a powerful ultrafast technique which can track photoinduced excited state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high temporal and spectral resolutions, FSRS provides a broad spectral window from ca. 100—2000 cm-1 for detection, enabling the direct mapping of...
Voltage controlled oscillator (VCO) based ADC is an important class of time-domain ADC that has gained widespread acceptance due to their several desirable properties. VCO-based ADCs behave like an open-loop continuous time ΔΣ modulator and achieve excellent resolution by first order noise shaping the quantization error. However, the SNDR of...
To obtain a mechanistic understanding of the chemical processes, techniques that offer a frame-by-frame visualization of molecular structure during a reaction are of vital importance. Numerous efforts and advances have been made in order to acquire such vivid molecular “movies”, especially in the electronic excited state. Ultrafast molecular spectroscopy method...
Evolution of the mobile communication standards and proliferation of hand-held devices mandate stringent Analog-to-Digital Converter (ADC) specifications. Among various ADCs, a ∆Σ ADC is best known as a power-efficient ADC when more than 12b is required. However, a conventional discrete-time (DT) ∆Σ Modulator (∆ΣM) is inadequate for low-power wideband applications...
Pathogenesis and immunity involved in fowl cholera were studied
with the turkey, one of the most susceptible natural hosts. The
causative agent, Pasteurella multocida, was analyzed in terms of its
virulence and immunogenic factors, using a highly virulent, encapsulated
strain P-1059.
Protective immunity was induced by lipopolysaccharide (LPS)-
protein complex...
The Roza flow of the Columbia River Basalt group in
Washington State U.S.A. extruded at about 15 Ma during
intermediate geomagnetic polarity. The Roza is underlain
by normal polarity flows and overlain by reversed units.
The Roza is an extensive flow, up to 60 in thick. As the
remanence-blocking isotherms...
The objective of this study is to assess the quantitative
genetic structure of fitness characters in Tribolium confusum
flour beetles. Estimates of genetic variation and covariation for a
series of fitness components (two measurements of survival,
larval weight, development time, fecundity, and female
productivity) were obtained from two populations of...
Harvesting energy from ambient sources can provide power autonomy to energy efficient electronics and sensors. The last decade has seen a multitude of ways to scavenge energy from various sources like solar, thermal, electromagnetic, electrostatic, piezo-electric and many more. Thermal energy from human body heat is ubiquitous and can be...
Data from 592 litters of pigs farrowed and raised at the
Oregon Agricultural Experiment Station at Corvallis from the spring
of 1961 through the spring of 1968 were analyzed for effects of year
and season of birth, breed, sex, inbreeding and age of dam on
measures of fecundity, growth rate...
This study was concerned with the flow of a magnetic self-propelled
ferrohydrodynamic fluid in a horizontal circular tube subjected
to axially varying temperature and magnetic field. The first
phase of the study involved the analytical solution to the governing
equations for the velocity and temperature profiles within the fully
developed...
In the first part of this dissertation, low frequency l/f or flicker noise in the frequency range of Hz to kHz has been identified and demonstrated to be described by temperature fluctuations in heat conduction in bipolar transistors operated at higher power densities. This noise phenomenon is not described by...
No-tillage winter wheat (Triticum aestivum L.) grown in a
wheat-fallow cropping system has consistently produced lower grain
yields than conventionally tilled soils in the semiarid Pacific
Northwest. A 2-year study was conducted in a long-term tillage trial
at Moro, OR to determine factors responsible for differences in wheat
growth and...
There is a perceived trade-off between fire risk reduction and northern spotted owl habitat protection in dry-conifer forests in southwestern Oregon. Management options for balancing this trade-off need to be sought at the landscape level. Applied landscape ecology suggests three important features to consider are (1) patch size and configuration...
A global solution is presented that accurately accounts for the
singular behavior at all irregular points. The linearized boundary
value problem in a semi-infinite strip in the physical plane is
transformed into a smooth unit disk by two successive conformal
mappings. The global solution results from a Fredholm integral
equation...
Managers of forest and plantation ecosystems are encountering growing problems involving plant pathogens and the expanding geographic ranges of these pathogens. Historically unexposed stands are exceptionally vulnerable when a non-native pathogen is introduced because these pathogens can cause devastating disease in a host population that lacks co-evolved resistance mechanisms. One...
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Supplemental Figure C.18. Protein sequence alignment using CLUSTAL O (1.2.4)
between PtLecRLK1
Conventional Delta-Sigma analog-to-digital converters (ADCs) utilize operational transconductance amplifiers (OTAs) in their loop filter implementation followed by multi-bit voltage domain quantizers. As CMOS integrated circuit technology scales to smaller geometries, the minimum transistor length and the intrinsic gain of the transistors decrease. Moreover, with process scaling the voltage headroom decreases...
Pseudotsuga menziesii dominates the forests of the Pacific Northwest.
But though it is dominat, Tsuaa heteroohylla or Abies amabilis
is usually climax. Many researchers have studied Pseudotsuga on the
widespread mesic sites where it is seral, but few have examined the
relatively rare ecosystems in which Pseudotsuga or its associate...
This investigation was designed to measure certain visually
perceived nonverbal behaviors of teachers in an effort to learn the
relationships between these behaviors and the affective responses of
students to the teachers, To this end, teachers were videotaped, and
the tapes were shown to students for their affective responses.
Thirty...
The atmospheric fluidized bed combustor (AFBC) is an alternative to
the pulverized coal burner. The size of a utility scale AFBC would be
enormous so that the use of large particles is necessary to reduce its
size. In modeling the combustion of coal and capture of sulfur released
from the...
Three studies were conducted to characterize and present early-seral
competition between Douglas-fir seedlings and the surrounding vegetation
communities during Pacific Northwest forest establishment. The first experiment
served as the foundation for this dissertation and was designed to quantify tradeoffs
associated with delaying forest establishment activities by introducing a fallow year...
Differential equations governing the combined heat and mass
transfer in soils are developed. Transient heat, liquid and vapor
transfer with phase change is considered. The liquid transfer is
treated as a function of the hydraulic conductivity and the gradient of
suction potential. The suction potential is considered a function of...
Imaging spectra of plant tissues yield considerable potential and useful information
for basic studies and agriculture practice. We constructed an imaging spectrophotometer
with spectral range from 400 nm to 1100 nm, which was used to study various
physiological events of plant germplasm: location of bundle sheath and mesophyll cells in...
A method of analysis of arbitrarily shaped prestressed concrete
members for biaxial bending is given. The stress-strain curve of
the concrete is represented by two parabolic segments, and the
effects of strain hardening of the steel are included in the analysis.
An iterative numerical procedure is used to solve for...
Marine sediments contain an abundance of methane that is biologically produced
and plays a significant role in the global carbon cycle. Microbes responsible for the
carbon cycle in marine sediments, and the processes that they carry out, need to be
characterized in order to fully understand the role of this...
Despite near unanimous opinion on the consequences of climate change by scientific community, the rate at which carbon is emitted into the atmosphere continues to increase. The need for a clean and sustainable source of energy is therefore one of humankind's most urgent challenges. Solar energy is the most abundant...
As advanced wired and wireless communication systems attempt to achieve higher performance, the demand for high resolution and wide signal bandwidth in their associated ADCs is strongly increased. Recently, time-domain quantization has drawn attention from its scalability in deep submicron CMOS processes. Furthermore, there are several interesting aspects of time-domain...
As the CMOS process scales down to submicron, digital circuit performance improves, while reduced supply voltage and lower transistor intrinsic gain make it difficult to implement analog circuits in a power efficient manner. Therefore, it has become advantageous to shift more analog signal processing functions conventionally realized in voltage (analog)...
Advances in electronic systems have lead to the demand for high resolution, high bandwidth Analog-to-Digital Converters (ADCs). Oversampled ADCs are well- known for high accuracy applications since they benefit from noise shaping and they usually do not need highly accurate components. However, as a consequence of oversampling, they have limited...
A common perspective promoted by health care professionals is that exercise may help reduce symptoms and improve activities of daily living among persons with multiple sclerosis (MS). Yet, the effects of resistance exercise on power, functional mobility, and fatigue are largely unknown. The purpose of this study was to examine...
In this dissertation, time-based signal processing techniques and their applications in oversampling and noise-shaping data converters are examined. These techniques demonstrate the ability to shift the burden of high performance analog circuits from the compressed voltage-domain to the augmented time-domain. First, the potential of high order noise-shaping and phase-domain feedback...
A procedure for automating the design and layout of analog-to-digital converters (ADCs) is presented. This procedure makes use of the existing synthesis and place-and-route tools that are common in digital circuit design. A method for adding rudimentary analog cells to the standard library is described, allowing the designer to synthesize...
Desire for low-power, high performance computing has been at core of the symbiotic union between digital circuits and CMOS scaling. While digital circuit performance improves with device scaling, analog circuits have not gained these benefits. As a result, it has become necessary to leverage increased digital circuit performance to mitigate...
Demographic characteristics of juvenile Dover sole
(Microstomus pacificus) were examined in relation to
physical and biotic factors to develop a hypothesis
explaining annual variations in recruitment. Surveys were
conducted along the Oregon continental shelf at depths
between 50-400 m bimonthly during 1989 and annually (in
March) between 1990 and 1993....
The increase in the demand for energy is estimated to be 28 TW by a year of 2050, which is twice of the energy produced in 2010, in response to the unprecedented growth of the global population. Current energy market is heavily relying on the fossil fuel, which brings the...
Improvement of manufacturing productivity is dependent on the successful
automation of manufacturing processes, the success of which is based in turn upon
the availability of information which describes the state of manufacturing operations.
Acoustic Emission (AE) signals related to the cutting process and tool wear have
been recently applied to...
A scalable synthesis of the "flat" tridecameric inorganic cluster [Al₁₃(μ₃-OH)₆(μ-OH)₁₈(H₂O)₂₄]¹⁵⁺ has been realized by treating an aqueous aluminum nitrate solution with zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO₃)₃. Products have been characterized by X-ray...
Part I: Plasmonic color filters can be manufactured at lower cost since they can be fabricated in single lithographic process step as compared to Fabry-Perot based filters. In addition, they have narrow passband making resolving sharp features in sample spectrum possible. Due to these benefits, in this thesis, Plasmonic color...
The photophysical properties of two-dimensional (2D) layered van der Waals (vdW) materials, and their heterostructures are manifestly distinct from crystalline bulk materials. Recently, the discovery of new 2D vdW materials and strongly-bound interlayer excitons in these materials has created a new branch in nanoscience. As such, there are a number...
Zebrafish (Brachydanio rerio) are small, freshwater teleost fishes in the family
Cyprinidae, the true minnows. They are native to the tropical latitudes of India, but
have become widespread through their use as aquarium fish and as models for several
branches of biological research. Their ease of rearing, short generation time,...