Adsorbed molecules are involved in many reactions on solid surfaces that are of great technological
importance. As such, there has been tremendous effort worldwide to learn how to theoretically
predict rates for reactions involving adsorbed molecules. Theoretical calculations of rate constants
require knowing both their activation energy and prefactor. Recent...
We, for the first time, employ magnesiothermic reaction to convert microwave-irradiated graphite oxide to pure graphene. The magnesiothermic reaction raises the carbon to oxygen atomic ratio from 22.2 to 165.7 and maintains a high surface area. The new strategy demonstrates an efficient method for obtaining highly pure graphene materials.
Porous silicon prepared by low-cost and scalable magnesiothermic reactions is a promising anode material for Li-ion batteries; yet, retaining good cycling stability for such materials in electrodes of practical loading remains a challenge. Here, we engineered the nanoporous silicon from a modified magnesiothermic reaction by controlled surface oxidization forming a...
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Mapping out multidimensional potential energy surfaces has been a goal of
physical chemistry for decades in the quest to both predict and control chemical
reactivity. Recently a new spectroscopic approach called Femtosecond Stimulated Raman
Spectroscopy or FSRS was introduced that can structurally interrogate multiple
dimensions of a reactive potential energy...
Magnesiothermic reduction can directly convert SiO₂ into Si nanostructures. Despite intense efforts, efficient fabrication of highly nanoporous silicon by Mg still remains a significant challenge due to the exothermic reaction nature. By employing table salt (NaCl) as a heat scavenger for the magnesiothermic reduction, we demonstrate an effective route to...
In Section 1 we will discuss multi-nucleon transfer reactions with light heavy ions, which can be thought of as competing with complete fusion at higher impact parameters. Quasi-elastic and multi-nucleon transfer reactions with the heaviest projectiles will be discussed in Section 2. In Section 3 we will cover recent developments...
The fate of biologically available nitrogen (N) and carbon (C) in stream ecosystems is controlled by the coupling of physical transport and biogeochemical reaction kinetics. However, determining the relative role of physical and biogeochemical controls at different temporal and spatial scales is difficult. The hyporheic zone (HZ), where groundwater–stream water...
While much effort has been directed at determining the spatial scales of adaptation in thermal reaction norms for growth, it is widely assumed that these reaction norms have high temporal stability. Water temperatures in the Gulf of Alaska in 2007 were the coldest on record since the mid-1970s and we...
Visual appeal of wood is as important as its
structural integrity in outdoor applications. Discoloration
and checking of wood favor the utilization of alternative
materials for outdoor cladding and decking. Lignin depolymerization
is one of the critical processes leading to
weathering. In the present paper, the potential of different
classes...