The size, shape, and stability of a species’ dietary niche can both influence and reflect a variety of biological patterns, including species interactions, extinction risk, and ecosystem function. This is particularly apparent when dietary changes manifest at ecosystem and clade scales to profoundly affect macroecological and macroevolutionary trajectories. However, many...
Temuan World of Words offers tantalising glimpses into the
world of one of the indigenous Orang Asli communities of
Peninsular Malaysia.
The Temuan negotiate a way of life that sits uneasily in spaces
which have not yet been fully co-opted into the service of a
cash-based economy– spaces which still...
Metal-oxo clusters are discrete, soluble pieces of bulk metal oxide. Cluster size, monodispersity, and chemical properties allow for potential use as solution-based precursors for functional metal oxide films. Classical monoalkyltin-oxo clusters are either charge neutral or stabilized by anions. The structure of Cs₄.₅H₂.₅[(BuSn)₃(α-SiW₉O₃₇)]*2H₂O enables its use in established ion exchange...
Metal-oxo clusters can be described as soluble pieces of metal-oxide frameworks. Currently, metal-oxo clusters are being considered as solution-based precursors for extreme ultraviolet (EUV, 13.5 nm) photoresist materials, which are a crucial component in the fabrication of microelectronic devices. Two different photoresist precursor systems have been investigated – alkyltin clusters...
Naturally occurring assemblies, such as DNA and proteins, utilize intermolecular forces (i.e H-bonding and van der Waals) to assemble. Utilizing these electrostatic interactions has only just started in the past five decades to be a tool used in synthetic chemistry in what is known as supramolecular chemistry. Supramolecular chemistry has...
Iron oxide materials including ferrihydrite and magnetite play essential roles in contaminant transport, pH control of surface and groundwater, and microbial activity. They have various applications ranging from data storage to cancer therapy. Recent studies showed that the NPs growth does not involve atom by atom nucleation but starts by...
Frontier research of non-aqueous actinide clusters is discussed. Since the inception of the uranyl peroxide clusters over the last decade, they have only been synthesized and characterized as solid crystals and in aqueous solution. This thesis provides thorough characterization of aqueous uranyl clusters and the first demonstration of uranyl cluster...
Polyoxometalates are a rapidly growing class of discrete metal oxide clusters with a wide range of applications including functional materials. These anionic clusters of the group V and VI transition metals are inexpensive and non-toxic. Within group V polyoxometalates, niobium and tantalum chemistry has been underdeveloped owing to their unique...
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May Nyman
Polyoxometalates are a rapidly growing class of discrete metal oxide clusters
Metal-oxo clusters can be described as soluble pieces of metal-oxide frameworks. Metal-oxo clusters are also the building blocks for the Metal-Organic Frameworks (MOFs) and coordination polymers. A better knowledge of metal-oxo clusters helps fundamentally understand geosciences, molecular engineering, catalysis, single-molecule magnetism, and MOFs for synthesis, design, and modification of these...
Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
A molecular approach to metal oxides allows to the study to fundamental bonding and formation behavior for such metals. Moreover, the molecular nature of such oxides or metal-oxo clusters allows the possibility of exploitation of the properties of the parent oxides. The tetravalent metals, in specific, (M=Zr, Hf, Ce, Th,...
Uranyl peroxide clusters are the newest family of polyoxometalates, discovered in 2015. Although this family is new, over 70 topologies have been reported. However, we lack the fundamental understanding of assembly mechanisms, particularly the role of the alkali countercations. Here, we use a wide range of solution and solid-state characterization...
Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
Metal-oxo clusters are discrete molecular metal-oxides. Most metals form numerous cluster compounds that can be ligated, unligated, charged or neutral, controlling their solubility in water and/or organic solvents. They are important species to study reaction pathways from the monomeric building units to the bulk metal oxides, and have many application...
Global interest in reducing carbon emissions by use of alternative energy sources makes nuclear energy production and the impacts of the nuclear energy cycle relevant. Studying the aqueous speciation of tetravalent metals commonly used for nuclear energy (uranium, thorium, plutonium) can inform us of general metal properties and their behavior...
Polyoxoniobates (PONbs) are attracting great attention in recent years due to its novelty as well as a variety of geometrical presentations in different pH conditions. In this paper we are reporting the reaction of tetramethyl-decaniobate ([(CH3)4N]6[Nb10O28]) with alkaline carbonates to observe the periodic trend of alkaline ions interacting with the...
Several potential sorbent materials containing iron oxides were prepared and evaluated for potential to remove divalent metals from waste waters. These included a ferrihydrite-coated sand, maghemite incorporated in Dowex[Trademark] ion exchange resin, gothite and two thermally activated ferrihydrites. Attempts to prepare sorbents from steel shot by coating with ferrihydrite or...
Western juniper (Juniperus occidentalis) encroachment has been associated with increased soil loss and reduced infiltration resulting in the loss of native herbaceous plant communities and the bird and animal species that rely on them. Hydrologically, however, change in water yield has been linked with the amount of annual precipitation a...
Conventional wastewater treatment facilities using activated sludge, secondary clarifiers, and chlorine disinfection comprise a large portion of urban wastewater treatment practices in the United States. While highly adept at removing chemical, physical, and numerous biological contaminants, these treatment methods are ineffective at removing contaminants of emerging concern, such as antibiotics...
Pacific Northwest Generating Cooperative (PNGC) operates the Landfill Gas to
Energy Facility at Coffin Butte Landfill in Corvallis, OR. At this facility, three internal
combustion engines use the landfill gas (predominantly methane and carbon dioxide) as
fuel to turn generators that produce enough electricity to power 1,800 average sized
homes....
The amount of energy we use and the ways that we get that energy sit on the edge of dramatic change as the carbon budget which can keep the planet under 1.5C of global average temperature increase gets smaller (Allen, 2018). In response, we continue to research and develop renewable...
The equation of state for a fluid described by the Weeks-Chandler-Andersen (WCA) potential was solved to determine at what pressures and temperatures the fluid will theoretically freeze. A Monte Carlo (MC) algorithm was used to sample a system of 256 spheres for a set of thermodynamic averages to locate and...
As more awareness of the global issue of sex trafficking comes to light, counselors must prepare to provide therapeutic services to this specific client population (Litam & Lam, 2021). Individuals who have survived sex trafficking are entering mental health counseling practices and community agencies regularly (Ide & Mather, 2019); yet,...
Small pelagic fish represent a critical trophic link between plankton and large predators in marine upwelling ecosystems such as the California Current System. Populations of these fish are highly variable over time and are characterized by extreme fluctuations in abundance, which have significant ecosystem impacts. The causes driving
this instability...
Channels that were scoured to bedrock by debris flows provided unique opportunities to calculate the rate of sediment and wood accumulation, to make inferences about processes associated with input and transport of sediment, and to gain insight into the temporal succession of channel morphology following disturbance. In an intensive investigation...
Coal was discovered in southwestern Washington over
One hundred years ago but until recently was of only minor
local importance. From the peak production year, in which
less than one-third of a million tons of coal were mined,
until the late 1960's, the coal production of the area degenerated
to...
Debris flows in the Pacific Northwest play a major role in routing wood and sediment stored on hillslopes and in first- through third-order channels to higher order channels and valley floors. Forest practices on steep, unstable slopes and removal of riparian trees along low-order streams can affect the frequency, magnitude,...
Lycopodium alkaloids have generated enormous amounts of interest from the scientific community, both as synthetic targets and for their medicinal properties. Herein is described work towards a unifying approach to large segments of the Lycopodium family. An organocatalyzed intramolecular heteroatom Michael reaction method, for the construction of piperidine and piperizine...
Feeding conjugated linoleic acids (CLA) improves reproductive performance in dairy cows; however, the molecular mechanisms by which CLA improves reproduction are not well understood. Therefore, we evaluated whether the CLA isomers, trans-10, cis-12 CLA and cis-9, trans-11 CLA altered synthesis of steroidogenic hormones in bovine luteal cells by measuring concentrations...
A remote job control system for the DRAFT machine is developed. It provides the user a convenient remote computing environment with facilities for job submission, a means of servicing the job queue on a first-come-first-serve basis, and usage reporting. It provides a logging facility to keep track of the user's...
A six degree of freedom (6DOF) point-absorber wave energy converter (WEC) called LUPA is being developed at Oregon State University. This research focused on analyzing a full- scale LUPA, called LUPA20, to answer the following questions: 1) How does a full-scale WEC perform due to various factors; 2) What are...
People have been growing and enjoying flowers and foliage plants for as long as history has been recorded. Once people’s needs were met for a place to live and food to eat, they began to grow and use plants for their beauty, fragrance, and shade, both indoors and out. Over...
In this dissertation, the process of computational modeling of amorphous oxide materials is studied. Amorphous oxides have random atomic arrangements with no long-range structural order which makes it difficult to study structure-property relationships. Despite the difficulties, amorphous oxides have great uses as semiconductors and dielectrics in thin-film transistors. The ability...
Certain bioactive food components, including indole-3-carbinol (I3C) and 3,3'-diindolylmethane (DIM) from cruciferous vegetables, have been shown to target cellular pathways regulating carcinogenesis. Previously, our laboratory showed that dietary I3C is an effective transplacental chemopreventive agent in a dibenzo[def,p]chrysene (DBC)-dependent model of murine T-cell lymphoblastic lymphoma. The primary objective of the...
A new high-frequency turbulence measuring instrument, MicroSoar, has been developed, tested, and used to make scalar variance dissipation rate measurements. MicroSoar was mounted on the undercarriage of SeaSoar, a depth-programmable winged platform, and towed by a ship, at speeds up to 7 kt, in a depth range of the sea...
Published March 1979. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
Oxo-hydroxo Group 5 metal clusters are an untapped resource to study and advance aqueous solution processing of metal oxide thin films. The tetramethylammonium (TMA) hexatantalate salt (TMA6[H2Ta6O19]) yields dense Ta2O5 films (~95% of the bulk ß-Ta2O5 density) with atomically smooth surfaces (<4 Å root mean square surface roughness). This same...
Revised January 2005. Reprinted July 2005. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
Reprinted July 1978. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
Revised July 1985. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
The Beginning Level of food preservation is for members of any age who are just starting the project. You might spend up to 3 years in this level as you learn the basic procedures and try the different methods.
This publication contains the 4-H Natural Science Project Record (4-H 303LR-a) and a complete set of specific project data sheets. In addition to the 4-H Natural Science Project Record, members may choose to use the specific data sheets with their project of choice. Please photocopy data sheets for members who...
Published October 1972. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
Oregon is a wonderful state. Forested land is found in every region. It's good to know about the types of plants and land use that dominate your home state. The goals of the Oregon 4-H Forestry Project are to give factual, science-based information about forests and to give you a...
Published July 1998. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
Revised July 1985. Facts and recommendations in this publication may no longer be valid. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
4-H Advancement programs consist of a series of steps that provide a framework for progressive learning within a specific project area. Advancement programs aid 4-H members to move at their own speed by encouraging self-learning that is based on their interests and abilities. Advancement programs are also self-paced, and age-...
Curriculum introduces adults and youth to the science and function of wetlands, streams and oceans, and how human activities affect climate and environmental function and health.
Published July 2000. A more recent revision exists. Please look for up-to-date information in the OSU Extension Catalog: http://extension.oregonstate.edu/catalog
4-H advancement programs consist of a series of steps that provide a framework for progressive learning within a specific project area. Advancement programs encourage 4-H members to learn at their own speed based on their interests and abilities. Advancement programs are self-paced, and age- and skill-level appropriate. Advancement programs can...