The creation of new semi-interpenetrating polymer networks (semi-IPNs) was attempted using miscible blends of high molecular weight cellulose esters (CE) and low molecular weight polyvinylphenol (PVP) with various initiators for the crosslinking reaction. Blends of cellulose acetate (CA) or cellulose acetate butyrate (CAB), at 50/50, 70/30, and 90/10 wt%CE/wt% PVP...
The rhenium (V) complex Tp'ReO₂ (Tp' = hydrido-tris-(3,5-
dimethylpyrazolyl)borate), generated in situ from PPh₃ reduction of
Tp'Re0₃, reacts with small ring heterocycles such as epoxides and
episulf ides. The strained trans-cyclooctene ring provides an unusual
thermodynamic bias against direct atom transfer, but trans-cyclooctene
oxide still produces substantial amounts of trans-cyclooctene....
Solid-state amorphous materials show amazing promise in thin-film electronics. The interface-to-bulk ratio of thin films makes interfacial chemistries of these systems of utmost importance. Thin films of amorphous metals, dielectrics and semiconductors have novel chemistries that are not only based upon their elemental constituent makeup, but also based upon the...
High speed photodetectors are a necessary element in
broad band digital and analog optical communication systems.
In this thesis easily integrable planar high speed
photodetectors made on undoped semi-insulating (SI) GaAs
substrates are modeled and tested. The fabrication process
of the detectors is fully compatible with GaAs
metal-semiconductor field effect...
Electron transport and relaxation may be substantially different in low-dimensional
systems compared to that observed in bulk material. In the present work, Monte Carlo
models are used for the solution to the Boltzmann transport equation, with scattering
rates calculated quantum mechanically for superlattice and quantum wells. Carrier
relaxation following optical...
Automation of computational chemistry, while only an engineering feat, has the potential to accelerating computational research be removing all by the science. The work in this thesis mainly discusses fundamental understanding of complex chemical systems. What is not obvious are the numerous tasks necessary for this fundamental understanding. Under the...
The challenges prompted by miniaturization of chromatographic systems have led scientists to explore new avenues in the synthesis of stationary phases. Packed capillary columns have found limited application in routine analysis due to a number of technical difficulties, most of which are attributable to the frits. New column designs insure...
The use of an adjacency matrix to determine distant (not maximal or
minimal) subgroup and supergroup relationships between crystallographic spacegroup
types is described. Full lists of space-group types that are supergroups and
subgroups for every space-group type were compiled. A list of the space-group
types connected to each space-group type...