Water electrolysis plays a pivotal role in achieving a green hydrogen economy by sourcing electricity from intermittent renewable sources. However, the efficiency of the electrolysis process is limited by the sluggish oxygen evolution reaction (OER) kinetics, whereas the kinetics of the hydrogen evolution reaction (HER) are more facile. This thesis...
This work explores the hypothesis that proton irradiation is a feasible alternative to simulate accelerated thermal aging for Ni2Cr long-range ordered phase formation within NiCr and NiCrFe alloys. In this study, various model alloys and commercial alloys 690 and 690+P (0.01 wt.% P) were subject to 2 MeV proton irradiation...
Background: Mycobacterium abscessus (MAB) is a rapidly growing opportunistic pathogen that causes infections in immunocompromised patients. The highly impermeable cell wall and surface transport systems are major contributing factors to MAB intrinsic resistance, influencing the efficacy of bactericidal antibiotics. Phages are promising alternatives to antibiotics and have been used in...
“Active carbon” is a rapidly cycling soil organic carbon (SOC) fraction that acts as an energy and nutrient source for the microbial community. Dilute permanganate oxidation has been used to measure an “active carbon” fraction with the assumption that permanganate oxidation mimics enzymatic decomposition. Permanganate oxidizable carbon (PoxC) has become...
This paper describes the construction and use of a cost-effective custom-built atomic layer deposition (ALD) system, as well as the investigation of aluminum oxide atomic layer deposition using trimethylaluminum and water. For this research, a cost-effective ALD system was constructed for less than $8,000 using existing parts that were given...
As climate change contributes to larger and more severe wildfires in California, areas of fire refugia – considered unburned and low-severity burn patches – are playing an increasingly important role in sustaining ecosystem resilience, maintaining biodiversity, and supporting post-disturbance recovery. At the same time, climate refugia – which are areas...
Magmatic-hydrothermal ore deposits are giant geochemical anomalies in the earth’s crust most often generated by normal magmatic terrestrial processes. They are often associated with oxidized and hydrous intermediate to highly evolved magmas that have concentrated metals and have the necessary components to efficiently extract and transport them as ascending magmatic-hydrothermal...
Scour is the main cause of bridge failures in the United States. Bridge failures raise a hazard to the safety of the traveling public as well as the massive economic consequences due to the high cost of constructing a new or a replacement bridge. The Oregon Department of Transportation (ODOT)...
Heavily acceptor doped Pb1.02Dx(Zr0.5Ti0.5)1-xO3 ceramics, where A is the dopant, were investigated in this research. Dopants studied included iron, magnesium and manganese at mole concentrations x ≤ 0.20. X-ray diffraction data along with scanning electron microscopy images revealed the solubility limits of these ceramics. All doped compositions exhibited a shift...
We explore the application of deep learning to the disparate fields of natural language processing and computational biology. Both the sentences uttered by humans as well as the RNA and protein sequences found within the cells of their bodies can be considered formal languages in computer science, as sets of...
In this thesis, we explore a general method for constructing path sums in a discrete spacetime using a jump amplitude matrix. This is accomplished by deriving a composition law that relates jump amplitudes to the propagator. Then properties of causal sets are used to average this relationship over sprinklings. This...
There are currently three main models used to describe the pattern of hemispheric specialization (i.e., lateralization) for emotion perception: the right hemisphere hypothesis, the valence model, and the motivational model. Although evidence exists in support of all three, the variation between each pattern of results may be due to differences...
Oxides are a versatile class of materials with a wide range of electronic, optical, and magnetic properties. This makes them ideal for use in a multitude of functional devices for oxide electronics, electrochemical conversion, and storage. The overall performance of these devices is governed by atomic scale charge and mass...
In order to advocate for a nonviolent future, I argue throughout this thesis that we must redefine our sense of self within a social context. I assert that Communitarianism, which seeks balance between the individual and their many overlapping communities, can situate our identities as less absolute and more constitutive...
This thesis argues for the importance of justice of recognition not only for humans, but the entire non-human world in the face of environmental destruction and climate crisis. The common response to the degradation of the world’s ecological sphere is to act with technological, scientific, and material based responses. However,...
The Arctic climate system is changing dramatically as a response to rising atmospheric greenhouse gas concentrations. Key indicators of Arctic change include thinning and retreating of Arctic pack ice, thawing permafrost, greening tundra, and rising surface temperatures. The structure of the atmospheric boundary layer influences and is influenced by processes...
In the face of the global climate crisis, paired with current and future risks over water resources, the importance of effective water resources management cannot be overstated. However, there is a significant lack of specific metrics used to track water stewardship on a broad scale. Thus, in order to track...
Computational statistical mechanics leans heavily on the class of Markov Chain Monte Carlo Algorithms. Many such algorithms exist, and simulations can run for several weeks, making the selection of algorithms a difficult, but critical task. In this work, we introduce a benchmark system of two quadratic wells with an analytical...
Early childhood is a crucial time for the holistic development of a child’s social, emotional, cognitive, and physical needs to build a solid and broad foundation for lifelong wellbeing and learning (Irwin et al., 2007). During this critical period, there is an increased demand for motor skills and executive function...
Hepatocellular carcinoma (HCC) is one of the leading causes of cancer death in the United States. Patients with cirrhosis are more likely to develop HCC. More than 80% of HCC patients are found have preexisting cirrhosis. The prevalence of cirrhosis increased from 0.26% to 0.3.% between 1999 to 2010 and...