During the years between 1930 and 1950 a number of attempts
were made to introduce techniques and ideas from cytology,
ecology, and genetics into the field of taxonomy. Advocates of
this "experimental taxonomy" believed that cytological, ecological,
and genetic techniques would provide a rigorous, objective
methodology to replace the traditional...
Dearomatization reactions exist broadly in biosynthesis and chemical synthesis. The highly functionalized atoms of arenes can be masked by it aromaticity, and upon dearomatization, those reactive atoms can be readily applied to bond formation and further manipulation. The total synthesis of (–)-cephalotaxine and (–)- homoharringtonine is described via an oxidative...
Substituted phenols are important substructures for pharmaceuticals, agrochemicals, natural products and biological probe molecules. The properties of phenolic molecules are substantially influenced by the substitution patterns of the phenolic ring. The chemical synthesis of phenols with various substitution patterns is an enduring challenge and multiple strategies have emerged. However, some...
Reducing future fire severity is a proposed ecological benefit of salvage logging following wildfire disturbance. Considerable debate continues over the ability of such management practices to achieve this objective given limited understanding of coarse woody detritus (CWD) dynamics, fuel bed alterations, and post-fire vegetative growth. The objective of this study...
Compact storage systems demonstrating increased hydrogen storage capacity are the key to advancing the growth of the hydrogen economy throughout the world and reducing the global dependence on fossil fuels for transportation. The use of highly porous adsorbent materials for reversible hydrogen storage is a promising pathway towards achieving storage...
Traditional approaches for the direct preparation of alkenes are unable to fully control either the stereochemical configuration of the carbon-carbon double bond or else the regiochemistry of the substituents surrounding it. The recently introduced concept of carbenoid eliminative cross-coupling (CEXC) offers a remedy to these deficiencies by providing for a...
The characteristics of an inhibitor of infectious pancreatic necrosis virus (IPNV)
found in normal rainbow trout serum (RTS) were studied. The serum inhibitor had a
molecular weight of approximately 150 kDa and was dependent on divalent cations,
either Ca²⁺ or Mg²⁺. It was stable at temperatures up to 50°C and...
Pharmaceuticals, molecular catalysts, and secondary metabolites often contain nitrogen. The problems faced synthesizing compounds which contain nitrogen was because of the Lewis base reactivity of nitrogen lone pairs, and the acidic protons of some nitrogenous functional groups. We developed two methods for the synthesis of nitrogeous compounds. Additionally, we successfully...
One of the surprising things about the 2016 presidential election was how much each presidential candidate was disliked. In this historic election, questions about whether voters made their decisions by supporting their candidate or voting against another have arisen. Studies have been done in the past that examine which traits...
Kombucha is a traditional fermented beverage that has become increasingly popular in the United States due to its perceived health benefits and unique flavor profiles. The drivers of kombucha flavor have not been fully characterized, at least in part because it is produced using a complex microbial community, leading to...