An improved procedure for the preparation of β-(3-cyclohexenyl) propionic acid from 4-vinylcyclohexene was developed. The
Friedel-Crafts cyclization of β-(3-(3-cyclohexenyl) propionyl chloride
with aluminum chloride was shown to give one bicyclic chlorine
containing ketone in 41% yield. This ketone was identified by a combination of spectral and chemical methods as a...
This report presents results of an investigation of water and streambed-sediment quality in selected tributaries of the South Umpqua River. Concentrations of inorganic constituents in water (major and minor ions, nutrients, and trace elements) and streambed sediment (primarily trace elements), along with standard field parameters, are tabulated for samples collected...
Quaternary Ammonium Compounds, Qams, are an important class of
chemicals which present interesting challenges to analysts. This thesis
reports results of investigations on uses of ion-pairing techniques for
separations and detection of Qams. Special apparatus for post-column
solvent extraction of liquid chromatographic eluates was developed as
part of this work....
This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
The seasonal distribution of bioavailable organochiorine contaminants in surface
water and the potential environmental factors influencing their bioavailability were
evaluated. The study was carried at the lower Willamette River at Portland Harbor, Oregon
where surface water runoff varied according to season. Bioavailable water concentrations of
DDTs and PCBs were determined...
The photodebromination of selected bromoarenes has been studied at 300 nm
to determine the the possible mechanistic pathways leading to product.
Irradiation of 4-bromobiphenyl (BpBr) at this wavelength leads to the product
biphenyl. The quantum yield of intersystem crossing (0.98) and quenching
studies with cis-1 ,3-pentadiene suggest that the reaction...
Sources of polar/water-soluble organic compounds conjunctly with apolar biomarkers were characterized in natural organic matter. This multi-biomarker approach was accomplished by a simple analytical method consisting of extraction with dichloromethane:methanol (2:1, v/v), silylation and analysis by gaschromatography- mass spectrometry (GC-MS). Polar and apolar biomarkers, derived mainly from higher plants and...
Acids contribute important flavor characteristics to
many foods and beverages. They occur naturally in these
products, arise from fermentation processes, or can be
added. Most acids taste sour. However, little is known
about their time-intensity characteristics of sourness.
This project was set forth to see if selected acids could be...