1-(2-pyridyl)-3-methyl-3-butene-2-ol was prepared by allowing 2-picolyllithium to react with methacrolein.
In the reaction of picolyllithium with crotonaldehyde, two products 1-(2-pyridyl)-4-methyl-3-butene-2-ol and 1-(2-pyridyl)-4-methyl-2-butene-4-ol were formed.
1-(2-pyridyl)-3-methyl-3-butene-2-ol was subjected to the low
pressure hydrogenation, using methanol as solvent and PtO₂ as catalyst. A red yellow liquid 1-(2-pyridyl)-3-methyl-2-butanol was
obtained. Derivatives of the...
The reaction of certain purin-8-ols with phosphorus
oxychloride and N,N-diethylaniline are described.
9-Amino-6-chloropurin-8-ol monohydrate reacted with
phosphorus oxychloride and N, N-diethylaniline to yield
the phosphorus oxychloride adduct. Other purin-8-ols
were prepared and the production of analogs similar to
the previously mentioned adduct was attempted.
6-Chloropurin-8-ol and 6, 9-diaminopurin-8-ol hydrochloride
monohydrate...
Both oxy-Cope and siloxy-Cope rearrangements involve
(1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism,
and the stepwise mechanism via a diradical intermediate are possible.
In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal
rearrangement takes place preferably through a diradical intermediate.
At high temperature, the reaction also...
The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec-
3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone
(VII) and cyclopentadec-5-en-l-one (VIII) after
hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic
shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with
a concerted or diradical...
The thermal and anionic rearrangements of substituted 1-vinyltrans-
cyclotridec-3-en-l-ol compounds have been studied to determine
what effects substituents would have on the sigmatropic shift when
placed on the two positions of the 1-vinyl group.
For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols
gave both the [3,3] and [1,3] shift products of...
E8,E10-dodecadien-1-ol, the primary component of the female sex pheromone of codling moth, Cydia pomonella L., has no attraction to male Oriental fruit moth (OFM), C. molesta (Busck). However, this compound when added to the OFM pheromone blend of Z8-dodecenyl acetate (85.5%), E8-dodecenyl acetate (5.5%), and Z8- dodecen -1 -ol (9.0%),...
Representing the most common flavonoid consumed in the American diet, the flavanols and their polymeric condensation products, the proanthocyanidins, are regarded as functional ingredients in various beverages, whole and processed foods, herbal remedies and supplements. Their presence in food affects food quality parameters including astringency, bitterness, sourness, sweetness, salivary viscosity,...
Green bean flavor has been studied since the 1960’s to better understand Blue Lake flavor in processed green beans in Oregon. Research by Stevens and colleagues showed that Blue Lake flavor could be reconstituted in a bland bean by adding 0.4ppm of 1-octen-3-ol and 1.6ppm of 3-hexen-1-ol. These two volatile...
Examination of a proposed reaction scheme to prepare bicyclo-(2.2.0)hexan-1-ol produced the first known condensation of an
enamine with its carbonyl precursor. Hydrolysis of the resulting
dienamine gave an unusual conjugated cyclobutenone in which the
double bond is exocyclic. Characterization and reactions of the
cyclobutenone were successfully carried out.
Essential to the testing of propositions in economic theory is the estimation of the parameters involved in relationships among economic variables. Probably the most widely used method of estimation is ordinary least squares (OLS). However, severe multicollinearity or near linear
dependence of the explanatory variables can cause the OLS estimates...
Understory vegetation communities are critical components of forest ecosystems. As a result, the importance of modeling understory vegetation characteristics in forested landscapes has become more apparent. Abundance measures such as shrub cover are bounded between 0 and 1, exhibit heteroscedastic error variance, and are often subject to spatial dependence. These...
The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have
been found to undergo sigmatropic ring expansion rearrangements in
HMPA. Preliminary investigations of several benzo-substituted medium
ring systems were undertaken in order to determine which of these
was best suited for further study. A synthetic sequence leading to
the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol,
which...
The essential oil of Alaska cedar heartwood is known to contain compounds which contribute to the remarkable durability of this species. While previous research has identified several compounds, a complete description of this oil, which has a "burnt-grape fruit" odor, has not been undertaken. In this research a profile of...
Accurate estimates of height-to-crown-base (HTCB) are essential for the reliable projections of stand structure over time required for sustainable forest management. Yet, HTCB often measured alongside total height (HT) for only for a subsample of trees in traditional stand-based inventories and must be imputed for all others. We compared the...
This thesis presents methods for obtaining asymptotically efficient and consistent parameters and variance estimates for simultaneous equations in a forest growth modelling context. Ordinary Least Squares (OLS), Seemingly Unrelated Regressions (SUR), Two-Stage Least Squares (2SLS) and Three- Stage Least Squares (3SLS) are presented for linear models. The variables, model types...
We report optical modulation of continuous terahertz (THz) wave in the frequency range of 570-600 GHz using photo-induced reconfigurable patterns on a silicon wafer. The patterns were implemented using programmable illumination from a commercially-available digital light processing (DLP) projector. A modulation depth of 20 dB at 585 GHz has been...
Inheritance of the volatile components in bush snap beans,
O.S.U. 58-110 X 'Romano' cross and reciprocal, was determined
using gas-liquid chromatographic technique with gas-entrainment
on-column trapping. A sample of 10 to 14 pods averaging 5 grams
from a single plant was found to be adequate for F₁, F₂, and backcross...
The purpose of this project was to study the reactions of 1-(α-pyridyl)-3-buten-1-ol (compound I) and to determine whether or
not the products of some of its reactions are quinolizinium salts.
Reaction of compound I with bromine or iodine yields halide
salts (when no external cooling is applied) instead of the...
Part I
The pyrolysis of cis- and trans- 1, 2-divinyl-1- trimethylsiloxy -
cyclohexane, II- and III-TMS, under the same conditions as the
pyrolysis of cis-l-vinyl -1-trimethylsiloxycyclooct-3-ene, I-TMS,
confirms that a sequence of concerted reactions for the rearrangement
of II- and III-TMS to trans-l-trimethylsiloxycyclodec-3-ene,
IV-TMS, is a viable pathway in the...
This thesis objective is to examine the relationship between individuals' goal orientations (learning-prove, learning-avoid, performance-prove, and performance-avoid) and the extent to which they provide knowledge. Included in this document is a review of literature pertaining to knowledge sharing and goal orientations. The author surveyed 64 College of Pharmacy students at...
Non-radial measure of technical efficiency of fish farms in Oyo State was examined using Data Envelopment Analysis (DEA). Use of the non-radial measures to calculate overuse of inputs by inefficient fish farmers was demonstrated and the potential for reducing inputs used by improving efficiency was evaluated. Ordinary Least Square (OLS)...
This analysis determines the impact of campaign contributions on Senators' legislative activity on the Energy Policy Act of 2003, identifies organizations within the power policy-planning network, and examines the social netwrok of the energy industry and its relationship with the power policy-planning network. After describing the research methods used for...
In this Letter, we investigate the slow-light effect of subwavelength diffraction gratings via the Rayleigh anomaly using a fully analytical approach without needing to consider specific grating structures. Our results show that the local group velocity of the transmitted light can be significantly reduced due to the optical vortex, which...
The retro-ene reaction of 2-vinylcyclohexanols occurs readily
in the vapor phase at 400-450° producing unsaturated carbonyl
compounds in good yields. The starting- materials were prepared in
general by the carbenoid addition reaction of ethyl diazoacetate,
appropriately substituted cyclohexene, and copper catalyst to
produce bicyclic esters which were reduced to the...
The potassium salts of a series of 1-vinylcycloalk-3-en-l-ols were found to undergo ring expanding [1, 3]-sigmatropic shifts at 25° when dissolved in hexamethylphosphoramide (HMPA) or 1, 2-dimethoxyethane (DME) with 18-crown-6. The yields and reaction rates were compared with those of the corresponding Siloxy-Cope ring expansions. These anionic cases showed about...
Levee management has historically been considered a local governance issue. Many users of the Portland International (PDX) airport may have no knowledge that the airport is in a floodplain and is protected by a hundred year old levee. This study asked survey respondents across the U.S. how much they would...
This study examines the association of household characteristics with forest product consumption and other benefits derived from community forest in Nepal. The analysis is based on random sample data of 80 households from a Community Forest User Groups of Baghmara Community Forestry (BCF) in Nepal. Using an OLS regression to...
Previous studies have demonstrated that light detection and ranging (LiDAR)-derived variables can be used to model forest yield variables, such as biomass, volume, and number of stems. However, the next step is underrepresented in the literature: estimation of forest yield with appropriate confidence intervals. It is of great importance that...
This paper empirically examines the effects of population aging on international trade using a cross-country panel data set for a select group of 22 OECD countries. Other recent studies have examined the effects of population age on other economic variables such as growth, savings, and investment but none till now...
Oregon’s gasoline tax no longer serves as an economically efficient revenue source due to increasing fuel efficiency and the emergence of alternative fuels. In response to this problem, the Oregon Department of Transportation is exploring alternatives to the gasoline tax. Among the most promising alternatives is a flat-rate vehicle mile...
Silicon photonics has rapidly become one of the most promising photonic integration platforms. Especially, microring resonator (MRR) plays a pivotal role in silicon photonics and has been widely used for electro-optic (E-O) modulators and wavelength filters due to its small footprint, low energy consumption, and high quality factor (Q-factor). Recently,...
Oxidative stress occurs when the balance between reactive oxygen species and antioxidant defense mechanisms in the body becomes tipped heavily in favor of the reactive oxygen species. Reactive oxygen species can be present in excess due to elevated O2 levels, radiation, infection, smoking, or even excessive exercise. It is also...
Genetic and morphological characteristics of an architectural mutant in common beans were studied. The mutant had shiny, dark green leaves, overlapping leaflets, short petioles and a reproductive terminal bud even though the line did not carry the fin gene. Branching was nearly absent resulting in a single stem vine. This...
Past research on Head Start has focused on child outcomes, yet Head Start services also target the behaviors of parents. Using data from the Fragile Families and Child Well-being Study (FFCW), the current study examined the effect of Head Start on mother (n = 3,575) and father (n = 1,812)...
The reactions of cyclodeca-1, 2, 5, 8-tetraene with mercuric salts
in solvents of varying nucleophilicity are described. Instead of forming
the usual oxymercuration products reported for reactions of olefins
and allenes with mercuric salts, the major products obtained in the
present cases result from the initial electrophilic addition of the...
There are record numbers of immigrants in the U.S., with no indication of declining in the future. Social debates surrounding issues such as immigration are fragile. It is critical that research and knowledge put out to the public and used by policy makers to create or reform immigration legislation must...
There are record numbers of immigrants in the U.S., with no indication of declining in the future. Social debates surrounding issues such as immigration are fragile. It is critical that research and knowledge put out to the public and used by policy makers to create or reform immigration legislation must...
This study examines the determinants of food consumption behaviors, such as purchasing less meat products, paying attention to how and where food is produced, and reducing food waste within the household. Food consumption is particularly important given that it can often comprise between 10% to 30% of the total household...
There are record numbers of immigrants in the U.S., with no indication of declining in the future. Social debates surrounding issues such as immigration are fragile. It is critical that research and knowledge put out to the public and used by policy makers to create or reform immigration legislation must...
We experimentally demonstrate highly efficient coupling into a slow light slotted photonic crystal waveguide. With optical mode converters and group index tapers that provide good optical mode matching and impedance matching, a nearly flat transmission over the entire guided mode spectrum of 68.8 nm range with 2.4 dB minimum insertion...
New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared
from phenol and acrylonitrile via a novel intramolecular
S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated
ketone from 4-cyclohexene carboxaldehyde. The formation of
the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
Global warming is an increasingly serious problem around the world. To mitigate the influence of global warming on people’s lives, the Obama Administration put an emphasis on reducing greenhouse gas (GHG) emissions to mitigate global warming. The adoption of energy efficient vehicles, including hybrid electric vehicles (HEVs), plug-in hybrid vehicles...
Increased livestock and aquaculture production can put pressure on the fishmeal market, and thus industrial fisheries stocks, since both of these sectors use fishmeal in their feeds. Data indicate that fishmeal supply has reached a production limit due to limited marine resources. Meanwhile there has been an explosive growth in...
Earlier papers by Brown [1973] and Brown and Beattie [1975] showed, for the common case of positively interrelated explanatory variables, that the ridge regression estimator of Hoerl and Kennard [1970] gave much larger bias and mean square error (MSE) for models with unlike signs. To avoid this excessive bias and...
Raspberries have been popular since the time of the ancient Greeks. Red raspberries are cultivated throughout the world, particularly in the Pacific Northwest region of the United States and Canada. The raspberry bushy dwarf virus (RBDV) causes significant reduction in yield and crumbly fruit in raspberries, blackberries and raspberry-blackberry hybrids....
In apples, the rapid changes occurring in fruit metabolism when approaching maturity affect their quality at harvest and after storage. The interest in the newly introduced cultivars, 'Gala', 'Braeburn' and 'Fuji' has initiated the following study on maturity indices and storage in the conditions of the Pacific Northwest. 'Gala', 'Braeburn'...
The issue of global climate change and an increasing interest in the reduction of fossil fuel carbon dioxide emissions by using forest biomass for energy production has increased the importance of quantifying forest biomass in recent years. The official U.S. forest carbon reporting is based on the forest biomass estimates...