In this dissertation, the structural properties, thermodynamics and defect behavior of amorphous metal oxides and polyoxometalates are studied. Amorphous metal oxides have many applications, most notably as a semiconducting material used as the active matrix of thin film transistors. Alas, the amorphous nature of these materials makes studying them rather...
Water electrolysis plays a pivotal role in achieving a green hydrogen economy by sourcing electricity from intermittent renewable sources. However, the efficiency of the electrolysis process is limited by the sluggish oxygen evolution reaction (OER) kinetics, whereas the kinetics of the hydrogen evolution reaction (HER) are more facile. This thesis...
This paper describes the construction and use of a cost-effective custom-built atomic layer deposition (ALD) system, as well as the investigation of aluminum oxide atomic layer deposition using trimethylaluminum and water. For this research, a cost-effective ALD system was constructed for less than $8,000 using existing parts that were given...
Due to the high cost of precursor materials, complex oxides of 4d and 5d transition metals are under-studied compared to their 3d counterparts. Recent studies have shown that oxides containing heavier transition metals can exhibit exotic electronic states due to presence of strong spin-orbit coupling. The goal of this dissertation...
A comparison was made of Al₂O₃ films deposited on Si via prompt inorganic condensation (PIC)
and atomic layer deposition (ALD). Current–voltage measurements as a function of annealing
temperature indicate that the solution-processed PIC films, annealed at 500°C, exhibit lower
leakage and roughly equivalent breakdown strength in comparison to ALD films....
Transparent conductive oxides (TCO) are at the forefront of technology with their uses in
touch screen phones and televisions, solar cells and more. Titanium dioxide and tin dioxide are two TCOs that have been studied in depth on their own, so to further explore these TCOs, this project focuses on...
Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
The phases of transition alumina are scientifically interesting due to their high specific surface area, favorable acid/ base characteristics, and chemical and hydrothermal stability which make this metallic oxide a prime candidate for use as a support for metallic nanoparticles (NPs) in heterocatalysis. Interactions at alumina/Pt interfaces are important for...
Additive manufacturing has become a promising method for the fabrication of inexpensive, green, flexible sensors and electronics. Printed electronics on low- temperature substrates are very appealing for the flexible hybrid electronics market for their use in disposable and biocompatible electronic applications and in areas like packaging, wearables, and consumer electronics....