Tile drainage increases aeration in the root zone of poorly drained soils by
accelerating water movement from the subsurface. Water movement is the main agent
of chemical transport, either transporting soluble materials directly (e.g., nitrate) or by
transporting the soil particles that bind adsorptive compounds (e.g., pesticides). The
detection frequency...
Experiments were conducted to study the effect of pore size
distribution on the diffusion of 2, 4-Dichlorophenoxyacetic acid (carbon-
14) through water saturated porous media. Eight size fractions of
glass beads were used representing the porous media. It was found
that as the average particle radius, and hence pore radius,...
Contaminant transport in ground water is an important environmental process that
affects a host of natural systems. Transport of contaminants is affected by many
processes, including aqueous complexation, adsorption, and redox reactions. One of the
most important components of an aquifer that controls transport is iron-oxide. In this
study, the...
Interactions between proteins and contact surfaces can have
important implications in the food industry. Such interactions
contribute to the course of fouling of membrane surfaces and they
appear to mediate bacterial and spore adhesion to some degree as
well. In addition to protein and solution properties, interfacial
behavior is strongly...
The effect of pH and ionic strength on the equilibrium adsorptive
behavior of β-lactoglobulin onto hydrophobic and hydrophilic
silicon surfaces was studied using ellipsometry. Plots of amount
adsorbed (μg protein/cm²) as a function of protein concentration
(mg/ml) exhibited attainment of plateau values beyond a protein
concentration of 0.250 mg/ml. At...
Batch sorption tests were conducted using 3,4-DCP and cellulose triacetate as the sorbate/sorbent pair. Sorbate concentrations
in the liquid were sampled with time and analyzed by electron
capture detector gas chromatography. Sorption was found to be a two
stage process characterized by a rapid initial uptake followed by a
extended...
Copper and zinc are heavy metals commonly present in highway stormwater runoff. Discharge of these metals to surface waters inhabited by sensitive aquatic species including threatened and endangered salmonids has necessitated the need for improved treatment techniques. Although copper is of the greater toxicological concern, zinc is often present at...
The adsorption behavior of a human recombinant Factor VIII (rFVIII) in the presence of the nonionic, poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) triblock surfactant Pluronic® F-68 was evaluated by dynamic air-water tensiometry. Surface tension kinetics were recorded for F-68 in the absence of protein at concentrations ranging from 0 to 10,000...
The marked increase in surface-to-volume ratio associated with microscale devices for hemodialysis leads to problems with hemocompatibility and blood flow distribution that are more challenging to manage than those encountered at the conventional scale. In this work, stable surface modifications with pendant polyethylene oxide (PEO) chains were produced on polycarbonate...