A graphical method, based on a set of acid-base titrations, is
presented for the determination of the carbon dioxide speciation in
natural solutions. The application of this method, in conjunction
with measurements of the partial pressure of carbon dioxide with
which our solutions were in equilibrium permitted the calculation
of...
A novel, low-cost instrument capable of measuring surface water PCO₂ was designed for use in dynamic, shallow-water environments. The instrument was tested in the Yaquina River Estuary, a macrotidal estuary known to experience a wide range of conditions ranging from dominance by the coastal ocean during summer upwelling to substantial...
The ratio of the absolute infrared intensity, A₃/A₂, for the
parallel mode (2336 cm⁻¹) and the perpendicular mode (658 cm⁻¹)
of a nonpolar solute molecule, carbon dioxide, has been determined
in a nonpolar solvent, Nujol. The solution ratio (5.0) which has
been extrapolated to zero concentration is less than the...
A cascade crosscurrent column, packed with Pall rings, was
employed for carbon dioxide absorption from a carbon dioxide-rich
air phase by contacting with water. Absorption efficiency was
presented as the percentage of CO₂ removed versus gas flow rates for
constant liquid to gas ratios (L/G).
Curves were developed for an...
The output of gas and tephra from volcanoes is an inherently disorganized process that makes reliable flux estimates challenging to obtain. Continuous monitoring of gas flux has been achieved in only a few instances at subaerial volcanoes, but never for submarine volcanoes. Here we use the first sustained (yearlong) hydroacoustic...
The corrosion behaviors of carbon and stainless steels were investigated in supercritical CO₂ (sCO₂ ) containing H₂O and O₂ simulating conditions that exist in direct sCO₂ power cycle heat exchangers. Thermodynamic properties of CO₂-H₂O-O₂ systems related to the corrosion phenomena were determined using NIST software. The exposure tests of the...
The carbon is photoelectron spectrum of CO₂ has been measured with very high photon energy resolution. The natural lifetime of the carbon is hole state has been determined from a series of spectra taken at photon energies of 308, 320, and 330 eV. The measured values of the lifetimes show...