An intramolecular variant of the modified-Julia olefination was demonstrated by the synthesis of α,β-unsaturated lactones in a mild and (Z)-selective fashion. The lynchpin reagent (benzothiazol-2-sulfonyl) acetic acid was synthesized in a straightforward fashion in 86% overall yield from commercially available 2-mercaptobenzothiazole via conversion to ethyl (benzothiazol-2-ylthio)acetate by base mediated alkylation...
Asymbiotic N fixation in leaf litter in the Northwest was assayed by acetylene reduction. Annual N input measured by periodic sampling in a young Willamette Valley Douglas-fir plantation at Adair, Oregon was 1.08 +_.13 kg/ha. Using different calculating methods, six other annual
estimates at the Adair site ranged from 0...
Precise in situ measurement of the spectral absorption and scattering coefficients in several regions has revealed patterns in the distribution of the inherent optical properties on spatial scales that were previously unobtainable. The precision of the measurements was found to be consistent and unbiased across a variety of oceanic regimes...
The mechanisms governing short- and long-term belowground carbon dynamics need to be understood. As part of a larger project developed to assess the effect of quantity and quality of litter inputs on the rate of soil organic matter (SOM) formation, I examined SOM in the H. J. Andrews Detritus Input...
The Façade photometric modeling system, developed by Paul E Debevec at Berkley, is capable of transforming a sparse set of camera images of an architectural scene into a photorealistic 3D model. Users define a rough model out of primitive building blocks and mark where a portion of the edges of...
Bluegill sunfish, Lepomia macrochirus, and cutthroat trout,
Salmo clarki, were exposed to a rapidly declining oxygen tension
for a period of time sufficient to just cause loss of equilibrium in
the fish. During recovery from the stress, measurements of
oxygen uptake, blood lactic acid, blood glucose, liver glycogen,
muscle glycogen,...