This paper describes the construction and use of a cost-effective custom-built atomic layer deposition (ALD) system, as well as the investigation of aluminum oxide atomic layer deposition using trimethylaluminum and water. For this research, a cost-effective ALD system was constructed for less than $8,000 using existing parts that were given...
Cubic phase Li₇La₃Zr₂O₁₂ (LLZO) is a promising solid electrolyte for all solid-state lithium-ion battery, due to its reasonable ionic conductivity, stable against metallic Li, wide chemical window, and thermal and chemical stability. The main aim of this thesis is to investigate the influences of different synthesis methods on the structure...
Hydrogen is the green fuel that can be produced from water through electrolysis and used via hydrogen fuel cells to generate electricity with zero carbon dioxide emission. The commercialization of electrolyzers and fuel cells is the critical step to achieving global carbon neutrality. However, it is severely hampered by the...
There is an emerging interest in developing wearable electronics as a platform, which
provides the flexibility of a wearable while maintaining its promising functionality as smart textiles. Metal-halide semiconductors are attractive materials with tunable optical and electrical properties. Researchers have widely studied and applied it for advanced
photonics and optoelectronic...
A unique microreactor-assisted nanomaterial synthesis and printing process was studied for the fabrication of patterned metal oxide nanostructured thin films. The process uses a continuous flow microreactor to control and generate a reactive chemical flux that was transported to a patterned microfluidic channel. The microreactor-assisted nanomaterial synthesis process can generate...
The solution chemistry and kinetic behavior of hafnium peroxy sulfate solutions ("HafSOx") is described in terms of peroxide content and solution speciation. Additionally, thin film behavior, including thermal behavior and solubility, is characterized, and a mechanism of patterning is presented, as well as parameters that should be considered when looking...
Diabetes is a pandemic that affects nearly 29.1 million Americans and the fourth leading cause of mortality in the US. Type 1 diabetes is a chronic condition which occurs due to little to no production of insulin by the pancreas. This form of diabetes requires constant monitoring of blood glucose...
The use of size and shape tunable quantum confinement nanocrystals has many potential applications for use in semiconductors, optics and sensors. The synthesis of lead sulfide (PbS) and copper indium diselenide (CuInSe₂) nanoparticles are of particular interest for use in semiconductor, optoelectronics and bio-medical applications.
The continuous synthesis of lead...
Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
TiO2 is a versatile wide bandgap transparent semiconducting oxide with three well known polymorphs: Anatase, Rutile and Brookite. These crystal structures are desired for many industrial applications mainly for their photocatalytic activity, oftentimes in thin-film form. Thin-film crystalline polymorphs of TiO2 are often made by physical vapor deposition on a...