In recent years, non-renewable and non-biodegradable plastic packaging forms the majority of landfilled waste. These products, mainly made from Polyethylene Tetraphlatate (PET) and other polyolefins, have excellent durability and barrier properties, but take hundreds of years to degrade.
Much focus has been put on developing environmentally friendly alternatives to polyolefins...
As the development, processing, and manufacturing of plastic has improved over the years, so has our amount of plastic waste. Currently, only approximately 9% of post-consumer plastics get recycled. The other 91% is buried in landfills, burned, ends up in the ocean, or is accumulating in communities without access to...
The rapid accumulation of plastic waste in landfill, waterways and oceans is becoming a critical problem, one that current recycling technologies are not capable of solving. Recent proposed approaches in the depolymerization of waste plastics employ an Olefin-Intermediate Process (OIP), where feedstocks like polyolefin plastics are ‘activated,’ producing an olefin...
The corrosion and heat resistance properties of nickel alloys are hallmarks of their importance in infrastructure and industrial catalysis processes, but these properties are highly dependent on the chemical composition of the alloy surface. Density functional theory was used for analysis of surface oxidation of four combinations of chromium and...
The oxidation of carbon monoxide (CO) to carbon dioxide (CO2) is ubiquitous throughout many industrial processes and is a common probe reaction used to help understand catalytic systems in research settings. The reaction is essential in power generation and transportation exhaust gas treatment technologies to ensure environmental safety, because CO...
Heterogeneous catalysis modulates the rate and selectivity of reaction processes by
stabilizing a series of intermediate states on solid surfaces, facilitating the production
of many commodity chemicals modern society relies upon. Conventional, thermal
catalytic processes—conducted at elevated temperatures and pressures—source
thermal, mechanical, and chemical potential energy from carbon-hydrogen bonds—
combustion...
Nitrate is a toxic surface and ground water contaminant that poses human-health and ecological hazards. Contamination is anthropogenically sourced to over-amendment of ammonia-based fertilizers, in turn generated by the most carbon intensive chemical process in use today. Electrochemical approaches offer a green alternative to transform harmful waste nitrate into value-added...
ZIF-8, a zeolitic imidazolate framework that consists of zinc ions and imidazolate linkers, is of great interest due to its simple synthesis methods, low-cost raw materials, chemical and thermal stability, as well as its stability in moist environments. Furthermore, due to its unique structure, it contains well-defined pores that have...
The anticonvulsant drug carbamazepine (CBZ) is a commonly prescribed drug that is used to treat patients with neurological disorders including epilepsy and bi-polar disorder. CBZ has a narrow range of efficacy: Below the therapeutic dose, seizures and other conditions are not controlled, and above the recommended window, patients experience side...
Water splitting is a green method being researched to produce green hydrogen in order to combat greenhouse gases emitted by the most popular energy source; fossil fuels. Water splitting involves two half reactions: hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Of these two, OER is the bottleneck water...
As a result of the COVID-19 pandemic, most colleges and universities around the world were forced to switch to remote learning. Many instructors were provided little guidance regarding how to restructure their courses for the remote classroom. The purpose of this study was to understand how the shift from in-person...
The detection of biomolecules is critical for clinical diagnostics but requires specialty labor and high cost. The use of microfluidic paper-based analytical devices (µPADs) for bioassays is simpler and cheaper but has low sensitivity. Improved immobilization of antibodies onto cellulose is demonstrated through surface functionalization with APTES and glutaraldehyde. The...
This thesis presents an experimental study of radial porosity in a manually filled cylindrical container with glass spheres. The symmetric distribution of bead diameter allowed for normalization of container properties and porosity models. The aspect ratio of the container was approximately 3.9, with tube-to-particle-diameter ratio λ ≈ 24.6 and height-to-particle-diameter...
Post-Consumer Recycled (PCR) resin grades have been successfully incorporated into plastic ink supply cartridges, with 80% of cartridge products containing 45% to 70% recycled polyethylene terephthalate (rPET). With this tremendously successful experience, incorporation of recycled polypropylene (rPP) into Injection Stretch Blow Molding (ISBM) bottles has been attempted to increase sustainability...
Hydrogen is of great interest as a fuel, as its oxidation produces benign water (without CO₂ emissions), its gaseous form can be transported in existing pipe infrastructure, and it can be obtained via renewable electricity from water. However, current hydrogen production is mainly produced from fossil fuels (e.g. methane), exacerbating...
In this work, a hybrid thermochemistry compressed air energy storage (CAES) system is investigated. Following a review on chemical reactions investigated for use in thermochemical energy storage (TCES) systems, from these chemistries, the conversion of magnesium carbonate, MgCO3, to magnesium oxide, MgO, and carbon dioxide, CO2, was further analyzed for...
Current natural product (NP) research is limited by its reliance on bioassay-guided fractionation to identify bioactive compounds in mixtures. Computational approaches may improve NP research by correlating mass spectra (MS) and nuclear magnetic resonance spectra (NMR) of bioactive mixtures to their bioactivity patterns. In this study, I use artificial neural...
Pesticides benefit agriculture by increasing crop yield, quality, and security. However, pesticides may inadvertently harm bees, which are valuable as pollinators. Thus, candidate pesticides in development pipelines must be assessed for toxicity to bees.
Leveraging a data set of 382 molecules with toxicity labels from honey bee exposure experiments, we...
Water electrolysis plays a pivotal role in achieving a green hydrogen economy by sourcing electricity from intermittent renewable sources. However, the efficiency of the electrolysis process is limited by the sluggish oxygen evolution reaction (OER) kinetics, whereas the kinetics of the hydrogen evolution reaction (HER) are more facile. This thesis...
This paper describes the construction and use of a cost-effective custom-built atomic layer deposition (ALD) system, as well as the investigation of aluminum oxide atomic layer deposition using trimethylaluminum and water. For this research, a cost-effective ALD system was constructed for less than $8,000 using existing parts that were given...
Oxides are a versatile class of materials with a wide range of electronic, optical, and magnetic properties. This makes them ideal for use in a multitude of functional devices for oxide electronics, electrochemical conversion, and storage. The overall performance of these devices is governed by atomic scale charge and mass...
Exergy relates to thermodynamic value or usefulness in the universe. In this dissertation, three methods in the realm of "process intensification" are explored to reduce exergy destruction by equipment and processes that are used to convert and upgrade methane. Thermodynamic efficiency of a virtual heat exchanger is improved with a...
Hydrogen is the green fuel that can be produced from water through electrolysis and used via hydrogen fuel cells to generate electricity with zero carbon dioxide emission. The commercialization of electrolyzers and fuel cells is the critical step to achieving global carbon neutrality. However, it is severely hampered by the...
Flax fibers are frequently used as a sustainable and recyclable reinforcement for composite materials in aesthetic applications (ex. car interiors). Flax fibers are biodegradable and can be sustainably harvested. Furthermore, the question of how to dispose of flax reinforced materials after the end of their lifetime can be solved in...
Solar cells, also known as photovoltaic devices, are a class of renewable energy systems that can convert photons into electrons without the carbon dioxide emission. Short-wavelength, high-energy photons in the ultraviolet (UV) range can't be efficiently utilized by most solar cells because of the spectral mismatch. Luminescent downshifting is a...
There is an emerging interest in developing wearable electronics as a platform, which
provides the flexibility of a wearable while maintaining its promising functionality as smart textiles. Metal-halide semiconductors are attractive materials with tunable optical and electrical properties. Researchers have widely studied and applied it for advanced
photonics and optoelectronic...
Heterogeneous catalytic reactions in solvents are important for chemical processes like direct methanol fuels, biomass conversion to biofuels and electrochemical reduction of CO2 to fuels. Numerous experimental studies have shown that co-adsorbates and solvents affect the rate and selectivity of heterogeneous catalytic reaction, therefore fundamental understanding of how co-adsorbates and...
Learning assistant (LA) programs are gaining increasing popularity as a means to shift instructional practice in STEM classrooms. In these programs, trained undergraduate students join the instructional team and support student-centered active learning pedagogies. Their professional development is typically supported through a seminar. In facilitating small group collaborative learning, LAs...
This thesis experimentally determines the feasibility to creating C4 to C10 hydrocarbons from CO2, CO, H2, H2O and CH4. This is done in two steps, the initial step is the formation of ethylene through DC electrical glow discharge at ambient pressure while the second step is through temperature pulse controlled...
In order to synthesize polyethylene by the microreactor with a catalyst, this thesis prepares the chemical coating layers for the reactor channel. There are two layers in the channel: the Phillips catalysts and an antimony-doped tin oxide layer on glass substrate. The Phillips catalyst help to synthesize polyethylene in the...
Water is one of the world’s most valued commodities, and antibiotic-resistant bacteria are one of the emerging pollutants of concern. Stormwater runoff picks up pollutants such as bacteria as it runs over impervious surfaces and into waterbodies. This project tested the use of biochar columns as an effective and inexpensive...
The work presented in this dissertation highlights the various techniques available to characterize the increasingly complex surfaces of engineered biomaterials. The methods used range from the simple measurement of a contact angle with a smartphone to a complex synchrotron technique like near edge x-ray absorption fine structure (NEXAFS) spectroscopy to...
Light trapping plays a phenomenal role in enhancing light confinement and light absorption within the solar cells, thus increasing the optical efficiency of the cell. Different strategies are employed for trapping light photons within the cell. Methods used include a substrate or single layer texturing, light trapping coating, plasmonic gratings,...
The goal of this project is to better characterize particle movement in a multi-channel fluidized bed. Fluidized beds are commonly used for heat transfer with the rapid fluidization and homogeneous heat distribution. By characterizing this particle flow, it would allow for an improved understanding of the heat transfer mechanisms within...
In this work, metal-organic frameworks (MOFs) are computationally represented, generated, and evaluated. The organic linker molecules are represented as graphs and use graph grammars where the atoms are represented by nodes and the bonds are represented by arcs. The grammar rules that dictate the graph generation process work on the...
Remote health monitoring tools have significant potential to revolutionize the current healthcare paradigm. Such tools could improve efficiencies in healthcare by alerting patients and doctors to abnormal health conditions in real time, shortening the time to diagnose and treat ailments. To meet these needs, we pursue the development of fabric-based...
Lanthanide (Ln) based molecular complexes have shown great potential as Lewis acid catalysts for the activation of small molecules. Despite the wealth of structural versatility and high catalytic activity of these complexes, they often lack selectivity and recyclability. This hinders their potential for use in large-scale industrial applications where waste...
Climate change is a pertinent issue causing an increase in the quantity and severity of wildfires. Current market solutions to protect homes from wildfires are expensive and do not always guarantee the safety of the home. Superabsorbent polymer (SAP) is a cross-linked polymer that can absorb over 100x its weight...
Significant challenges remain before lithium-ion batteries can support the decarbonization of the transportation and power sectors required to avert catastrophic climate change. The energy density of these batteries must be increased, while decreasing the price, and maintaining or increasing their lifespan. To improve the practical energy density of existing materials,...
Arsenic in its inorganic form is naturally present in groundwater. Continued exposure to arsenic contaminated water can result in long lasting health complications, ranging from cognitive development issues to cancer. One method which may be convertible to a field test is the use of PEG functionalized gold nanoparticles which aggregate...
Recently, there has been an expansion of large-scale studies looking at strain variation of Brettanomyces. These studies have found variation between strains in terms of utilization of maltose and production of volatile phenols. While there is research going into this subject, there is a gap in knowledge regarding the differences...
Solar thermal energy can be stored and later converted to electrical energy using a combination of thermochemical energy storage (TCES) and a thermoelectric generator (TEG). This TEG and TCES combination illustrates a potential route for clean electricity storage from renewable energy. TCES allows for thermal energy from the sun to...
Metal Organic Framework Structures (MOFs) have shown great promise for use in gas storage. Computer simulations have been touted as a method to identify strong candidate molecules for experimental research. This project assessed the relationship between computer simulations of methane absorption and experimental gas absorption. We acquired experimental data and...
Transport phenomena specially the ones that occur in the various engineering disciplines such as tissue engineering and natural environment are often complex to analyze mostly due to the dynamic and geometric complexities; as such, they have been the subject of an active and intense area of research in past decades....
Utilization of solar energy or wind energy for electricity production is inherently challenging due to the diurnal and seasonal variations and normal intermittency. Effective, high efficiency storage methods need to be developed for further advancing renewable energy utilization. Endothermic chemical processing and thermochemical energy storage can be both employed as...
Worldwide production of natural gas has surged in the last few decades leading to an economic windfall for many communities, but sometimes these new sources of natural gas are located in geographically isolated locations. These areas are so remote that it isn’t economically feasible to transport this stranded gas to...
Metal-organic frameworks (MOFs) have gained increasing attention due to their promising applications (e.g., gas storage/separations, and catalysis) as nanoporous materials stemming from generally ultrahigh porosities and surface areas. Recently, research has shifted to synthesize MOF thin films and micropatterns that enable new applications (e.g., optoelectronics, smart coatings, and sensors).
In...
Uses for materials with a large surface area and high porosity have grown sig-nificantly in recent years. Porous materials have found usage in applications such as separation, gas storage, sensing, purification and more, prompting researchers to find and discover numerous new porous materials to suit a specific purpose. Hundreds of...
Wood-based composites (WBCs) are an important sector of the US economy. For a WBC product to succeed, understanding its long-term durability, including seasonal variations in temperature and humidity, is critical. Durability is especially important WBCs because they are predominantly made from wood, which is a biological, hygroscopic material that is...
Successful cryopreservation of all biological specimens would have an untold positive impact on medicine and scientific research. However, cryopreservation of the most complex biological specimens, such as tissues and organs, remains elusive. Vitrification, or ice-free cryopreservation, is promising for cryopreservation of complex specimens. The biggest challenge, though, is the toxicity...
Nonthermal electrical plasmas can allow energy intensive reactions to occur without the use of high operating temperatures or pressures. This is because the collisions of electrons accelerated through an electric field with molecules is the cause of reactions as opposed to thermal collisions between molecules. In this study, the production...
To assess the conversion and embedment of yttrium nitrate to yttrium oxide using selective laser melting, a thermodynamic approach for laser power and scan speed predictions on surface temperature, recoil pressure, and resulting track morphology window are employed. Inkjet printing is used to deposit the liquid film of yttrium nitrate...
Metal-oxides are very important in industrial applications such as thermal barrier coatings, corrosion protection, and heterogeneous catalysis. The wide variety of applications for metal-oxides are derived from the array of properties of metal-oxides. It is, therefore, important to understand and predict the conditions of synthesis and operation to optimize the...
Paper-based assays for HIV diagnosis are cheap, portable, and require little to no skilled training, electricity, or expensive equipment to perform successfully. However, there is a need for tests with lower limits of detection (LOD) for diagnosing infection at the earliest stages. Effective labeling to increase signal-to-noise ratio is critical...
Natural freshwater availability is decreasing as the global population increases. Advances in desalination technologies aim to produce fresh water in an economical way. More sustainable energy sources are desired for these desalination plants to limit the carbon footprint of water production since global carbon dioxide production is exacerbating freshwater scarcity....
One of the principal drivers of climate change is the concentration of greenhouse gases such as CO2 in the atmosphere. A large portion of this CO2 ends up in the waters off the continental coasts where it transforms into biomass. The major sink for this matter is the ocean sediments...
Tracking footwear wear patterns is vital to the footwear industry. In the game of tennis, there are several court surfaces that produce unique wear patterns on footwear that are constantly changing according to the following factors: level of competition, level of experience, coordination, age, height, weight, and more. By tracking...
While hemodialysis is a unique therapy for treating chronic kidney failure, the application of extracorporeal blood processing presents the opportunity for treating a wider range of bloodborne diseases. The objective of the i-Blood research team is to develop a blood processing device that utilizes microscale-based technology as a platform for...
Cancer is currently the second leading cause of death in the United States and the sixth leading cause of death worldwide. Due to cancer’s variability in type, location, growth rates, and patient physiology, treatment models are based off of previous experimental and clinical work. This variability, however, can lead to...
Molybdenum disulfide (MoS2) has potential applications as a low-cost catalyst for the hydrogen evolution reaction (HER). Defects on MoS2, such as edge sites and sulfur vacancies, are known to be the major active sites for HER. Controlling the formation of these defects allows for the enhancement in reactivity of MoS2...
Microscale-based technology has potential applications in the medical field. The development of a new microscale medical device requires experimentation and testing. This can be done by creating a breadboard device that can perform the functionalities the final device should be able to do. This breadboard device can also be used...
Concentrated solar power (CSP) along with thermal energy storage (TES) has the potential to provide reliable energy from an intermittent source. TES is used to store energy while the sun is shining, allowing for the stored energy to be used when the sun is no longer shining. There are many...
Extending rheological characterization methods to very small length scales is of interest. AC susceptometry using magnetic nanoparticle probes has been proposed for measurement of frequency-dependent rheological properties at the nanoscale. As this technique has been primarily used for ideally Newtonian fluids, this research aimed to extend this technique to viscoelastic...
Lithium serves an unparalleled role for high energy-density storage applications and is vital for the continued advancement of the world economy. However, global supply is heavily reliant on lithium deposits situated in select locations, creating unpredictability in the price and concerns for the sustained production of the resource. Additionally, future...
The purpose of this research is to provide a simple fabrication method for zinc oxide and antimony sulfide based thin film solar cells. Both a ZnO nanorod electron conducting structure and a stibnite absorber show promise in a solar cell. Initial attempts at using only ZnO and Sb2S3, however, resulted...
A present abundance of biomass and a decreasing supply of petroleum signal the need for efficient pathways from renewable feedstocks to high value chemicals. One such class of chemicals is oleofurans, molecules comprised of a furan ring and carbon chain which can be used to make powerful hard water surfactants....
The wetting of a surface by a liquid is a crucial part of many natural and industrial processes. Despite numerous existing studies, some elements of wetting-dewetting such as contact angle variation are still poorly understood. Knowledge of contact angle behavior during the flow is necessary for modeling fluid displacements in...
High purity isopropyl alcohol (IPA) is utilized in silicon wafer manufacturing in cleaning and drying processes. With the ever-decreasing die size, there is an increased need for even higher purity chemicals. This process was designed to further purify a 250,000 lbs/month stream high purity isopropyl alcohol stream for use in...
Nanoparticles have become more prevalent from their use in sunscreen to antimicrobial agents in socks. In light of these applications, gaining a fundamental understanding of how NPs interact with humans is crucial for their future. Specifically, how cells interact with NPs and what factors drive the modes of cellular uptake....
Bimetallic catalysis is a promising way to tune the catalytic properties of heterogeneous catalysts. In particular, bimetallic catalysts are extensively used to enhance the selectivity of monometallic catalysts in a variety of contexts, from oxidation catalysis to oxygenate coupling. In this work, we investigate PdxCuy/SiO2 and PdxAgy/SiO2 catalysts in the...
In this work, colloidal PbSe quantum dots (QDs) are shown to be synthesized in a controlled manner by changing the growth time and reaction temperature in a microwave synthesis method. It is explained why quantum dots make such a unique material to create electronic devices and the specific benefits that...
Despite an expansive selection of available thin-layer chromatography (TLC) stationary phases, almost none are well-suited for separation of polar, ionic analytes. This work demonstrated that a highly porous stationary phase layer comprised solely of nanostructured biosilica frustules, isolated from living Pinnularia sp. diatom microalgae, improved TLC separation of the polar,...
Surface characterization of materials is widely utilized over a range of disciplines and essential to the development of new materials, technology, or processes. Metal oxide nanoclusters have shown promise as potential new generation photoresist materials for extreme ultraviolet (EUV) nanolithography. Organotin clusters have been proposed as potential candidates for resist...
There is significant interest in harnessing the biosynthetic capacities of photosynthetic diatom microalgae for the production of unique bioinspired nanomaterials. Specifically, this research focuses on understanding the photoluminescent properties of diatom biosilica and β-chitin nanofiber production in diatoms. Diatoms are single-celled microalgae that possess intricately patterned biosilica shells called, frustules....
Highly elastic solutions have been shown to increase contaminant removal from silicon wafers, indicating the possibility for reduced reliance upon hazardous chemicals and expensive technologies during the fabrication of semiconductor devices. The onset of this enhanced removal is explored using rinsing and siphoning experimentswith polymer fluids of high molecular weights...
Our society today is heavily dependent on fossil fuels such as coal and oil. However, growing environmental concerns and future fossil fuel supplies have led to interests in alternative fuels. Dimethyl Ether (DME) is an inexpensive, clean-burning, non-toxic, and potentially renewable fuel, making it a suitable choice as an alternative...
The OSU-Benton County Green Stormwater Infrastructure Research (OGSIR) Facility was created to test various methods of stormwater treatment. At this facility, runoff from the Benton County Development Department property is captured and pumped into a bioswale. This bioswale is comprised of layers of rock, gravel, sand, and soil, and is...
Real transportation fuels contain a wide range of hydrocarbon species, and this complexity poses challenges for modeling. Surrogates with a simpler blend of hydrocarbon reference fuels can approximate the physical and chemical characteristics of real fuels and enable practical simulation of the reacting flows that occur in engines and combustors....
Platinum and palladium surfaces are utilized as catalytic surfaces in the chemical industry. Understanding how hydrogen atoms interact with the metal surfaces will allow for further advancement in this area. Specifically, the interaction of hydrogen on the surface and subsurface of these metals was investigated using density functional theory calculations...
Finding renewable sources of agricultural fertilizer will be necessary to ensure a stable food supply for future generations. Phosphorus is of particular concern, since mining phosphate rock is the main source and reserves are forecasted to deplete in the next 50 – 200 years. Human urine contains substantial amounts of...
Cubic phase Li₇La₃Zr₂O₁₂ (LLZO) is a promising solid electrolyte for all solid-state lithium-ion battery, due to its reasonable ionic conductivity, stable against metallic Li, wide chemical window, and thermal and chemical stability. The main aim of this thesis is to investigate the influences of different synthesis methods on the structure...
Metal-Organic Frameworks (MOFs) are crystalline compounds formed from reacting a metal ion with an organic ligand. They represent a promising new avenue in materials science for gas separations and storage. Certain MOFs, in particular Mg-MOF-74, have shown a strong affinity for the capture of CO2. This project investigated a known...
Carbon steel, which contains mostly iron, has been widely used as reinforcement in reinforced concrete. In the alkaline environment in reinforced concrete, a thin iron oxide film, called the passive film, forms on the surface of the steel, which protects the surface from active corrosion. The exact atomic structure of...
Platelets undergo morphological changes essential to hemostasis upon activation at sites of vascular injury. The Rho GTPases Rac1, Cdc42, and RhoA drive these changes. Rho guanine nucleotide dissociation inhibitors (RhoGDIs) bind to the Rho GTPases to block the GDP from dissociating from the Rho GTPases, as well as anchoring the...
The catalyst support effect on NiMoS of bio-hydrogenated diesel production was investigated via density functional theory. The activity, stability and selectivity of catalyst on three widely used catalyst supports (Al2O3, TiO2 and SiO2) were studied and compared.
Catalyst-support interaction and Brønsted acidity strength of different catalyst supports were characterized, which...
Ambient-pressure X-ray photoelectron spectroscopy has been used to study the initial stages of dry thermal oxidation of Si₀.₆₀Ge₀.₄₀(001) grown epitaxially on Si(001). Chemical state resolved AP-XPS was performed at temperatures up to 300 ˚C and O₂ pressures up to 1 mbar. Comparisons were made to Si(001) and Ge(001). The Si...
A unique microreactor-assisted nanomaterial synthesis and printing process was studied for the fabrication of patterned metal oxide nanostructured thin films. The process uses a continuous flow microreactor to control and generate a reactive chemical flux that was transported to a patterned microfluidic channel. The microreactor-assisted nanomaterial synthesis process can generate...
Silicon wafer cleaning is a ubiquitous unit operation in the semiconductor industry to remove excess material or nanoparticle impurities to obtain perfectly smooth and clean wafer surfaces. Extensive research has already been completed to understand the physics behind hydraulic jumps observed due to balance of forces when a coherent Newtonian...
Digital inkjet printing is developing quickly today because inkjet printing processes consume less energy and water and produce less waste discharge than traditional dyeing and other printing technologies. Inkjet printing provides more versatility and flexibility in terms of printing patterns and colors. Natural pigments are gaining more attention today as...
Covalent organic frameworks (COFs) are an emerging type of microporous crystalline polymers connected by organic units via strong covalent bonds. Due to the well-defined crystalline structure and excellent chemical and thermal stabilities, COF materials are being considered as promising candidates in a variety of applications, such as gas adsorption, catalysis...
Copper zinc tin sulfide (CZTS) is a potential solar material for thin film solar cells according to its suitable band gap in the visible light range, high absorption coefficient, low toxicity, good photostability and relative earth abundance of component elements. However, the production cost of this solar thin film material...
The micro-based reactor can be considered as two phases: the main fluid and the gel phase. When the reactants p-chlorophenol enters reactor, diffuses from the main fluid to the gel phase. The diffusion and convention of p-chlorophenol happen in the main fluid. However, there is no convection in the gel...
Amorphous indium gallium zinc oxide (IGZO) thin film transistors (TFT) has revolutionized the display industry enabling smaller pixel sizes and higher refreshing rates than traditional amorphous Si: H TFTs. These attributes of IGZO were leveraged to make a field-effect sensing (FES) platform capable of sensing various biomarkers. The sensitivity and...
Pseudomonas aeruginosa is a ubiquitous bacterium that has an incredible ability to survive in various extreme environments and to persist despite bombardment by all types of antimicrobial agents. Its virulence and success within a broad range of hosts are largely thanks to the strength of its biofilms. The rheology of...
Watershed analysis is a method used to collectively characterize ecosystem elements present within a watershed. Wastewater flow and pollutant content help to define the appropriate wastewater treatment system necessary to treat the wastewater within the watershed. Watershed monitoring aids to investigate the potential contamination through analysis of surface waterbodies. Major...
The immobilization of chelators to solid supports has recently gained renewed interest due to the increasing biomedical and environmental applications made possible by these molecules’ ability to bind Fe(III) and other metal ions. The uses of immobilized chelators have expanded to include the treatment of metal overload in serum, the...
Stranded natural gas and biogas comprise a vast energy resource that is mostly wasted via flaring. This represents an opportunity to investigate novel ways to harness this resource. Nonthermal plasmas consist of excited electrons, ions and neutral atoms/molecules that have the ability to disrupt chemical bonds at ambient temperatures and...
There is a significant need for technological advancement in blood processing. New technologies in rapid processing of frozen blood products could significantly improve management of the blood supply chain in the United States by enabling on-demand use of frozen blood products that can be stored for 10 years instead of...
Suspensions of particles in fluids are everywhere in our life, such as paints, pharmacies, food, etc. Suspensions can exhibit properties that common fluids do not possess. For example, the paint needs to flow well when brushing so that it can be smeared on the wall, which is aided by the...
Protein adsorption on blood contacting medical devices usually causes fouling and failure, and may promote clotting and undesirable immune responses. Hydrophilic polymer coatings in a dense, pendent “brush” conformation can resist protein adsorption on the surface while increasing biocompatibility. Such coatings can also be used to immobilize a variety of...