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  • Characterization of BaCuSF Thin Films Grown in Excess Copper, by Pulsed Laser Deposition

    Creator:
    DeBlander, Evan F.
    Abstract:
    Thin films of the p-type semiconductor, barium copper sulfide fluoride (BaCuSF) were deposited using pulsed laser deposition. Similar p-type conductivity in Cu2O is caused by copper vacancies. Addition of copper dopant is proposed as a method for filling the copper vacancies in BaCuSF. The films are characterized to determine quality...
    Resource Type:
    Honors College Thesis
    Full Text:
    of copper dopant is proposed as a method for filling the copper vacancies in BaCuSF. The films are

  • BaCuChF (Ch = S, Se, Te) p-type transparent conductors

    Creator:
    Zakutayev, Andriy
    Abstract:
    BaCuChF (Ch = S, Se, Te) materials are chalcogen-based transparent conductors with wide optical band gaps (2.9 – 3.5 eV) and a high concentration of free holes (10¹⁸ – 10²⁰ cm⁻³) caused by the presence of copper vacancies. Chalcogen vacancies compensate copper vacancies in these materials, setting the Fermi level...
    Resource Type:
    Dissertation
    Full Text:
    Transparent Conductors by Andriy Zakutayev A DISSERTATION submitted to

  • Copper and iron chalcogenides for efficient solar absorption

    Creator:
    Platt, Heather A. S.
    Abstract:
    This dissertation outlines two approaches for improving the efficiency and reducing the cost of photovoltaic energy generation. First, the structures of known binary copper and iron compounds are used to choose the promising compositions Fe₂XS₄ (X = Si, Ge), Cu₃TaQ₄ (Q = Se, Te), and BaCuQ'F (Q' = S, Se,...
    Resource Type:
    Dissertation
    Full Text:
    Zakutayev have taught me a lot about solid state physics, and I especially want to thank them for their

  • New luminescent materials and high-performance solution-processed oxide thin films

    Creator:
    Jiang, Kai
    Abstract:
    Crystals of an incongruent-melting compound, Ba₃MgSi₂O₈, were grown by the flux method and its structure was determined by single crystal X-ray diffraction methods. Ba₃MgSi₂O₈ crystallizes in trigonal space group P-3[bar]m1 with a = 5.6123(3) Å, c = 7.2667(9) Å and Z = 1. Eu²⁺ ions prefer one crystallographic Ba site...
    Resource Type:
    Dissertation
    Full Text:
    Oxide Thin Films Abstract approved: Douglas A. Keszler Crystals of an incongruent

  • Thin-Film Dielectric Structure of Spin-Coated ZrO2 from Aqueous Inorganic Solution

    Creator:
    Moreno Luna, Hidekel A.
    Abstract:
    An inorganic aqueous precursor for the deposition of ZrO2 thin films via spincoating was developed. Hydrolysis and condensation chemistries of ZrOCl₂·8H₂O were used as the principal reactions to guide the synthesis. Refractive index, n, for a film annealed at 300 °C at 550 nm was measured to be n=1.97 by...
    Resource Type:
    Honors College Thesis
    Full Text:
    , Oregon State University, 2005 3. K. Jiang, A. Zakutayev, J. Stowers, M.D. Anderson, Solid State

  • Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

    Creator:
    Jieratum, Vorranutch
    Abstract:
    The materials Fe₂(Si,Ge)(S,Se)₄, Cu₃PS[subscript 4-x]Se[subscript x] (0 ≤ x ≤ 4), and Cu₃PxAs[subscript 1-x]S₄ (0 ≤ x ≤ 1) have been synthesized and studied as new earth-abundant absorbers for single and multijunction photovoltaic cells as well as solar fuel generation. The synthesis, single-crystal growth, and optical and electrical properties of...
    Resource Type:
    Dissertation
    Full Text:
    Candidates and YZrF7: A New Upconversion Host Abstract approved

  • Photoresist and ion-exchange chemistry of HafSOx

    Creator:
    Telecky, Alan J.
    Abstract:
    The chemistry of hafnium oxide based and materials are described in the context of ion exchange and lithography. HafSOx, represented by the composition HfO₂₋[subscript x](SO₄)x, is described to possess a significant capacity towards ion exchange in acidic and basic solutions, enabling films of HafSOx to be cleanly and readily be...
    Resource Type:
    Dissertation
    Full Text:
    : __________________________________________________ Douglas A. Keszler The chemistry of hafnium oxide based and

  • Aqueous niobium chemistry at low pH : new precursors for oxide thin films

    Creator:
    Park, Deok-Hie
    Abstract:
    Phosphate and peroxide stabilize new oxo-hydroxo niobium clusters in water at low pH. The clusters open a new chapter in aqueous niobium chemistry under acidic conditions. The clusters also produce atomically smooth, amorphous niobium oxide phosphate (NbPOx) thin films. Reaction pathways from cluster solutions to amorphous niobium oxide phosphate solids...
    Resource Type:
    Dissertation
    Full Text:
    : ______________________________________________________ Douglas A. Keszler Phosphate and peroxide stabilize new oxo-hydroxo niobium clusters

  • Aqueous chemistries for oxide electronics

    Creator:
    Meyers, Stephen T.
    Abstract:
    The variegated aqueous chemistries of metal cations are applied to the design and synthesis of non-toxic solution precursors suitable for additive printing of large-area oxide electronics. Polycondensation behaviors of aqueous Al+3 and PO4 +3 are manipulated in the deposition of atomically smooth amorphous aluminum oxide phosphate (AlPO) dielectric films. AlPO...
    Resource Type:
    Dissertation
    Full Text:
    approved: _____________________________________________________ Douglas A. Keszler The

  • Measurement of optical bandgap energies of semiconductors

    Creator:
    Russell, Joshua A.
    Abstract:
    A method for bandgap energy determination using di use re ection is presented and compared to the traditional integrating sphere method. We have found the bandgap energies of ZnO, TiO₂, Cu₂O, Si, SnZrS₃, SnZrSe₃, Sn₂S₃, and BiCuOSe powders with both methods and found they agree within 0.03 eV. We have...
    Resource Type:
    Masters Thesis
    Full Text:
    characterization. Andriy Zakutayev mentored me on the measurement and growth techniques of a solid state lab. And